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Kinetics of enzymatic unhairing by protease in leather industry 总被引:2,自引:0,他引:2
In leather industry, unhairing is a heavy pollution operation. The conventional lime-sulfide process produces a large amount of sulfide which is toxic to health and difficult to dispose. Moreover, conventional lime-sulfide process leads to the destruction of the hair causing increased COD, BOD and TDS loads in the effluent. As an alternative method, enzymatic unhairing is a promising clean technology. The main utilized enzyme preparations are proteases.There are many reports about enzymatic unhairing, most of which are qualitative. The kinetics of enzymatic unhairing by protease was discussed in this article. It will provide useful information to enzymatic unhairing. In our research, by analysis of the concentrations of released total protein in enzyme bath during protease unhairing, the good linearity between released total protein and square root of time (min1/2) was obtained at the initial stage. The good linearity suggests that enzymatic unhairing by protease is a diffusion-controlled process at the initial stage. The analysis of kinetics of released saccharides also confirms the same conclusion. On the other hand, the same characteristics between the kinetics of released saccharides and that of released total protein further confirms that it is the hydrolysis of core protein by protease that leads to the degradation of proteoglycans and the release of protein and saccharides. However, in our tests, the kinetics of released collagen indicates that the injury to skin took place in 3-6 h. Therefore, it’s necessary to control the time of protease unhairing within an appropriate limit. 相似文献
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Preliminary report on methane emissions from the Three Gorges Reservoir in the summer drainage period 总被引:3,自引:0,他引:3
Fei Lu Le Yang Xiaoke Wang Xiaonan Duan Yujing Mu Wenzhi Song Feixiang Zheng Junfeng Niu Lei Tong Hua Zheng Yongjuan Zhou Jiangxiao Qiu Zhiyun Ouyang 《环境科学学报(英文版)》2011,23(12):2029-2033
Considerable variations may exist in CH4 emissions from the Three Gorges Reservoir. 相似文献
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A new type of sponge iron sphere (NSIS) with 1-5 mm diameter, made of concentrated iron powder and possessed high activity and intension, was prepared by mini-pellet sintering integrated with H2 direct reduction. Static state experiment has been carried on to investigate the Cd2+ removal efficiency from wastewater by the NSIS and to explore the Cd2+ removal reaction kinetics. It was suggested that initial pH value and Cd2+ original concentration had significant influence on Cd2+ removal percentage. Cd2+ removal percentage decreased significantly with the increasing of Cd2+original concentration whether the original pH value be adjusted to 3.0 or without adjustment. The results showed that the Cd2+ removal process followed the first order reaction because the reaction order was from 0.803 to 0.996. The apparent reaction rate constant between Cd2+ and NSIS was from 0.0025 to 0.1000 (mg·L?1)1-n·min?1. Compared with SIS reduced by charcoal reduction, NSIS deoxided by hydrogen possessed higher activity, and could remove the same quantity of Cd2+ within a shorter period of time. 相似文献
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