全文获取类型
收费全文 | 200篇 |
免费 | 2篇 |
国内免费 | 4篇 |
专业分类
安全科学 | 4篇 |
废物处理 | 7篇 |
环保管理 | 15篇 |
综合类 | 17篇 |
基础理论 | 28篇 |
污染及防治 | 99篇 |
评价与监测 | 19篇 |
社会与环境 | 17篇 |
出版年
2023年 | 7篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 5篇 |
2019年 | 5篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 14篇 |
2015年 | 5篇 |
2014年 | 8篇 |
2013年 | 17篇 |
2012年 | 17篇 |
2011年 | 13篇 |
2010年 | 9篇 |
2009年 | 18篇 |
2008年 | 10篇 |
2007年 | 17篇 |
2006年 | 12篇 |
2005年 | 9篇 |
2004年 | 5篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 1篇 |
1997年 | 2篇 |
1994年 | 1篇 |
1965年 | 1篇 |
1958年 | 1篇 |
排序方式: 共有206条查询结果,搜索用时 15 毫秒
41.
Daniela Plachá Helena Raclavská Martina Kučerová Jana Kuchařová 《Waste management (New York, N.Y.)》2013,33(5):1104-1112
In this study we observed the production of volatile fatty acids (VFAs) during the composting process of compost heaps in two different bioreactors (open and closed) at three different depths (0, 40 and 80 cm). The compost was prepared as a mixture of bio-waste, horse manure, grass and sawdust to ensure sufficient pH conditions in compost heaps. VFA contents in the composting materials were analysed weekly over 14–119 d. The degradation process was monitored, along with temperature, pH, total organic carbon, oxidizable carbon and mono- and oligosaccharides. VFA contents were evaluated with regard to the depth of the sample site in the compost heap and to conditions in the bioreactors. The maximum VFA occurrence was observed during the first 35 d; acetic and propionic acids in particular were determined to occur in each sample. Considerable variations in their formation and elimination were observed in the two bioreactors as well as at the various depths in the compost heaps. Significant correlations were found between individual VFAs, as well as between VFA concentrations and organic carbon contents. 相似文献
42.
We use the contingent valuation method to measure the amount citizens are willing to pay to improve scenic mountain-view amenities through the removal of billboards. Our approach addresses both the perceived property rights as well as the perceptions of the status quo in the southern Appalachian Mountains. We find that individuals who retire to the mountains have different preferences for land use and mountain views than individuals who have ancestors who lived in Watauga County. In the aggregate, we find that citizens are willing to pay almost one-half million dollars to remove billboards from Watauga County roadsides. This study provides insights to the debate surrounding land use along public roads. 相似文献
43.
Pribylová P Klánová J Holoubek I 《Environmental pollution (Barking, Essex : 1987)》2006,144(1):248-254
Wide distribution of chlorinated paraffins in the environment has already been demonstrated in several studies; however, information about their levels in the Central Europe is still very limited. First study focused on the SCCP contamination of the Czech aquatic environment have been performed recently, and its results motivated the authors to analyze sediments from a wide set of the Czech rivers in order to obtain more detailed information. Thirty-six sediment samples from eleven rivers and five drainage vents neighboring the chemical factories were analyzed; special attention was paid to the industrial areas. For the first time in the Czech Republic, medium-chain in addition to short-chain chlorinated paraffins were analyzed using GC-ECNI-MS. Chlorinated paraffins were detected in sediment samples on the concentration levels up to 347 ngg(-1) for short-chain chlorinated paraffins, and 5575 ngg(-1) for medium-chain chlorinated paraffins. Average chlorination degree of SCCPs was 65%. 相似文献
44.
45.
Mukhopadhyay SK Biswas H De TK Sen S Jana TK 《Journal of environmental monitoring : JEM》2002,4(4):549-552
Monthly variation of CO2 fugacity (fCO2) in surface water and related atmospheric exchanges were measured in the Hooghly estuary which is one of the most important estuaries, since it is fed by one of the world's largest rivers, the Ganges with a flow of 15,646 m3 s-1 (1.6% of the world's combined river flow). Carbon dioxide fluxes averaged over the entire estuary are in the range of -2.78 to 84.4 mmol m-2 d-1. This estuary acts as a sink for CO2 during monsoon months and seasonal variation of its flux is controlled by dilution of seawater by river water. Since the solubility of CO2 and the disassociation of carbonic acid in estuarine water are controlled by temperature and salinity, the observed variations of CO2 fluxes are compared with those predicted from seasonal changes in temperature, salinity and the ratio of gross primary production to community respiration using empirical equations with an explained variability of 55%. 相似文献
46.
Jana Klánová Pavel ?upr Daniela Baráková Zdeněk Šeda Petr Anděl Ivan Holoubek 《Environmental pollution (Barking, Essex : 1987)》2009,157(12):3248-3254
Data from ten years of integrated monitoring were used here to evaluate whether pine needles are a feasible tool for an assessment of long-term trends of the atmospheric contamination. Pine needles collected once a year were compared to high volume air samples collected for 24 h, every 7 days, and passive air samples integrated over 28-day periods. Results showed the same concentration patterns of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) captured in needles and high volume samples. Passive air samplers were less efficient in sampling the particle-bound compounds. Theoretical air volume equivalent to each needle sample (VEQ) was calculated as a ratio of the needle concentration over the mean air concentration. Results indicated different equivalent volumes for PAHs and organochlorines, possibly due to the faster degradation rates of PAHs in needles. The most important finding is that in the long term a needle monitoring gives very similar information on temporal trends of the atmospheric pollution as does a high volume air monitoring. 相似文献
47.
The formation and fate of chlorinated organic substances in temperate and boreal forest soils 总被引:1,自引:0,他引:1
Nicholas Clarke Květoslava Fuksová Milan Gryndler Zora Lachmanová Hans-Holger Liste Jana Rohlenová Reiner Schroll Peter Schröder Miroslav Matucha 《Environmental science and pollution research international》2009,16(2):127-143
Background, aim and scope Chlorine is an abundant element, commonly occurring in nature either as chloride ions or as chlorinated organic compounds
(OCls). Chlorinated organic substances were long considered purely anthropogenic products; however, they are, in addition,
a commonly occurring and important part of natural ecosystems. Formation of OCls may affect the degradation of soil organic
matter (SOM) and thus the carbon cycle with implications for the ability of forest soils to sequester carbon, whilst the occurrence
of potentially toxic OCls in groundwater aquifers is of concern with regard to water quality. It is thus important to understand
the biogeochemical cycle of chlorine, both inorganic and organic, to get information about the relevant processes in the forest
ecosystem and the effects on these from human activities, including forestry practices. A survey is given of processes in
the soil of temperate and boreal forests, predominantly in Europe, including the participation of chlorine, and gaps in knowledge
and the need for further work are discussed.
Results Chlorine is present as chloride ion and/or OCls in all compartments of temperate and boreal forest ecosystems. It contributes
to the degradation of SOM, thus also affecting carbon sequestration in the forest soil. The most important source of chloride
to coastal forest ecosystems is sea salt deposition, and volcanoes and coal burning can also be important sources. Locally,
de-icing salt can be an important chloride input near major roads. In addition, anthropogenic sources of OCls are manifold.
However, results also indicate the formation of chlorinated organics by microorganisms as an important source, together with
natural abiotic formation. In fact, the soil pool of OCls seems to be a result of the balance between chlorination and degradation
processes. Ecologically, organochlorines may function as antibiotics, signal substances and energy equivalents, in descending
order of significance. Forest management practices can affect the chlorine cycle, although little is at present known about
how.
Discussion The present data on the apparently considerable size of the pool of OCls indicate its importance for the functioning of the
forest soil system and its stability, but factors controlling their formation, degradation and transport are not clearly understood.
It would be useful to estimate the significance and rates of key processes to be able to judge the importance of OCls in SOM
and litter degradation. Effects of forest management processes affecting SOM and chloride deposition are likely to affect
OCls as well. Further standardisation and harmonisation of sampling and analytical procedures is necessary.
Conclusions and perspectives More work is necessary in order to understand and, if necessary, develop strategies for mitigating the environmental impact
of OCls in temperate and boreal forest soils. This includes both intensified research, especially to understand the key processes
of formation and degradation of chlorinated compounds, and monitoring of the substances in question in forest ecosystems.
It is also important to understand the effect of various forest management techniques on OCls, as management can be used to
produce desired effects. 相似文献
48.
Bacteria associated with oak and ash on a TCE-contaminated site: characterization of isolates with potential to avoid evapotranspiration of TCE 总被引:1,自引:0,他引:1
Nele Weyens Safiyh Taghavi Tanja Barac Daniel van der Lelie Jana Boulet Tom Artois Robert Carleer Jaco Vangronsveld 《Environmental science and pollution research international》2009,16(7):830-843
Background, aim, and scope
Along transects under a mixed woodland of English Oak (Quercus robur) and Common Ash (Fraxinus excelsior) growing on a trichloroethylene (TCE)-contaminated groundwater plume, sharp decreases in TCE concentrations were observed, while transects outside the planted area did not show this remarkable decrease. This suggested a possibly active role of the trees and their associated bacteria in the remediation process. Therefore, the cultivable bacterial communities associated with both tree species growing on this TCE-contaminated groundwater plume were investigated in order to assess the possibilities and practical aspects of using these common native tree species and their associated bacteria for phytoremediation. In this study, only the cultivable bacteria were characterized because the final aim was to isolate TCE-degrading, heavy metal resistant bacteria that might be used as traceable inocula to enhance bioremediation. 相似文献49.
Gregory L. Brinkman Jana B. Milford James J. Schauer Martin M. Shafer Michael P. Hannigan 《Atmospheric environment (Oxford, England : 1994)》2009,43(12):1972-1981
Personal exposure to fine particulate matter (PM2.5) is due to both indoor and outdoor sources. Contributions of sources to personal exposure can be quite different from those observed at ambient sampling locations. The primary goal of this study was to investigate the effectiveness of using trace organic speciation data to help identify sources influencing PM2.5 exposure concentrations. Sixty-four 24-h PM2.5 samples were obtained on seven different subjects in and around Boulder, CO. The exposure samples were analyzed for PM2.5 mass, elemental and organic carbon, organic tracer compounds, water-soluble metals, ammonia, and nitrate. This study is the first to measure a broad distribution of organic tracer compounds in PM2.5 personal samples. PM2.5 mass exposure concentrations averaged 8.4 μg m?3. Organic carbon was the dominant constituent of the PM2.5 mass. Forty-four organic species and 19 water-soluble metals were quantifiable in more than half of the samples. Fifty-four organic species and 16 water-soluble metals had measurement signal-to-noise ratios larger than two after blank subtraction.The dataset was analyzed by Principal Component Analysis (PCA) to determine the factors that account for the greatest variance. Eight significant factors were identified; each factor was matched to its likely source based primarily on the marker species that loaded the factor. The results were consistent with the expectation that multiple marker species for the same source loaded the same factor. Meat cooking was an important source of variability. The factor that represents meat cooking was highly correlated with organic carbon concentrations (r = 0.84). The correlation between ambient PM2.5 and PM2.5 exposure was relatively weak (r = 0.15). Time participants spent performing various activities was generally not well correlated with PCA factor scores, likely because activity duration does not measure emissions intensity. The PCA results demonstrate that organic tracers can aid in identifying factors that influence personal exposures to PM2.5. 相似文献
50.
Mixing ratios of carbonyls and BTEX in ambient air of Kolkata, India and their associated health risk 总被引:2,自引:0,他引:2
Dutta C Som D Chatterjee A Mukherjee AK Jana TK Sen S 《Environmental monitoring and assessment》2009,148(1-4):97-107
Mixing ratios of 15 carbonyls and BTEX (benzene, toluene, ethyl benzene, xylenes) were measured for the first time in ambient air of Kolkata, India at three sites from March to June 2006 and their photochemical reactivity was evaluated. Day and nighttime samples were collected on weekly basis. Formaldehyde was the most abundant carbonyl (mean concentration ranging between 14.07 microg m(-3) to 26.12 microg m(-3) over the three sites) followed by acetaldehyde (7.60-18.67 microg m(-3)) and acetone (4.43-10.34 microg m(-3)). Among the high molecular weight aldehydes, nonanal showed the highest concentration. Among the mono-aromatic VOCs, mean concentration of toluene (27.65-103.31 microg m(-3)) was maximum, closely followed by benzene (24.97-79.18 microg m(-3)). Mean formaldehyde to acetaldehyde (1.4) and acetaldehyde to propanal ratios (5.0) were typical of urban air. Based on their photochemical reactivity towards OH. radical, the concentrations of the VOCs were scaled to formaldehyde equivalent, which showed that the high molecular weight carbonyls and xylenes contribute significantly to the total OH-reactive mass of the VOCs. Due to the toxic effect of the VOCs studied, an assessment for both cancer risk and non-cancer hazard due to exposure to the population were calculated. Integrated life time cancer risk (ILTCR) due to four carcinogens (benzene, ethyl benzene, formaldehyde and acetaldehyde) and non-cancer hazard index for the VOCs at their prevailing level were estimated to be 1.42E-04 and 5.6 respectively. 相似文献