Fast and complete removal of the 5-fluorouracil drug from water by electro-Fenton oxidation

Cytostatic drugs are a troublesome class of emerging pollutants in water owing to their potential effects on DNA. Here we studied the removal of 5-fluorouracil from water using the electro-Fenton process. Galvanostatic electrolyses were performed with an undivided laboratory-scale cell equipped with a boron-doped diamond anode and a carbon felt cathode. Results show that the fastest degradation and almost complete mineralization was obtained at a Fe²⁺ catalyst concentration of 0.2 mM. The absolute rate constant for oxidation of 5-fluorouracil by hydroxyl radicals was 1.52 × 10⁹ M^?1 s^?1. Oxalic and acetic acids were initially formed as main short-chain aliphatic by-products, then were completely degraded. After 6 h the final solution mainly contained inorganic ions (NH₄ ⁺, NO₃ ^? and F^?) and less than 10% of residual organic carbon. Hence, electro-Fenton constitutes an interesting alternative to degrade biorefractory drugs.     

Degradation of ethinyl estradiol by nitrifying activated sludge

Degradation of ethinyl estradiol (EE2) by nitrifying activated sludge was studied with micro-organisms grown in a reactor with feedback of sludge fed with only a mineral salts medium containing ammonium as the sole energy source. Ammonium was oxidised by this sludge at a rate of 50 mg NH4+ g(-1) DW h(-1). This activated sludge was also capable of degrading EE2 at a maximum rate of 1 microg g(-1) DW h(-1). Using sludge with an insignificant nitrifying capacity of 1 mg NH4+ g(-1) DW h(-1), no degradation of EE2 was detected. Oxidation of EE2 by nitrifying sludge resulted in the formation of hydrophilic compounds, which were not further identified. Most probably degradation by nitrifying sludge results in a loss of estrogenic activity, as hydroxylated derivatives of EE2 are known to have a substantially lower pharmacological activity than EE2.     

Female seed beetles, <Emphasis Type="Italic">Callosobruchus maculatus,</Emphasis> remate for male-supplied water rather than ejaculate nutrition

Female seed beetles, Callosobruchus maculatus, mate multiply even though association with males and copulations carry costs, such as injury to the genital tract. Multiple mating (polyandry) may, however, offset these costs through the acquisition of food and water, two material benefits hypothesized to be obtained from the large ejaculates produced by males. The material benefits hypothesis can be tested by increasing female access to nutrients and water, with the prediction that female mating frequency will decrease as copulation is no longer required to derive these materials. Females were given water, 5% sugar–water or baker’s yeast, and were compared with females deprived of these. We presented females with virgin males daily for 8 days and recorded female mating frequency, survivorship, and fecundity. Females provided with water and sugar–water decreased mating frequency. Thus, water, rather than nutrients in the ejaculate, appears to be important to females of this species. In addition, both life span and fecundity were extended for females in the sugar–water and water treatments. Since water is scarce in the arid environment in which this species is found, we conclude that polyandry provides material benefits to females that may offset some of the costs of associating with males.     

Habitat type-based bioaccumulation and risk assessment of metal and As contamination in earthworms, beetles and woodlice

The present study investigated the contribution of environmental factors to the accumulation of As, Cd, Cu, Pb and Zn in earthworms, beetles and woodlice, and framed within an exposure assessment of the European hedgehog. Soil and invertebrate samples were collected in three distinct habitat types. Results showed habitat-specific differences in soil and invertebrate metal concentrations and bioaccumulation factors when normalized to soil metal concentration. Further multiple regression analysis showed residual variability (habitat differences) in bioaccumulation that could not be fully explained by differences in soil metal contamination, pH or organic carbon (OC). Therefore, the study demonstrated that in bioaccumulation studies involving terrestrial invertebrates or in risk assessment of metals, it is not sufficient to differentiate habitat types on general soil characteristics such as pH and/or OC alone. Furthermore, simple generic soil risk assessments for Cd and Cu showed that risk characterization was more accurate when performed in a habitat-specific way.     

Characterizing sources of nitrate leaching from an irrigated dairy farm in Merced County, California

Dairy farms comprise a complex landscape of groundwater pollution sources. The objective of our work is to develop a method to quantify nitrate leaching to shallow groundwater from different management units at dairy farms. Total nitrate loads are determined by the sequential calibration of a sub-regional scale and a farm-scale three-dimensional groundwater flow and transport model using observations at different spatial scales. These observations include local measurements of groundwater heads and nitrate concentrations in an extensive monitoring well network, providing data at a scale of a few meters and measurements of discharge rates and nitrate concentrations in a tile-drain network, providing data integrated across multiple farms. The various measurement scales are different from the spatial scales of the calibration parameters, which are the recharge and nitrogen leaching rates from individual management units. The calibration procedure offers a conceptual framework for using field measurements at different spatial scales to estimate recharge N concentrations at the management unit scale. It provides a map of spatially varying dairy farming impact on groundwater nitrogen. The method is applied to a dairy farm located in a relatively vulnerable hydrogeologic region in California. Potential sources within the dairy farm are divided into three categories, representing different manure management units: animal exercise yards and feeding areas (corrals), liquid manure holding ponds, and manure irrigated forage fields. Estimated average nitrogen leaching is 872 kg/ha/year, 807 kg/ha/year and 486 kg/ha/year for corrals, ponds and fields respectively. Results are applied to evaluate the accuracy of nitrogen mass balances often used by regulatory agencies to assess groundwater impacts. Calibrated leaching rates compare favorably to field and farm scale nitrogen mass balances. These data and interpretations provide a basis for developing improved management strategies.     

Integrated economic-ecological analysis and evaluation of management strategies on nutrient abatement in the Rhine basin

Management of river basins involves the making of informed choices about the desired levels of economic activities and ecosystem functioning in the catchment. Information on the economic and ecological effects of measures as well as their spatial distribution is therefore needed. This paper proposes the following instruments to support decision-making in river basins: (1) the linking of models and indicators to describe the economic and ecological effects of management actions and their spatial distribution and (2) an extended evaluation framework that aims to evaluate management actions on three objectives for sustainable river management. These are cost-effectiveness, spatial equity, and environmental quality. This paper illustrates the potential of these instruments for river basin management by a case-study on nutrient management in the Rhine basin. In this case-study four nutrient abatement strategies are formulated, based on policies of the International Commission for the Protection of the Rhine and the North Sea Commission. These strategies are analysed and evaluated on their contribution to the three management objectives. Results show that none of these strategies score highest on cost-effectiveness, spatial equity and environmental quality simultaneously. It appears that cost-effectiveness is in conflict with environmental quality, whereas spatial equity and cost-effectiveness show quite close correspondence. This means that a trade-off has to be made between costs and spatial equity on the one hand, and environmental standards on the other hand. This paper offers a framework to make these trade-offs more explicit and provides quantitative information on cause-effect relationships, economic and environmental effects and the spatial distribution of these effects for various management strategies. This information can be particularly useful in the development of compromises required to establish international agreement and co-operation.     

WEST AFRICA: VOLTA DISCHARGE DATA QUALITY ASSESSMENT AND USE1

ABSTRACT: Water resource management in West Africa is often a complicated process due to inadequate resources, climatic extremes, and insufficient hydrological information. Insufficient data hinder sustainable watershed management practices, one of the top priorities in the Volta River Basin. This research properly fills in missing data by modeling the hydrological distribution in the Volta River Basin. On average, discharge gages across the basin are missing 20 percent of their monthly data over 20 years. Two methods were used to supplement missing data: a statistically linear model and a conceptual hydrological model. A linear equation, developed from the regression of precipitation and runoff, was used to evaluate the quality of existing data. The hydrological model separates the system into root and groundwater zones. Measured values were used to calibrate the hydrological model and to validate the statistical model. The quality of existing data was analyzed and organized for usability. Accuracy of the hydrological model was also evaluated for its effectiveness using R² and standard error. It was found that the hydrological model was an improvement from the linear model on a monthly basis; R² values improved by as much as 0.5 and monthly error decreased. Monthly predictions of the hydrological model were used to fill gaps of measured data sets.     

Gender aspects in the management of water

Water resources increasingly need to meet the demands and needs of different sectors and to be protected against deteriorating quantity and quality. This paper discusses the different interests of men and women in the use of water resources, and what effects the neglect of female interests in particular, has on development. The authors stress that besides class and ethnic differences, the different interests of men and women also play a role in the cross-sectoral management of water resources. Water pricing, property rights and management structures are three key aspects where a gender approach is required. In the management of water resources in smaller catchment areas, several instruments for a gender approach have been developed. Discussed are gender specific participatory research, planning and tools, gender in management organizations and task divisions and involvement of multidisciplinary teams with a gender orientation.