印制电路板工艺涂层防湿热、防霉菌、防盐雾试验标准的对比与分析

本文对现有标准中印制电路板工艺涂层的防湿热、防霉菌、防盐雾试验方法进行了对比,分析了各标准在标准试样制备、试验依据方法及表征参数等方面的要求,对比分析结果可为印制电路板工艺涂层三防性能验证试验方案设计提供指导。     

Reduction of Cr(VI) by malic acid in aqueous Fe-rich soil suspensions

Detoxification of Cr(VI) through reduction by organic reductants has been regarded as an effective way for remediation of Cr(VI)-polluted soils. However, such remediation strategy would be limited in practical applications due to the low Cr(VI) reduction rate. In this study, the catalytic effect of two Fe-rich soils (Ultisol and Oxisol) on Cr(VI) reduction by malic acid was evaluated. As the results shown, the two soils could obviously accelerate the reduction of Cr(VI) by malic acid at low pH conditions, while such catalytic effect was gradually suppressed as the increase in pH. After reaction for 48 h at pH 3.2, Oxalic acid was found in the supernatant of Ultisol, suggesting the oxidization of hydroxyl in malic acid to carboxyl and breakage of the bond between C₂ and C₃. It was also found that the catalytic reactivity of Ultisol was more significant than that of Oxisol, which could be partly attributed to the fact that the amount of Fe(II) released from the reductive dissolution of Ultisol by malic acid was larger than that of Oxisol. With addition of Al(III), the catalytic effect from Ultisol was inhibited across the pH range examined. On the contrary, the presence of Cu(II) would increase the catalytic effect of Ultisol, which was more pronounced with the increase in pH. This study proposed a potential way for elimination of the environmental risks posed by the Cr(VI) contamination by use of the natural soil surfaces to catalyze Cr(VI) reduction by the organic reductant such as malic acid, a kind of organic reductant originating from soil organic decomposition process or plant excretion.     

滤料粒径对给水曝气生物滤池运行稳定性的影响

利用给水曝气生物滤池(UBAF)处理刘屋洲水源水,考察了不同陶粒粒径对氨氮、高锰酸盐指数的去除效果以及水头损失变化的影响。结果表明,陶粒3～5 mm的UBAF对氨氮、高锰酸盐指数的去除效果较高,但是其水头损失较大,且反冲洗前后水头损失变化偏大,不利于UBAF稳定运行。陶粒6～10 mm的UBAF运行状况良好,氨氮的去除率为73.8%,高锰酸盐指数的去除率为18.6%,滤池24 h过滤水头损失<0.4 m,反冲洗前后过滤水头损失变化量<5 cm。其出水氨氮和高锰酸盐指数均达到《生活饮用水卫生标准》(GB5749-2006),滤池的水头损失小,反冲洗前后也变化甚微。进一步的实验表明陶粒破碎会导致滤料粒径级配变化,使得水头损失增加。     

SCR脱硝蜂窝陶瓷催化剂载体的制备

以二氧化钛、氧化铝作为主要原料,通过柱塞式挤压成型法制备了0.15 m×0.15 m×1 m规格的蜂窝陶瓷催化剂载体。通过对不同原料组成的载体性能对比,研究了各配方组分对载体性能的影响。为了提高载体活性,在21号配方的基础上加入A、B 2种商用造孔剂,考察了不同造孔剂的造孔性能。考察了蜂窝陶瓷载体负载催化剂后选择性催化还原(SCR)NO的活性,结果负载催化剂后的载体21a的在300℃时NO转化率达到最大96.5%。     

Securing water for wetland conservation: a comparative analysis of policy options to protect a national nature reserve in China

This study evaluates four policy options to secure the water supply needed for wetland conservation in Qixinghe--a national wetland nature reserve in China--using four criteria: cost effectiveness, probability of success in achieving the water-saving goal, political feasibility, and farmer acceptance. This multi-criteria analysis framework reveals the ecological, economic, and socio-political trade-offs for policymakers when choosing among the four policy options. Results suggest that upgrading irrigation infrastructure in the area surrounding the wetland (Option I) is the most politically feasible option, but it is the second best option in terms of cost effectiveness. Constructing a dam to store and control floodwater (Option II) is the most reliable for achieving the water-saving goal. It is also the farmers' most favored strategy. But this option is the least cost effective and receives little support from local governments. Promoting farmers' adoption of water-saving practices (Option III) is the most cost effective, but it is less reliable for achieving the water-saving goal than Options I or II. Converting paddy crops to dry-land crops (Option IV) is politically infeasible and least reliable for achieving the water-saving goal. The overall ranking of the four options is determined using the policymakers' revealed weights on the four criteria. Option I is ranked first, followed by Options II, III, and IV.     

补水景观湖水生态系统构建对水质的影响及因子分析

以广州市最大补水人工景观湖白云湖水生态系统构建示范区为对象,利用综合污染指数评价了以沉水植被构建为主的修复措施对示范区水体水质改善的影响,并应用因子分析法对各水质指标和生态因子之间的相互关系进行了研究。综合污染分析结果表明,恢复沉水植物后,示范区水体各项污染物浓度大幅降低,水质从V-劣V类提高到III-IV类,水体综合污染状态由严重污染改善为轻污染。因子分析显示,10项水质指标可划分为四类主因子来反映水质状况,其中,第一主因子主要反映水体营养盐指数,第二主因子反映水体有机污染指数,第三主因子反映温度变化对水质的影响,第四主因子反映水体的酸碱度;综合评分结果说明了生态系统构建后水质综合评分可大幅降低,且月评分结果呈现温度越高、水质越优的特点,水体特征呈现向草型水体发展的趋势。上述结果表明,水生态系统构建可有效改善示范区水质,是保障城市河道补水水源安全的有效方法。     

荆州市浅层地下水环境质量综合评价与分区

通过实地调查荆州市浅层地下水环境,合理选择评价指标集（16项）,分别采用模糊数学综合评价法和F值法对该浅层地下水环境质量进行综合评价,分析对比两种方法的评价结果,对浅层地下水环境进行分区和污染分析。评价结果表明：浅层地下水环境质量不容乐观,整体状况较差。浅层地下水中主要超标组分为Fe、Mn、NO-3、NO-2、As、Ba等,对比分析荆州市2006~2011年主要超标组分的平均含量,可知6 a来,Fe、Mn、NO-2的平均含量均超过地下水Ⅲ类水质标准,NO-3、As、Ba的平均含量虽然均未超过地下水Ⅲ类水质标准,但其平均含量呈现随着年份递增的趋势。浅层地下水环境质量分区结果显示：严重区面积为2 623 km2约占305%,较严重面积为1 33128 km2约占1548%,合格区面积为3 07192 km2约占3572%,较好区面积为1 5738 km2仅占183%。浅层地下水环境质量在很大程度上不仅受当地特有的区域原生地质环境影响,还与人类活动有密切关系     

Characterization of endophytic Rahnella sp. JN6 from Polygonum pubescens and its potential in promoting growth and Cd,Pb, Zn uptake by Brassica napus

Microbe-assisted phytoremediation has been considered as a promising measure for the remediation of heavy metal-polluted soils. In this study, a metal-tolerance and plant growth-promoting endophytic bacterium JN6 was firstly isolated from roots of Mn-hyperaccumulator Polygonum pubescens grown in metal-contaminated soil and identified as Rahnella sp. based on 16S rDNA gene sequence analysis. Strain JN6 showed very high Cd, Pb and Zn tolerance and effectively solubilized CdCO₃, PbCO₃ and Zn₃(PO₄)₂ in culture solution. The isolate produced plant growth-promoting substances such as indole-3-acetic acid, siderophore, 1-aminocyclopropane-1-carboxylic deaminase, and also solubilized inorganic phosphate. Based upon its ability in metal tolerance and solubilization, the isolate JN6 was further studied for its effects on the growth and accumulation of Cd, Pb and Zn in Brassica napus (rape) by pot experiments. Rape plants inoculated with the isolate JN6 had significantly higher dry weights, concentrations and uptake of Cd, Pb and Zn in both above-ground and root tissues than those without inoculation grown in soils amended with Cd (25 mg kg^?1), Pb (200 mg kg^?1) or Zn (200 mg kg^?1). The isolate also showed a high level of colonization in tissue interior of rapes. The present results demonstrated that Rahnella sp. JN6 is a valuable microorganism, which can cost-effectively improve the efficiency of phytoremediation in soils contaminated by Cd, Pb and Zn.     

移动床生物膜反应器预处理含酚废水

采用两级移动床生物膜反应器（MBBR）预处理高挥发酚含量的石化厂汽提净化水,考察了HRT和DO对废水中挥发酚和COD去除效果的影响。实验结果表明：在两级MBBR总HRT为10 h、MBBR中部废水DO 为1~3 mg/L的条件下, 装置连续运行处理ρ（挥发酚）=110~201 mg/L、COD=644~1 827 mg/L、BOD₅/COD=0.15~0.69的废水,两级MBBR处理后出水平均ρ（挥发酚）为17.6 mg/L,挥发酚去除率达87.9%;平均COD为745 mg/L,COD去除率为32.7%;出水BOD₅/COD平均为0.68,表明经过两级MBBR处理后,废水的可生化性有所提高,有利于废水的后续生化处理。     

Impact of haze and air pollution-related hazards on hospital admissions in Guangzhou,China

Guangzhou is a metropolitan in south China with unique pollutants and geographic location. Unlike those in western countries and the rest of China, the appearance of haze in Guangzhou is often (about 278 days per year on average of 4 years). Little is known about the influence of these hazes on health. In this study, we investigated whether short-term exposures to haze and air pollution are associated with hospital admissions in Guangzhou. The relationships between haze, air pollution, and daily hospital admissions during 2008–2011 were assessed using generalized additive model. Studies were categorized by gender, age, season, lag, and disease category. In haze episodes, an increase in air pollutant emissions corresponded to 3.46 (95 % CI, 1.67, 5.27) increase in excessive risk (ER) of total hospital admissions at lag 1, 11.42 (95 % CI, 4.32, 18.99) and 11.57 (95 % CI, 4.38, 19.26) increases in ERs of cardiovascular illnesses at lags 2 and 4 days, respectively. As to total hospital admissions, an increase in NO₂ was associated with a 0.73 (95 % CI, 0.11, 1.35) and a 0.28 (95 % CI, 0.11, 0.46) increases in ERs at lag 5 and lag 05, respectively. For respiratory illnesses, increases in NO₂ was associated with a 1.94 (95 % CI, 0.50, 3.40) increase in ER at lag 0, especially among chronic obstructive pulmonary disease. Haze (at lag1) and air pollution (for NO₂ at lag 5 and for SO₂ at lag3) both presented more drastic effects on the 19 to 64 years old and in the females. Together, we demonstrated that haze pollution was associated with total and cardiovascular illnesses. NO₂ was the sole pollutant with the largest risk of hospital admissions for total and respiratory diseases in both single- and multi-pollutant models.