The Watershed Flow and Allocation Model: An NHDPlus‐Based Watershed Modeling Approach for Multiple Scales and Conditions

The Watershed Flow and Allocation model (WaterFALL^®) provides segment‐specific, daily streamflow at both gaged and ungaged locations to generate the hydrologic foundation for a variety of water resources management applications. The model is designed to apply across the spatially explicit and enhanced National Hydrography Dataset (NHDPlus) stream and catchment network. To facilitate modeling at the NHDPlus catchment scale, we use an intermediate‐level rainfall‐runoff model rather than a complex process‐based model. The hydrologic model within WaterFALL simulates rainfall‐runoff processes for each catchment within a watershed and routes streamflow between catchments, while accounting for withdrawals, discharges, and onstream reservoirs within the network. The model is therefore distributed among each NHDPlus catchment within the larger selected watershed. Input parameters including climate, land use, soils, and water withdrawals and discharges are georeferenced to each catchment. The WaterFALL system includes a centralized database and server‐based environment for storing all model code, input parameters, and results in a single instance for all simulations allowing for rapid comparison between multiple scenarios. We demonstrate and validate WaterFALL within North Carolina at a variety of scales using observed streamflows to inform quantitative and qualitative measures, including hydrologic flow metrics relevant to the study of ecological flow management decisions.     

气-质和液-质联用分析杀菌剂配方的组成、污染物及杂质

利用气-质和液相／电喷雾-质谱联用仪对商用杀菌剂进行了分析．其中,气-质联用可用于分析杀菌剂中的挥发性化合物,但是对于活性化合物,如嗪氨灵,却不能分析．电喷雾／液质联用可以分析嗪氨灵和不挥发的表面活性剂及污染物．本文介绍了气-质和液相／电喷雾-质谱联用仪用于分析商用杀菌剂,结果表明,两种技术具有互补性．     

Modeling future land cover and water quality change in Minneapolis,MN, USA to support drinking water source protection decisions

Continued alteration of the nitrogen cycle exposes receiving waters to elevated nitrogen concentrations and forces drinking water treatment services to plan for such increases in the future. We developed four 2011–2050 land cover change scenarios and modeled the impact of projected land cover change on influent water quality to support long-term planning for the Minneapolis Water Treatment Distribution Service (MWTDS) using Soil Water and Assessment Tool. Projected land cover changes based on relatively unconstrained economic growth led to substantial increases in total nitrogen (TN) loads and modest increases in total phosphorus (TP) loads in spring. Changes in sediment, TN, and TP under two “constrained” growth scenarios were near zero or declined modestly. Longitudinal analysis suggested that the extant vegetation along the Mississippi River corridor upstream of the MWTDS may be a sediment (and phosphorus) trap. Autoregressive analysis of current (2008–2017) chemical treatment application rates (mass per water volume processed) and extant (2001–2011) land cover change revealed that statistically significant increases in chemical treatment rates were temporally congruent with urbanization and conversion of pasture to cropland. Using the current trend in chemical treatment application rates and their inferred relationship to extant land cover change as a bellwether, the unconstrained growth scenarios suggest that future land cover may present challenges to the production of potable water for MWTDS.     

Suggested Guidelines for Use of Avian Species as Biomonitors

An animal’s suitability as a biomonitor of environmental change can be determined by biological, reproductive and ecological characteristics determined at the class, order and species level. The animal’s habitat where the research is to be performed and the form, function and structure of the environmental change being studied within that habitat also determines suitability. Non-threatened populations of large, non-migratory, long-lived, seasonally-breeding tertiary avian predators, whose dietary preferences are narrow and known, can be useful as monitors of environmental chemical contaminants. If chemicals are being monitored, a quantifiable endpoint effect must be demonstrated in the species, or a similar species under experimental laboratory conditions. Logistical and economic issues as well as public and regulatory authority acceptance should also be considered when assessing the suitability of a species as a biomonitor.     

Testing personal inhalable aerosol samplers: a suggested improved protocol based on new scientific knowledge

In 2002 the Comité Européen Normalisation (CEN) published its document Workplace atmospheres-assessment of performance of instruments for measurement of airborne particle concentrations (EN 13205) that describes a standard protocol by which to carry out the testing and validation of personal aerosol samplers of the type widely used for occupational aerosol exposure assessment. It emerged from more than a decade of discussion and a large body of research experience involving several laboratories. The protocol that is described, however, still poses significant technical and economic challenges, not least because it involves laborious-and hence costly-procedures in large, specialized wind tunnel facilities. More recent research has identified a number of areas by which the protocol may be improved and made more accessible to testing laboratories, including a set of validated aerosol sampler scaling laws, a better understanding of the reduced role of the bluff body of the wearer on sampler performance, and the availability of new options for rapid sampler testing methods. Taking these into account, a dummy new protocol is offered for discussion.     

The development of cryoprobe nuclear magnetic resonance spectroscopy for the rapid detection of organic contaminants in potable water

The detection of trace levels of a range of organic contaminants (including pesticides, toxins and an explosive) in potable water, using cryoprobe NMR spectroscopy with limited sample preparation and rapid acquisition times, is described. Emphasis is placed on the applicability of NMR spectroscopy for use in emergency scenarios as the unbiased nature of the technique facilitates the detection and characterization of unknown compounds at levels as low as 50 microg L(-1).     

Effect of biosurfactants on crude oil desorption and mobilization in a soil system

Microbially produced biosurfactants were studied to enhance crude oil desorption and mobilization in model soil column systems. The ability of biosurfactants from Rhodococcus ruber to remove the oil from the soil core was 1.4-2.3 times greater than that of a synthetic surfactant of suitable properties, Tween 60. Biosurfactant-enhanced oil mobilization was temperature-related, and it was slower at 15 degrees C than at 22-28 degrees C. Mathematical modelling using a one-dimensional filtration model was applied to simulate the process of oil penetration through a soil column in the presence of (bio)surfactants. A strong positive correlation (R(2)=0.99) was found between surfactant penetration through oil-contaminated soil and oil removal activity. Biosurfactant was less adsorbed to soil components than synthetic surfactant, thus rapidly penetrating through the soil column and effectively removing 65-82% of crude oil. Chemical analysis showed that crude oil removed by biosurfactant contained a lower proportion of high-molecular-weight paraffins and asphaltenes, the most nonbiodegradable compounds, compared to initial oil composition. This result suggests that oil mobilized by biosurfactants could be easily biodegraded by soil bacteria. Rhodococcus biosurfactants can be used for in situ remediation of oil-contaminated soils.     

Modeling the Spatially Varying Water Balance Processes in a Semiarid Mountainous Watershed of Idaho1

Stratton, Benjamin T., Venakataramana Sridhar, Molly M. Gribb, James P. McNamara, and Balaji Narasimhan, 2009. Modeling the Spatially Varying Water Balance Processes in a Semiarid Mountainous Watershed of Idaho. Journal of the American Water Resources Association (JAWRA) 45(6):1390‐1408. Abstract: The distributed Soil Water Assessment Tool (SWAT) hydrologic model was applied to a research watershed, the Dry Creek Experimental Watershed, near Boise Idaho to investigate its water balance components both temporally and spatially. Calibrating and validating SWAT is necessary to enable our understanding of the water balance components in this semiarid watershed. Daily streamflow data from four streamflow gages were used for calibration and validation of the model. Monthly estimates of streamflow during the calibration phase by SWAT produced satisfactory results with a Nash Sutcliffe coefficient of model efficiency 0.79. Since it is a continuous simulation model, as opposed to an event‐based model, it demonstrated the limited ability in capturing both streamflow and soil moisture for selected rain‐on‐snow (ROS) events during the validation period between 2005 and 2007. Especially, soil moisture was generally underestimated compared with observations from two monitoring pits. However, our implementation of SWAT showed that seasonal and annual water balance partitioning of precipitation into evapotranspiration, streamflow, soil moisture, and drainage was not only possible but closely followed the trends of a typical semiarid watershed in the intermountain west. This study highlights the necessity for better techniques to precisely identify and drive the model with commonly observed climatic inversion‐related snowmelt or ROS weather events. Estimation of key parameters pertaining to soil (e.g., available water content and saturated hydraulic conductivity), snow (e.g., lapse rates, melting), and vegetation (e.g., leaf area index and maximum canopy index) using additional field observations in the watershed is critical for better prediction.     

Assessment of in situ thermal treatment for chlorinated organic source zones

The East Gate Disposal Yard (EGDY) at Fort Lewis is the source of a large trichloroethene (TCE) plume at this military installation. Source reduction using thermal treatment was applied using electrical resistance heating. A total of about 5,800 kg of TCE‐equivalent volatile organic compounds (VOCs; TCE and dichloroethene) was extracted during thermal treatment of the three zones selected for source reduction. Pretreatment groundwater TCE concentrations were measured up to 100 ppm. Posttreatment groundwater TCE concentrations within the treatment zones averaged less than 100 ppb. Posttreatment soil TCE concentrations decreased by over 96 percent compared to pretreatment soil concentrations. The overall contaminant flux from EGDY was reduced by an estimated 60 to 90 percent by the source reduction effort. The traditional and new techniques for site characterization and remediation performance monitoring applied at EGDY provide insight for installing, operating, monitoring, and assessing thermal treatment. © 2009 Wiley Periodicals, Inc.     

Workplace violence intervention effectiveness: A systematic literature review

This is a systematic review of literature published since 1992, to determine the effectiveness of interventions in preventing workplace violence and to suggest interventions that need further evaluation research. The health care industry is the topic of 54% of the papers, the retail industry is the topic of 11% of the papers, and the remaining papers address the workplace in general or other situations. This finding drives the organization of this review: the first group of papers discussed in this review evaluates interventions to prevent workplace violence in the retail industry – mostly to prevent robbery and violence to retail workers. Singly or in combination, environmental designs in the retail industry, such as increased lighting to improve visibility and a limited cash-handling policy, can make workers safer, but more research is needed to overcome the barriers to implementation of environmental designs, especially in small businesses. The second group of papers in this review is about interventions to prevent violence to health care workers – mostly training and techniques of dealing with combative patients. Training health care workers to better cope with violent patients and to avoid injury is becoming standard practice, but research is needed to identify specific aspects of training and patient management programs that are most effective.