Microbial degradation of the benzonitrile herbicides dichlobenil, bromoxynil and ioxynil in soil and subsurface environments--insights into degradation pathways, persistent metabolites and involved degrader organisms

The benzonitriles dichlobenil, bromoxynil and ioxynil are important broad-spectrum or selective herbicides used in agriculture, orchards and public areas worldwide. The dichlobenil metabolite 2,6-dichlorobenzamide is the most frequently encountered groundwater contaminant in Denmark, which suggests that the environmental fate of these three structurally related benzonitrile herbicides should be addressed in detail. This review summarises the current knowledge on microbial degradation of dichlobenil, bromoxynil and ioxynil with particular focus on common features of degradation rates and pathways, accumulation of persistent metabolites and diversity of the involved degrader organisms.     

A new approach to in-situ determination of roadside particle emission factors of individual vehicles under conventional driving conditions

A method for continuous on-road measurements of particle number emissions for both diesel- and petrol-fuelled vehicles is presented. The setup allows the determination of particle number emission factors on an individual vehicle basis by the simultaneous measurement of CO₂ and particle concentrations. As an alternative to previous measurements on the kerbside, the sample is taken directly in the street, with the advantage of sampling in-situ within the exhaust plumes of passing vehicles, allowing the separation of the individual high-concentration plumes. The method was tested in two experiments that were conducted in the Gothenburg area. In the first study, which was performed at an urban roadside, we were able to determine particle emission factors from individual vehicles in a common car fleet passing the measurement site. The obtained emission factors were of the same order of magnitude (between 1.4 × 10¹² and 1.8 × 10¹⁴ particles km^?1) as values published in the recent literature for light duty vehicles. An additional on-road experiment was conducted at a rural road with four light duty reference vehicles (three of them petrol-powered and one diesel-powered) at driving speeds of 50 and 70 km h^?1, realised with different engine speeds. The results of the traffic emission studies show that the method is applicable provided that instruments with an adequate dynamic range are used and that the traffic is not too dense. In addition, the variability in particle emissions for a specified driving condition was estimated.     

A method of approach to landscape stability. Part 1: Fundamentals and methodology

A four-stage method of providing conditions for improving the stability of a landscape sector is presented. In the first stage, structure and function of the landscape system is examined, predominantly based on the results of monitoring. In the second stage, a method is suggested for applying monitoring data to a dynamic structure with complex functions of the territory under examination. In the third stage, the territory is optimized as to the function of particular components within it. The optimization consists in controlling the dynamics of the flows of material, energy, and population within the sector. In the fourth stage, the holistic function of the landscape strip should be monitored with respect to representative key factors. The entire concept is based on assuming the existence of destabilizing processes leading to ecocritical situations and determining mitigating factors using heuristic methods of optimization.     

The case for free market environmentalism

Environmental Ethics is the ethics of how we humans are to relate to each other about the environment we live in. The best way to adjust inevitable differences among us in this respect is by private property. Each person takes the best care of what he owns, and ownership entails the free market, which enables people to make mutually advantageous trades with those who might use it even better. Public regulation, by contrast, becomes management in the interests of the regulators, or of special interests, such as lovers of rare species-not the people they're supposed to be serving.     

Impacts of foreign investment on sustainable development in a Chilean mining region

The desert mining region of Antofagasta, Chile, enjoyed spectacular economic growth in the 1990s as a result of foreign direct investment (FDI), mainly in the exploitation of the region's rich copper deposits. In a country considered by international financial institutions to be a good example of economic performance, Antofagasta has been termed a model region,and Chile's economic and social development in the 1990s has been considered a suitable model for other Latin American countries. However, development indices based on statistical data must be examined with caution, as human welfare does not necessarily keep pace with economic growth. This article analyses the Antofagasta Region in terms of problems that may occur in conjunction with accelerated economic growth, and how these can affect the environment, as well as the regional labour market. The article also examines a regional economic strategy for Antofagasta recently proposed by the local government, and suggests new alternatives for the sustainable economic development of the region.     

Experience with airborne detection of radioactive pollution (ENMOS, IRIS)

This paper discusses the advantages of airborne monitoring of radioactive pollution and shows example maps indicating manmade pollution from different sources. The sensitivity of airborne radioactive detection is discussed. Comparisons of airborne and different ground measurements are presented. New instrumentation for airborne or ground moving vehicles is briefly described. Airborne footprinting provides rapid, well-defined spatial images of natural and manmade radioactive contamination. Data acquisition integrated with GPS navigation provides consistent data and guarantees proper data location. Real-time airborne measurements are re-calculated, with the use of special algorithms, into absolute units for individual radioactive nuclei contamination of the ground together with dose calculation. Raw records and calculated data are provided after enhanced post-flight processing. Dose rates and detection of different radioactive elements are presented. (ENMOS is a product of Picodas Group Inc. and IRIS is the product of Pico Envirotec Inc.)     

Summary of regulatory/policy/economic issues related to nitrogen

This is a summary of the two presentations from the session that dealt with the regulatory, policy and economic issues related to nitrogen compounds and the need to reduce their emissions. The papers were presented by Ronald Evans and Jan Willem Erisman. Information on ecological impacts of nitrogen species and atmospheric relationships are presented in other papers in this special issue. This summary provides an overview of the discussions from the above presentations.     

Brominated aromatics from combustion

The production of brominated aromatics from combustion was shown to be influenced by the operating conditions. Brominated aromatics also showed high yields compared to their chlorinated analogues.