基于ERICA的生物辐射剂量评价

电离辐射防护不仅要保护人类而且要保护非人类生物,这是辐射防护概念的一个重大变化,也是生态保护的一大重要举措。本文概述了欧盟生物辐射剂量评价方法 FASSSET的框架体系结构、参考生物和剂量学模型。本文以某内陆核电厂为例,采用ERICA方法对该核电厂水生生物的辐射影响进行了预测计算。计算结果表明,该内陆核电厂2台百万千瓦级核电机组正常运行时对水生生物的辐射剂量率低于国际组织推荐的400μGy.h-1控制限值和ERICA的筛选剂量值10μGy.h-1。因此,该内陆核电厂不会对厂址附近水域水生生物造成不利影响。ERICA方法可作为中国现阶段开展生物辐射剂量评价的推荐方法。     

流域水资源标准体系风险分析与对策

为实施流域水资源有效保护,从技术管理层面分析流域水资源共享过程中标准体系的构成与作用。对现阶段实施的生活饮用水卫生标准、地表水环境质量标准和排水标准中涵盖的有机污染物进行对称性分析,指出标准体系中存在的技术风险以及生活污水和工业废水混排存在的管理风险。以松花江流域中某化工厂排水为实例进行有机污染物成份检测,发现了标准体系对污染物监控存在的疏漏。提出从人体健康角度完善排水和水环境质量标准,从流域水资源共享角度对排水和给水设施进行整体规划和布局,从水资源安全保障角度建立流域有机污染物优先控制名单。     

锰电解行业铬钝化剂回收利用技术研究

以某电解锰工艺末端铬钝化废水为研究对象,采用氧化、除杂、反应制得成品,污水达标处理及回用的组合工艺,制备达到国家标准的中铬黄产品,以实现铬的回收利用。结果表明:对于H2O2氧化工艺,选用V(水样)/V(30%H2O2)为(600～1000):1;可采取加碱沉淀Mn的工艺去除杂质金属离子;铬酸铅的生成反应适宜温度为55～60℃,硝酸铅投加量为理论值的1.05倍～1.10倍;采取加石灰调pH、投加硫酸铝的方法可去除水样中剩余铅离子,V(上清液)/V(5%硫酸铝溶液)为1000～2000较合适;生产该产品基本上能够做到保本、微利,但具有显著的环境效益和社会效益。     

Source and deposition of polycyclic aromatic hydrocarbons to Shanghai, China

Despite recent efforts to investigate the distribution and fate of polycyclic aromatic hydrocarbons (PAHs) in air, water, and soil, very little is known about their temporal change in wet deposition. As a result of increased attention to public health, a large-scale survey on the deposition flux and distribution of PAH contamination in rainwater was urgently conducted in Shanghai, China. In this study, 163 rainwater samples were collected from six sites, and 15 PAH compounds were detected by the use of a simple solid phase microextraction (SPME) technique coupled with gas chromatography-mass spectrometry. The dominant PAH species monitored were naphthalene, phenanthrene, anthracene, and fluoranthene. The concentration of total PAHs per event was between 74 and 980 ng/L, with an average value of 481 ng/L, which is at the high end of worldwide figures. The annual deposition flux of PAHs in rainwater was estimated to be 4148 kg/yr in the Shanghai area, suggesting rainfall as a major possible pathway for removing PAHs from the atmosphere. Diagnostic analysis by the ratios of An/178 and Fl/Fl+Py suggested that combustion of grass, wood, and coal was the major contributor to PAHs in the Shanghai region. Back trajectory analysis also indicated that the pollutant sources could be from the southern part of China.     

徐州市生态市建设存在的问题及对策探讨

分析了徐州市在建设生态城市中所面临的问题,从生态环境的管理和保护、循环经济的发展、城市基础设施的改造、城市绿化系统的建设等方面提出了相应的建议和措施,为生态城市的建设提供依据和借鉴。     

A land use regression for predicting NO2 and PM10 concentrations in di erent seasons in Tianjin region, China

Land use regression (LUR) model was employed to predict the spatial concentration distribution of NO2 and PM10 in the Tianjin region based on the environmental air quality monitoring data. Four multiple linear regression (MLR) equations were established based on the most significant variables for NO2 in heating season (R2 = 0.74), and non-heating season (R2 = 0.61) in the whole study area; and PM10 in heating season (R2 = 0.72), and non-heating season (R2 = 0.49). Maps of spatial concentration distribution for NO2 and PM10 were obtained based on the MLR equations (resolution is 10 km). Intercepts of MLR equations were 0.050 (NO2, heating season), 0.035 (NO2, non-heating season), 0.068 (PM10, heating season), and 0.092 (PM10, non-heating season) in the whole study area. In the central area of Tianjin region, the intercepts were 0.042 (NO2, heating season), 0.043 (NO2, non-heating season), 0.087 (PM10, heating season), and 0.096 (PM10, non-heating season). These intercept values might imply an area’s background concentrations. Predicted result derived from LUR model in the central area was better than that in the whole study area. R2 values increased 0.09 (heating season) and 0.18 (non-heating season) for NO2, and 0.08 (heating season) and 0.04 (non-heating season) for PM10. In terms of R2, LUR model performed more e ectively in heating season than non-heating season in the study area and gave a better result for NO2 compared with PM10.     

Characterization of personal exposure concentration of fine particles for adults and children exposed to high ambient concentrations in Beijing, China

In China, the health risk from overexposure to particles is becoming an important public health concern. To investigate daily exposure characteristics to PM 2.5 with high ambient concentration in urban area, a personal exposure study was conducted for school children, and office workers in Beijing, China. For all participants (N = 114), the mean personal 24-hr exposure concentration was 102.5, 14.7, 0.093, 0.528, 0.934, 0.174 and 0.703 μg/m 3 for PM 2.5 , black carbon, Mn, Al, Ca, Pb, and Fe. Children's exposure concentrations of PM 2.5 were 4-5 times higher than those in related studies. The ambient concentration of PM 2.5 (128.5 μg/m 3 ) was significantly higher than the personal exposure concentration (P 0.05), and exceed the reference concentration (25 μg/m 3 ) of WHO air quality guideline. Good correlation relationships and significant differences were identified between ambient concentration and personal exposure concentration. The relationships indicate that the ambient concentration is the main factor influencing personal exposure concentration, but is not a good indicator of personal exposure concentration. Outdoor activities (commute mode, exposure to heating, workday or weekend travel) influenced personal exposure concentrations significantly, but the magnitude of the influence from indoor activities (exposure to cooking) was masked by the high ambient concentrations.     

重庆主城区流域邻苯二甲酸酯生态风险评价

以长江、嘉陵江重庆主城区段为研究水域,利用Agilent6890N气相色谱仪对丰水期该研究水域12个采样点水体中五种邻苯二甲酸酯（PAEs）含量进行测定,分析了PAEs在该区域水体中丰水期的分布特征并进行了生态安全评价。结果表明：丰水期水体中∑PAEs的浓度范围为0.87μg/L-55.66μg/L;DBP与DEHP为优先污染物,其浓度范围在0.15μg/L-28.32μg/L与0.26μg/L-26.29μg/L;按商值法对PAEs进行生态安全评价,DMP、DEP对该水域中水生动植物无生态风险,DBP和DEHP存在潜在低风险。     

泡沫-细水雾对变压器油池火的冷却及热辐射阻隔特性研究

泡沫-细水雾在全尺寸变压器灭火实验中展现出高效灭火性能。纯水细水雾具有冷却效果好、热辐射阻隔能力强的特点,但添加泡沫灭火剂后对其冷却及热辐射阻隔特性的影响机制尚不明确。对泡沫-细水雾和纯水细水雾的冷却与热辐射阻隔特性进行了对比实验,并基于雾特性测试结果对相应性能的差异进行了分析。发现添加泡沫灭火剂后能降低水雾的粒径,从而令泡沫-细水雾的冷却和热辐射阻隔性能优于纯水细水雾。此外,泡沫灭火剂中的阻燃物质也是加速火焰熄灭的重要因素。研究结果可为变压器灭火系统选择、泡沫-细水雾系统工况参数优化等方面提供理论指导。