不同地域天然伊利石表面酸碱特性的比较

利用电位滴定技术和恒定容量表面络合模式表征不同来源天然伊利石的表面酸碱性质。鉴于固体基质在酸量滴定过程中发生溶解，相应的滴定上清液被视为体系空白。考虑到水解铝、硅酸和伊利石表面活性位之间的表面络合或沉淀反应，提出两种表面质子反应模型。对其中的特例，还考虑了表面离子交换反应。模拟程序的拟合结果显示两种模型对水解伊利石体系的滴定行为均可获得满意的描述。相的的表面固有酸度常数表明样品的酸碱性质之间存在一些共性。     

中国华北地区冬季大气污染物航空测量(Ⅰ)——空中气态污染物污染特征研究

为掌握致酸大气污染物ＳＯ２ 和ＮＯｘ 的空间浓度分布，并探讨上述污染物扩散、迁移和传输规律，进而研究其在酸性降水形成过程中的作用，在“八五”期间酸性降水的研究中，针对中国华北地区城市和工业集中以及ＳＯ２ 和ＮＯｘ 等酸性大气污染物排放量大的特点，以石家庄及其以东地区为飞行区域，进行了华北地区冬季空中ＳＯ２ 和ＮＯｘ 污染特征的航空测量。通过测定发现在华北地区１－５ ｋｍ 左右的空中存在着ＳＯ２ 和ＮＯｘ 高浓度污染空域，同时ＳＯ２ 存在着高浓度汇集区     

203HgCl2在紫贻贝(Mytilus cdulis)体内的累积和结合以及锌对其影响的实验研究

本文研究了紫贻贝（Mytilus edulis）对无机汞²⁰³HgCl₂的累积和结合.实验结果表明:紫贻贝累积汞速度很快,能力很强.用Sephadex G75凝胶层析表明:所有的²⁰³Hg几乎都以生物大分子存在（M.W.>1000）.其中大部分²⁰³Hg的分子量大于50000,小部分分子量在1000—50000之间.本文还讨论了汞的累积机制,并研究了Zn²⁺对于²⁰³Hg累积的影响.     

乙酸型顶极群落的内平衡与反馈调节机制研究

通过产酸脱硫反应器处理高浓度硫酸盐有机废水的连续流试验，从“动态”角度考察COD／SO4^2-比改变引起的pH值、氧化还原电位（ORP）、碱度（ALK）和末端产物（VFAs）等的变动及生态因子的叠加效应引发的优势种群变迁，分析了乙酸型顶极群落的稳定性及其发生定向性生态演替的规律，进而阐明了乙酸型顶极群落抵抗环境压力的内平衡与反馈调节机制，并指出乙酸型代谢和乙酸型顶极群落是产酸脱硫生态系统的典型特征。     

流动注射在线氢化物发生—原子荧光光谱法测定环境水样中痕量无机汞和有机汞

提出了一种流动注射在线氢化物发生—原子荧光光谱法测定水样中痕量无机汞和有机汞的分析方法。以溴化剂作为有机汞的消解剂 ,在有、无溴化剂的存在下 ,采用流动注射在线氢化物发生—原子荧光光谱法分别测定总汞和无机汞 ,差减法求出有机汞的含量。方法操作简便快速 ,灵敏度高 ,干扰少 ,经加标回收实验验证 ,回收率达 95 %～ 10 5 %。     

Rapid prediction of disinfection by-product formation potential by fluorescence

Recent drinking water regulations have lowered the disinfection by-product standards as well as added new disinfection by-products for regulation. Natural organic matter (NOM) plays a major role in the formation of undesirable organic by-products following disinfection/oxidation of drinking water. It is suspected that most precursors to disinfection by-products are humic, although nonhumic substances are also suspected of contributing to these by-products. Many of the disinfection by-products have adverse health effects in humans (i.e., carcinogenic or mutagenic effects). The primary chlorinated disinfection by-products of concern include trihalomethanes, haloacetic acids, and haloacetonitrile. Fluorescence spectroscopy was used to study humic and fulvic acids. The two fractions of humic substances, humic and fulvic acids, were characterized by a double-peak phenomena in an overlapping fluorescing region. Disinfection by-product formation potentials of humic and fulvic acids have been correlated with total organic carbon, UV absorbance at 254 nm, specific absorbance and fluorescence. River humic and fulvic acid was found to have the highest reactivity to disinfection by-product formation as compared to soil and peat humic and fulvic acid. Fluorescence spectroscopy has shown to be a rapid and predictive tool for disinfection by-products formation potential of humic and fulvic acids.     

锦州湾表层沉积物中铅、锌、镉在各地球化学相间的分配规律

研究了受重金属严重污染的锦州湾内表层沉积物中铅、锌、镉在各地球化学相间的含量,及其在湾内河水-海水混合界面附近各相间的迁移转化特征。结果表明,锦州湾表层沉积物中上述重金属以非残渣相为主要存在形式,其中铁锰氧化物为重要的清除载体;以铁锰氧化物和碳酸盐形式存在的重金属含量由水环境的E_H和pH控制;在污染源附近的海区,表层沉积物中重金属在非残渣相和残渣相间的比值与近岸锌厂排出的这些重金属在废水和废渣中的含量比呈正相关关系。     

Land use as a mitigation strategy for the water-quality impacts of global warming: a scenario analysis on two watersheds in the Ohio River Basin

This study uses an integrative approach to study the water-quality impacts of future global climate and land-use changes. In this study, changing land-use types was used as a mitigation strategy to reduce the adverse impacts of global climate change on water resources. The climate scenarios were based on projections made by the Intergovernmental Panel on Climate Change (IPCC) and the United Kingdom Hadley Centre's climate model (HadCM2). The Thornthwaite water-balance model was coupled with a land-use model (L-THIA) to investigate the hydrologic effects of future climate and land-use changes in the Ohio River Basin. The land-use model is based on the Soil Conservation Service's curve-number method. It uses the curve number, an index of land use and soil type, to calculate runoff volume and depth. The ArcView programming language, Avenue, was used to integrate the two models into a geographic information system (GIS). An output of the water-balance model, daily precipitation values adjusted for potential evapotranspiration, served as one of the inputs into the land-use model. Two watersheds were used in the present study: one containing the city of Cincinnati on the main stem of the Ohio River, and one containing the city of Columbus on a tributary of the Ohio River. These cities represent two major metropolitan areas in the Ohio River Basin with different land uses experiencing different rates of population growth. The projected hypothetical land-use changes were based on linear extrapolations of current population data. Results of the analyses indicate that conversion from agricultural land use to low-density residential land use may decrease the amount of surface runoff. The land-use practices which generate the least amount of runoff are forest, low-density residential, and agriculture; whereas high-density residential and commercial land-use types produce the highest runoff. The hydrologic soil type present was also an important factor in determining the amount of runoff and non-point-source pollution. A runoff-depth matrix and total nitrogen matrix were created for Cincinnati and Columbus to describe possible land-use mitigation measures in response to global climate change. The differences in Cincinnati and Columbus were due to differences in geographic location, air temperature, and total runoff. The results of this study may be useful to planners and policy makers for defining the possible impacts of future global climate and land-use changes on water resources.     

A/O和A2/O法除磷脱氮工艺影响因素及除磷动力学的研究

重点介绍A/O除磷工艺和A~2/O除磷脱氮工艺,以及影响除磷脱氮工艺因素和除磷动力学的研究。工艺研究采用了动态与静态实验方法,采用色质联机研究了有毒有机物的降解情况。试验结果表明,A/O、A~2/O工艺的BOD_5去除率近于二级污水处理厂,A~2/O法TP去除率近于三级污水处理厂,且去除难降解有毒有机物的效率高于传统的活性污泥法。动力学公式的修正使之更适于低碳源的情况。八种影响因素的研究为工艺的设计与运行提供了依据。     

A regional environmental management information system for Chinese EPA—the system analysis and design

REMIS is one of key research projects sponsored by the central government. It is recommended to regional EPAs as a main tool of the environmental management. REMIS simulates the functions of the regional EPAs and aimed to improve their management level. The national environmental management information system will base on REMIS.Functional analysis is the kernel of the REMIS system analysis. Data and data flow analysis are used to support the functional analysis.Investigations on the functions of the local EPAs of eight provinces and 12 cities have been taken. The functions were carefully sorted. Modular design method was used in system analysis and system design.The system analysis included functional analysis, data analysis and data flow analysis. The system design is based on the system analysis. HIPO diagram of each modular, data base structure, menu design, selection of hardware and software environment were the main items of the system design.