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471.
A process simulation of a high grade coated paper mill has been developed as part of a process integration study. Data necessary to calibrate and validate the simulation developed with the Cadsim Plus® software were obtained by: measurements, samples analysis and estimations through partial and local mass balances. The simulation was designed in a way that allows grade changes to reproduce the mill operation. The simulation is used to support process studies to optimise water and raw materials consumption and to evaluate results obtained by mathematical optimisation. Different scenarios were studied in order to evaluate the feasibility and the effects of process redesign of the mill's networks. 相似文献
472.
Florence Vouvé Leticia Cotrim da Cunha Léon Serve Jean Vigo Jean-Marie Salmon 《Chemistry and Ecology》2013,29(6):435-452
Fluorescence excitation-emission matrices showed the spectral signature of dissolved organic matter (DOM) downstream in the River Têt at all seasons corresponding to humic substances with maximum fluorescence emission λem=420–460 nm for excitations of λex=340–360 nm and the occasional presence of tryptophan, tracer of anthropogenic pressure, spectroscopically identified by λex/λem=310/350 nm. A factorial discriminant analysis, performed using the parameters selected (λex/λem pairs of wavelength), succeeded in a better discrimination of seasons than stations, and clearly showed the presence of two fluorophores. Fluorophore 1, with two absorption bands: λex=260–320 nm and 330–390 nm for λem=440–500 nm, and Fluorophore 2, with one absorption band: λex=300–360 nm for λem=410 nm, which are attributed to humic acid (HA) and fulvic acid (FA), respectively. Variations of DOM relative contents downstream in the River Têt, according to seasons and stations, showed high amounts of DOM (pedogenic character) along the river in the humid period, with the highest value obtained in the mountain section. In contrast, in summer, the DOM contents were low (aquagenic character). Moreover, DOM presents a relatively constant composition with a percentage of FA ranging from 40% at the mountain station to 48% at the mouth river, whatever the season. 相似文献
473.
474.
Laurent Goujard Pierre-Jean Roumanet Bruno Barea Yann Raoul Fabio Ziarelli Jean Le Petit Nathalie Jarroux Elisée Ferré Philippe Guégan 《Journal of Polymers and the Environment》2016,24(1):64-71
This work compares the biodegradability of polyesters produced by an esterification reaction between glycerol and oleic di-acid (D 18:1) issued from green chemical pathways, via either classical thermo-chemical methods, or an enzymatic method using the immobilized lipase of Candida antartica B (Novozym 435). An elastomeric polymer synthesized by enzymatic catalysis is more biodegradable than an elastomeric thermo-chemical polyester synthesized by a standard chemical procedure. This difference lies in percentage of the dendritic motifs, in values of the degree of substitution, and certainly in cross-links inducing an hyper-branched structure less accessible to the lipolytic enzymes in a waste treatment plant. However, when the elastomeric polymer synthesized by enzymatic catalysis is processed at high temperature as required for certain industrial applications, it presents an identical rate of biodegradation than the chemical polyester. The advantages of the thermo-chemical methods are greater speed and lower cost. Enzymatic synthesis appears be suited to producing polyesters, devoid of metallic catalysts, which must be used without processing at high temperature to keep a high biodegradability. 相似文献
475.
Stimulation of reductive dechlorination of hexachlorobenzene in soil by inducing the native microbial activity 总被引:16,自引:0,他引:16
The reductive dechlorination and behaviour of 14C-hexachlorobenzene (HCB) was investigated in an arable soil. The activity of the native anaerobic microbial communities could be induced by saturating the soil with water. Under these conditions high rates of dechlorination were observed. After 20 weeks of incubation only 1% of the applied 14C-HCB could be detected in the fraction of extractable residues. Additional organic substances, like wheat straw and lucerne straw, however considerably delayed and reduced the dechlorination process in the soil. The decline of HCB was not only caused by dechlorination but also by the formation of non-extractable residues, whereby their amounts varied with time depending on the experimental conditions. Several dechlorination products were detected, indicating the following main HCB transformation pathway: HCB → PCB → 1,2,3,5-TeCB → 1,3,5-TCB → 1,3-DCB, with 1,3,5-TCB as main intermediate dechlorination product. The other TeCB-, TCB- and DCB-isomers were also detected in low amounts, showing the presence of more than one dechlorination pathway. Since the methane production rates were lowest when the dechlorination rates were highest, it can be assumed that methanogenic bacteria were not involved in the dechlorination process of HCB. The established 14C-mass balances show, that with increasing dechlorination and incubation times, the 14C-recoveries decreased. 相似文献
476.
BACKGROUND: Motor vehicle injury is the major cause of mortality among young adults. Information about the individual characteristics of those who drive dangerously could enhance traffic safety programs. The goal of this research was to examine the association between various personality-related characteristics and risky driving behaviors. METHODS: Young adults in Michigan, USA (n = 5,362) were surveyed by telephone regarding several personality factors (risk-taking, hostility, aggression, tolerance of deviance, achievement expectations) and driving behaviors (competitive driving, risk-taking driving, high-risk driving, aggressive driving, and drink/driving). Michigan driver records were obtained to examine offenses, serious offenses, driving offense points, crashes and serious crashes in the three pre-interview years. Multivariate regression analyses, adjusting for age, race, and marital status were conducted separately by sex to identify personality factors related to driving. RESULTS: For men and women, greater risk-taking propensity, physical/verbal hostility, aggression, and tolerance of deviance were significant predictors of a competitive attitude toward driving, risk-taking driving, high-risk driving, driving aggression, and drink/driving. Greater risk-taking propensity, physical/verbal hostility, aggression, and to a small degree, expectations for achievement predicted higher numbers of offenses, serious offenses, and points. CONCLUSION: Traffic safety policies and programs could be enhanced through recognition of the role personality factors play in driving behavior and the incorporation of this knowledge into the design and implementation of interventions that modify the behaviors associated with them. 相似文献
477.
Sivak M Luoma J Flannagan MJ Bingham CR Eby DW Shope JT 《Journal of Safety Research》2007,38(3):337-355
INTRODUCTION: This article examines five major road-safety risk factors: exceeding posted speed limits, not using safety belts, driving while intoxicated, nighttime driving, and young drivers. METHOD: The importance of each of these factors is documented, known effective countermeasures (both policy and technology based) are discussed, and impediments to the implementation of these countermeasures in the United States are examined. RESULTS: Based on current understanding of the five major risk factors, and of the available countermeasures, there appear to be a variety of opportunities to make substantial gains in road safety using existing knowledge. The limited implementation of a variety of known countermeasures therefore appears to be inconsistent with high-level, strategic goals to improve road safety. Consequently, a recommendation is made to comprehensively re-examine the balance between the countermeasures discussed in this article and economic, mobility, and privacy concerns. IMPACT ON PUBLIC SAFETY: Such a re-examination is likely to result in broad support for these countermeasures, with a consequent major improvement in road safety. 相似文献
478.
Christ De Rooij Jean Charles Boutonnet Veronique Garny Andre Lecloux Roger Papp Roy S Thompson Dolf Van Wijk 《Environmental monitoring and assessment》1998,53(3):489-508
This risk assessment on tetrachloroethylene (PER) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 18 studies for fish, 13 studies for invertebrates and 8 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 51 µg/l. Most of the available monitoring data apply to rivers and estuary waters and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.2 µg PER/l water and a worst case PEC of 2.5 µg PER/l water. The calculated PEC/PNEC ratios give a safety margin of 20 to 250 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation. 相似文献
479.
Basic principles and ecological consequences of changing water regimes on nitrogen cycling in fluvial systems 总被引:8,自引:0,他引:8
Understanding the environmental consequences of changing water regimes is a daunting challenge for both resource managers
and ecologists. Balancing human demands for fresh water with the needs of the environment for water in appropriate amounts
and at the appropriate times are shaping the ways by which this natural resource will be used in the future. Based on past
decisions that have rendered many freshwater resources unsuitable for use, we argue that river systems have a fundamental
need for appropriate amounts and timing of water to maintain their biophysical integrity. Biophysical integrity is fundamental
for the formulation of future sustainable management strategies. This article addresses three basic ecological principles
driving the biogeochemical cycle of nitrogen in river systems. These are (1) how the mode of nitrogen delivery affects river
ecosystem functioning, (2) how increasing contact between water and soil or sediment increases nitrogen retention and processing,
and (3) the role of floods and droughts as important natural events that strongly influence pathways of nitrogen cycling in
fluvial systems. New challenges related to the cumulative impact of water regime change, the scale of appraisal of these impacts,
and the determination of the impacts due to natural and human changes are discussed. It is suggested that cost of long-term
and long-distance cumulative impacts of hydrological changes should be evaluated against short-term economic benefits to determine
the real environmental costs. 相似文献
480.
Marcelo Alejandro Villegas Vallejos André Andrian Padial Jean Ricardo Simões Vitule Emygdio Leite de Araujo Monteiro-Filho 《Conservation biology》2020,34(2):405-415
Terrestrial animals are negatively affected by habitat loss, which is assessed on a landscape scale, whereas secondary effects of habitat loss, such as crowding, are usually disregarded. Such impacts are inherently hard to address and poorly understood, and there is a growing concern that they could have dire consequences. We sampled birds throughout a deforestation process to assess crowding stress in an adjacent habitat remnant in the southern Brazilian Atlantic Forest. Crowding is expected of highly mobile taxa, especially given the microhabitat heterogeneity of Neotropical forests, and we hypothesized that the arrival of new individuals or species in refuges shifts assemblage patterns. We used point counts to obtain bird abundances in a before-after-control-impact design sampling of a deforestation event. Temporal changes in taxonomic and functional diversity were examined with metrics used to assess alpha and beta diversity, turnover of taxonomic and functional similarity, and taxonomic and functional composition. Over time increased abundance of some species altered the Simpson index and affected the abundance-distribution of traits in the habitat remnant. Taxonomic composition and functional composition changed in the remnant, and thus bird assemblages changed over time. Taxonomic and functional metrics indicated that fugitives affected resident assemblages in refuges, and effects endured >2 years after the deforestation processes had ceased. Dissimilarity of taxonomic composition between pre- and postdeforestation assemblages increased, whereas functional composition reverted to preimpact conditions. We found that ecological disruptions resulted from crowding and escalated into disruptions of species’ assemblages and potentially compromising ecosystem functioning. It is important to consider crowding effects of highly mobile taxa during impact assessments, especially in large-scale infrastructure projects that may affect larger areas than is assumed. 相似文献