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521.
D. Agosti C. Austin O. A. Gökçen W. A. König E. D. Morgan E. D. Scott R. Wehner 《Chemoecology》1996,7(1):57-60
Summary In all the species of theCataglyphis bicolor group examined yet, i.e.C. bicolor, C. diehli, C. isis, C. nodus, andC. viaticus, 2-methyl-1-hexanol is the characteristic substance and almost the only substance found in the mandibular glands. Its chirality has been determined inC. bicolor and shown to be exclusively (S)-2-methyl-1-hexanol. 相似文献
522.
Camila Hendges Andréia da Paz Schiller Jéssica Manfrin Eurides Kuster Macedo Jr. Affonso C. Gonçalves Jr. José Renato Stangarlin 《Journal of environmental science and health. Part. B》2019,54(4):219-225
The objective of this study was to evaluate pesticide poisonings in the southern region of Brazil between years 1999 and 2014. Data were collected from the database Sinitox. Intoxications and deaths were evaluated according to the distribution by gender (female and male), age group (≤14, 15–59 and ≥60 years), area of occurrence (urban and rural), circumstance (accident, occupational and suicide attempt) and evolution of the cases over time (cure, unconfirmed cure, death and sequelae). In the evaluated period, 21,305 cases of intoxication were registered. The results show that males between the ages of 15 and 59 years are more affected; and there is a greater representativeness in the urban area. These results are related to the application of agrochemicals being carried out by individuals between 15 and 59 years of age. The great correlation of urban area possibly occurs in function of the air currents brought from the field and as a result, population has been more affected and the consumption of contaminated food. It was observed that women handling pesticides more cautiously, in this way the accidents with male gender are more frequent, however, many women use the product intentionally to provoke suicide. 相似文献
523.
Bernardo Alves de Lima Pedro Paulo Rocha de Castro Alexandre Boscaro França Eduardo Prado Baston Renata Carolina Zanetti Lofrano Gisella Rossana Lamas Samanamud Carla Cristina Almeida Loures Luzia Lima Rezende Naves Fabiano Luiz Naves 《Environmental monitoring and assessment》2018,190(9):560
Ozone and a Fe2+/TiO2-based catalyst were examined in the degradation of a synthetic solution of benzene toluene and xylene (BTX) in an advanced oxidation process (AOP). The catalyst beads were made from the slurry waste of aluminum production process, by inserting the TiO2 content and subsequent calcination. The reduction of the BTX concentration load was monitored by the reduction of chemical oxygen demand (COD) and BTX concentration. Different levels were used on factors: pH, time of treatment, initial concentration of BTX, and percentage of TiO2. The process was conducted in a bubble column reactor with the insertion of catalyst beads. A response surface methodology technique (CCD) was used to build a model based on COD reduction results. The model was optimized using the normal-boundary intersection (NBI) algorithm to maximize COD reduction and minimize the variance attributed to the process. Optimization led to COD reductions of 80% in 2 h of experiment. Correlation analysis of coefficient models from experimental data R2adj was 0.9966, showing a good fit of model data. In the optimized conditions, the possible increase of the biodegradability ratio of the BTX solution, through the biochemical oxygen demand (BOD) and COD, was also analyzed. Under pre-treatment conditions, the BOD/COD ratio was 0.13. After the treatment, it increased to 0.56. 相似文献
524.
Jaime Paneque-Gálvez Irene Pérez-Llorente Ana Catarina Luz Maximilien Guèze Jean-François Mas Manuel J. Macía Martí Orta-Martínez Victoria Reyes-García 《Ambio》2018,47(8):908-923
It has been suggested that traditional ecological knowledge (TEK) may play a key role in forest conservation. However, empirical studies assessing to what extent TEK is associated with forest conservation compared with other variables are rare. Furthermore, to our knowledge, the spatial overlap of TEK and forest conservation has not been evaluated at fine scales. In this paper, we address both issues through a case study with Tsimane’ Amerindians in the Bolivian Amazon. We sampled 624 households across 59 villages to estimate TEK and used remote sensing data to assess forest conservation. We ran statistical and spatial analyses to evaluate whether TEK was associated and spatially overlapped with forest conservation at the village level. We find that Tsimane’ TEK is significantly and positively associated with forest conservation although acculturation variables bear stronger and negative associations with forest conservation. We also find a very significant spatial overlap between levels of Tsimane’ TEK and forest conservation. We discuss the potential reasons underpinning our results, which provide insights that may be useful for informing policies in the realms of development, conservation, and climate. We posit that the protection of indigenous cultural systems is vital and urgent to create more effective policies in such realms. 相似文献
525.
Hanxiang Wu Sophie Marhadour Zhi-Wei Lei Wen Yang Cécile Marivingt-Mounir Jean-Louis Bonnemain Jean-François Chollet 《Environmental science and pollution research international》2018,25(15):14336-14349
Producing quality food in sufficient quantity while using less agrochemical inputs will be one of the great challenges of the twenty-first century. One way of achieving this goal is to greatly reduce the doses of plant protection compounds by improving the targeting of pests to eradicate. Therefore, we developed a vectorization strategy to confer phloem mobility to fenpiclonil, a contact fungicide from the phenylpyrrole family used as a model molecule. It consists in coupling the antifungal compound to an amino acid or a sugar, so that the resulting conjugates are handled by active nutrient transport systems. The method of click chemistry was used to synthesize three conjugates combining fenpiclonil to glucose or glutamic acid with a spacer containing a triazole ring. Systemicity tests with the Ricinus model have shown that the amino acid promoiety was clearly more favorable to phloem mobility than that of glucose. In addition, the transport of the amino acid conjugate is carrier mediated since the derivative of the L series was about five times more concentrated in the phloem sap than its counterpart of the D series. The systemicity of the L-derivative is pH dependent and almost completely inhibited by the protonophore carbonyl cyanide 3-chlorophenylhydrazone (CCCP). These data suggest that the phloem transport of the L-derivative is governed by a stereospecific amino acid carrier system energized by the proton motive force. 相似文献
526.
Jéssica Manfrin Daniel Schwantes Affonso Celso Gonçalves Jr. Michelli Caroline Ferronato Valdemir Aleixo Andréia da Paz Schiller 《Environmental monitoring and assessment》2018,190(4):243
Due to intense agricultural and industrial activities, the environment has been affected by increasing amounts of pollutants, such as lead, a toxic heavy metal. When introduced to the environment, toxic metals are distributed and incorporated into the liquid medium, sediments, and aquatic biota; bioaccumulating. This research aimed to identify and quantify the levels of toxic metals present in the waters and sediments of Toledo River, compare the obtained results with legislation and other studies, as well as to evaluate the possible pollutant sources of the water body. Six water and sediment samples were taken at seven strategic sites. The concentrations of Cu, Zn, Fe, Mn, Cd, Pb, and Cr in water were compared to the maximum limits established by Brazilian legislation IN CONAMA No. 357/05, for class II fresh waters. The sediment samples were submitted to nitroperchloric digestion, and then the total concentrations of the metals were determined by flame atomic absorption spectrometry (FAAS). The toxicological quality of the Toledo River has been considerably affected by the activities carried out in its surroundings, such as extensive areas of agriculture, pig farming and industrial areas, causing concentrations of Cd, Fe, and mainly Pb, which is observed at concentrations higher than value allowed by the legislation. 相似文献
527.
Priscilla Araújo Victor Sílvia Belém Gonçalves Fabricio Machado 《Journal of Polymers and the Environment》2018,26(5):1755-1774
A modified sequential mass-suspension polymerization was employed to ensure adequate dispersion of lignin into the monomeric phase. Due to its complex macromolecular structure and low compatibility with styrene, eucalyptus wood-extracted lignin, via a modified Kraft method, was esterified with methacrylic anhydride to ensure organic phase homogeneity into the reaction medium. Infrared spectroscopy showed a decrease in the hydroxyl band, a characteristic of natural lignin (3200–3400 cm?1) and an increase in the characteristic ester band (1720–1740 cm?1) whereas nuclear magnetic resonance measurements exhibited intense peaks in the range from 1.7 to 2.05 ppm (–CH3) and 5.4 to 6.2 ppm (=CH2), related to methacrylic anhydride. Comparatively, the esterified lignin also displayed an increase of its glass transition temperature for 98?°C, related to natural lignin, whose T g was determined to be equal to 91?°C. Styrene/lignin-based polymers exhibited higher average molar masses in comparison to the values observed for polystyrene synthesized with similar amounts of benzoyl peroxide, due to the ability of lignin to act as a free-radical scavenger. Composites obtained with styrene and natural or esterified lignin were successfully synthesized, presenting regular morphology and proper lignin dispersion. Based on a very simple polymerization system, it is possible to enhance the final properties of polystyrene through the incorporation of lignin, which represents an important platform for developing attractive polymeric materials from renewable resources. 相似文献
528.
Hagen Koch Ana Lígia Chaves Silva José Roberto Gonçalves de Azevedo Werônica Meira de Souza Johann Köppel Clecio Barbosa Souza Junior Alessandra Maciel de Lima Barros Fred F. Hattermann 《Regional Environmental Change》2018,18(7):1927-1942
Many renewable resources for the generation of electricity, such as hydropower and wind power, are dependent on climatic factors. Reservoirs have been created to overcome the stochastic nature of river flows and to make water supply more reliable. However, reservoirs are affecting the ecological status of river ecosystems, e.g., by modifying the flow regime, triggering discussions regarding the discharge of reservoirs. In Brazil’s northeast region, the installed capacity for wind power generation has increased substantially in recent years. Setting up a modeling system for simulating wind power and hydropower generation in this study, it is analyzed whether wind power generation, peaking in the dry season, can help to achieve a more environmentally oriented flow regime in the Sub-middle and Lower São Francisco River Basin. Simulated higher discharges from reservoirs during the rainy season and lower discharges during the dry season, representing a more natural flow regime, will reduce hydropower generation in the dry season. Under recent conditions, the resulting gap in electricity generation can only be partially covered by wind power. A large share needs to be generated by thermal power plants or be imported from other regions in Brazil. The planned future increase in installed wind power capacity can change this picture; the demand for electricity generated by thermal power plants and imported will decrease. Adopting an integrated approach for hydropower and wind power generation, the flow regime in the Sub-middle and Lower São Francisco River Basin can be modified to improve the ecological status of the river system. 相似文献
529.
Ait-Mouheb Nassim Bahri Akiça Thayer Bechir Ben Benyahia Boumediene Bourrié Guilhem Cherki Brahim Condom Nicolas Declercq Rémi Gunes Adem Héran Marc Kitir Nurgul Molle Bruno Patureau Dominique Pollice Alfieri Rapaport Alain Renault Pierre Riahi Khalifa Romagny Bruno Sari Tewfik Sinfort Carole Steyer Jean-Philippe Talozi Samer Topcuoglu Bulent Turan Metin Wéry Nathalie Yıldırım Ertan Harmand Jérôme 《Regional Environmental Change》2018,18(3):693-705
Regional Environmental Change - Climate change and a growing population around the Mediterranean Rim are increasing the need for water and, consequently, the pressure on resources in terms of both... 相似文献
530.
Ali Fadel Bruno J. Lemaire Brigitte Vinçon-Leite Ali Atoui Kamal Slim Bruno Tassin 《Environmental science and pollution research international》2017,24(26):20934-20948
Many freshwater bodies worldwide that suffer from harmful algal blooms would benefit for their management from a simple ecological model that requires few field data, e.g. for early warning systems. Beyond a certain degree, adding processes to ecological models can reduce model predictive capabilities. In this work, we assess whether a simple ecological model without nutrients is able to describe the succession of cyanobacterial blooms of different species in a hypereutrophic reservoir and help understand the factors that determine these blooms. In our study site, Karaoun Reservoir, Lebanon, cyanobacteria Aphanizomenon ovalisporum and Microcystis aeruginosa alternatively bloom. A simple configuration of the model DYRESM-CAEDYM was used; both cyanobacteria were simulated, with constant vertical migration velocity for A. ovalisporum, with vertical migration velocity dependent on light for M. aeruginosa and with growth limited by light and temperature and not by nutrients for both species. The model was calibrated on two successive years with contrasted bloom patterns and high variations in water level. It was able to reproduce the measurements; it showed a good performance for the water level (root-mean-square error (RMSE) lower than 1 m, annual variation of 25 m), water temperature profiles (RMSE of 0.22–1.41 °C, range 13–28 °C) and cyanobacteria biomass (RMSE of 1–57 μg Chl a L?1, range 0–206 μg Chl a L?1). The model also helped understand the succession of blooms in both years. The model results suggest that the higher growth rate of M. aeruginosa during favourable temperature and light conditions allowed it to outgrow A. ovalisporum. Our results show that simple model configurations can be sufficient not only for theoretical works when few major processes can be identified but also for operational applications. This approach could be transposed on other hypereutrophic lakes and reservoirs to describe the competition between dominant phytoplankton species, contribute to early warning systems or be used for management scenarios. 相似文献