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201.
Congener group patterns of technical short chain and medium chain chloroparaffins (SCCP and MCCP) were determined by electron capture negative ionization (ECNI) and chloride attachment chemical ionization (CACI) mass spectrometry (MS). In contrast to CACI-MS, congener patterns obtained by ECNI showed always a shift to the next higher chlorinated congener and carbon chain length group. Consequently, the calculated molecular masses and chlorine contents were higher for ECNI (factor 1.10+/-0.03 and 1.09+/-0.03, respectively). ECNI/CACI ratios in sediment samples from the North and Baltic Sea were also slightly higher. However, a more pronounced shift of the congener pattern for a given carbon chain length to congeners with 2-3 more chlorine atoms was observed. SCCP and MCCP concentrations obtained by ECNI-MS were in the range of 8-63ngg(-1) (North Sea) and 22-149ngg(-1) dry weight (Baltic Sea). MCCP levels were highest in all samples (MCCP/SCCP factor 1.1-3.2). 相似文献
202.
Passive air sampling for persistent organic pollutants: introductory remarks to the special issue 总被引:1,自引:0,他引:1
Harner T Bartkow M Holoubek I Klanova J Wania F Gioia R Moeckel C Sweetman AJ Jones KC 《Environmental pollution (Barking, Essex : 1987)》2006,144(2):361-364
There have been a number of developments in the need, design and use of passive air samplers (PAS) for persistent organic pollutants (POPs). This article is the first in a Special Issue of the journal to review these developments and some of the data arising from them. We explain the need and benefit of developing PAS for POPs, the different approaches that can be used, and highlight future developments and needs. 相似文献
203.
da Silva Joelma P. do S. Costa Maria Campina Fabia F. Bezerra Camila F. de Freitas Thiago S. Sousa Amanda K. Sobral Souza Celestina E. de Matos Yedda M. L. S. Pereira-Junior Francisco N. Menezes Irwim R. A. Coutinho Henrique D. M. Rocha Janaína E. 《Environmental geochemistry and health》2021,43(4):1609-1616
Environmental Geochemistry and Health - Mercury is widely found in nature, however, in low concentrations, but anthropological activities have increased its concentration considerably. This causes... 相似文献
204.
Jurikova Martina Dvorakova Darina Pulkrabova Jana 《Environmental science and pollution research international》2022,29(40):60341-60353
Environmental Science and Pollution Research - Drinking water is one of the main contributors to overall human exposure to per- and polyfluoroalkyl substances (PFAS), a broad group of environmental... 相似文献
205.
Niedobová Jana Ouředníčková Jana Michalko Radek Skalský Michal 《Environmental Chemistry Letters》2022,20(2):983-990
Environmental Chemistry Letters - Glyphosate is an herbicide which was previously considered safe for non-target organisms. 825.8 million kilograms of glyphosate-based products were used... 相似文献