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针对燃煤电厂汞污染物排放控制的问题, 以尿素为前驱体, 通过直接热聚合法制得绒毛状石墨相氮化碳(g-C3N4), 并用于低温条件下吸附脱除单质汞(Hg0)。利用透射电子显微镜(TEM)、X射线衍射(XRD)、氮气吸附-脱附、X射线光电子能谱(XPS)等手段对吸附剂进行表征。结果表明:未改性g-C3N4具有良好的低温脱汞活性, 在120 ℃时其脱汞效率可达84.7%;CuCl2改性可以有效提高g-C3N4的脱汞性能, 其脱汞效率在40~200 ℃范围内均可达到97%以上; 温度对吸附剂脱汞效率的影响较小。XPS表征测试结果表明, 铜离子和共价态氯原子均参与了单质汞的吸附脱除反应, Hg0被Cu2+离子和共价态Cl原子氧化成了Hg2+离子, 再吸附于g-C3N4表面而脱除。CO2、SO2和水蒸气对吸附剂脱汞效率影响较小, 但水蒸气可提高汞吸附量。 相似文献
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Zeng Fabin Jiang Zhongan Wang Yapeng 《Environmental science and pollution research international》2023,30(1):606-621
Environmental Science and Pollution Research - The impact airflow generated by ore unloading in the chute raises the dust carried by the ore itself and the floating dust, and then, the dust raised... 相似文献
176.
Modeling Large Fire Frequency and Burned Area in Canadian Terrestrial Ecosystems with Poisson Models
Yueyang Jiang Qianlai Zhuang Daniel Mandallaz 《Environmental Modeling and Assessment》2012,17(5):483-493
Large wildland fires are major disturbances that strongly influence the carbon cycling and vegetation dynamics of Canadian boreal ecosystems. Although large wildland fires have recently received much scrutiny in scientific study, it is still a challenge for researchers to predict large fire frequency and burned area. Here, we use monthly climate and elevation data to quantify the frequency of large fires using a Poisson model, and we calculate the probability of burned area exceeding a certain size using a compound Poisson process. We find that the Poisson model simulates large fire occurrence well during the fire season (May through August) using monthly climate, and the threshold probability calculated by the compound Poisson model agrees well with historical records. Threshold probabilities are significantly different among different Canadian ecozones, with the Boreal Shield ecozone always showing the highest probability. The fire prediction model described in this study and the derived information will facilitate future quantification of fire risks and help improve fire management in the region. 相似文献
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Kong S Lu B Ji Y Zhao X Bai Z Xu Y Liu Y Jiang H 《Journal of environmental monitoring : JEM》2012,14(3):791-803
15 road and 14 soil dust samples were collected from an oilfield city, Dongying, from 11/2009-4/2010 and analyzed by inductively coupled plasma-mass spectroscopy (ICP-MS) for V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb within PM(2.5), PM(10) and PM(100) fractions synchronously. Metal concentrations, sources and human health risk were studied. Results showed that both soil and road dust exhibited higher values for Mn and Zn and lower values for Co and Cd for the three fractions. Mass concentration ratios of PM(2.5)/PM(10) and PM(10)/PM(100) for metals in road and soil dust indicate that most of the heavy metals tend to concentrate in fine particles. Geoaccumulation index and enrichment factors analysis showed that Cu, Zn and Cd exhibited moderate or heavy contamination and significant enrichment, indicating the influence of anthropogenic sources. Vanadium, Cr, Mn and Co were mostly not enriched and were mainly influenced by crustal sources. For Ni, As and Pb, they ranged from not enriched to moderately enriched and were influenced by both crustal materials and anthropogenic sources. The conclusions were confirmed by multivariate analysis methods. Principle component analysis revealed that the major sources were vehicle emission, industrial activities, coal combustion, agricultural activities and crustal materials. The risk assessment results indicated that metal ingestion appeared to be the main exposure route followed by dermal contact. The most likely cause for cancer and other health risks are both the fine particles of soil and road dusts. 相似文献
178.
Species immigration history can structure ecological communities through priority effects, which are often mediated by competition. As competition tends to be stronger between species with more similar niches, we hypothesize that species phylogenetic relatedness, under niche conservatism, may be a reasonable surrogate of niche similarity between species, and thus influence the strength of priority effects. We tested this hypothesis using a laboratory microcosm experiment in which we established bacterial species pools with different levels of phylogenetic relatedness and manipulated the immigration history of species from each pool into microcosms. Our results showed that strong priority effects, and hence multiple community states, only emerged for the species pool with the greatest phylogenetic relatedness. Community assembly also resulted in a significant positive relationship between bacterial phylogenetic diversity and ecosystem functions. Interestingly, these results emerged despite a lack of phylogenetic conservatism for most of the bacterial functional traits considered. Our results highlight the utility of phylogenetic information for understanding the structure and functioning of ecological communities, even when phylogenetically conserved functional traits are not identified or measured. 相似文献
179.
Jiang Rurong Ren Fang Yao Jinhua 《Environmental science and pollution research international》2022,29(45):68087-68095
Environmental Science and Pollution Research - Alkyl polyglycosides (APG), a biodegradable biosurfactant, have been widely used in environmental pollution control. However, the application of APG... 相似文献
180.
Zuo Xu Nie Jianxin Jiang Beier Jiang Aijun Zou Shiyang Wu Junrong Ding Bingquan Wang Xue hui Liu Yang 《Environmental science and pollution research international》2022,29(50):75597-75608
Environmental Science and Pollution Research - Advanced oxidation processes (AOPs) are efficient methods for water purification. However, there are few studies on using peroxymonosulfate (PMS) to... 相似文献