Co3O4/BiVO4复合阳极活化过一硫酸盐强化光电催化降解双酚A

采用静电纺丝法制备了Co_3O_4/BiVO_4复合薄膜电极,并以之为光阳极,在过一硫酸盐(PMS)辅助作用下开展了光电催化降解双酚A研究.结果表明,PMS在可见光下可显著强化Co_3O_4/BiVO_4复合阳极光电催化降解双酚A,在0.25 V外加偏压以及可见光照射下,当加入2 mmol·L-1PMS时,双酚A在2 h内的降解效率为96%.降解动力学常数为0.471 4 min-1.系统研究了PMS初始浓度、外加偏压对双酚A降解性能的影响.结果发现,双酚A在较低的PMS投加量和较低的外加偏压(0.25 V)下即可有效降解.采用电子自旋共振波谱仪鉴定体系的主要活性自由基为SO·-4和·OH.并进一步通过淬灭实验结果证明空穴、SO·-4和·OH起主要氧化作用.光电反应后的体系中未检测到金属离子溶出,可避免二次污染.     

Application of Tradable Emission Permits in Europe

Abstract

The purpose of this study is merely to review the current situation in the designing and implementation of the emission trading programs in Europe. Historical data show that although there is a series of shortcomings in their current functioning, employing such instruments for GHG reduction policy making is strongly expected to be efficient and effective. The European Union Emission Trading Scheme (EU ETS), Clean Development Mechanism (CDM) and Joint Implementation (JI) are just a few examples of the ambitious EU initiative that heavily relies on such instruments. We dwell on their operations and achievements by far and all the content in this article is expected to convince the Chinese government and regional public authorities to take positive actions and attitudes in promoting these instruments.     

Runoff variation affected by precipitation change and human activity in Hailiutu River basin,China

For recent years, runoff generation and hydrological processes in Hailiutu River basin have been greatly changed by climate change and human activity, especially water and soil conservation construction. In this study, the trends in precipitation, evapotranspiration (ET) and river runoff as well as the effects of precipitation change and human activity on runoff variation have been studied. The results showed that during 1960–2000, annual precipitation and river runoff, monthly precipitation and ET in September and October as well as monthly runoff in all months showed a significant decrease. In addition, peak flow and base flow had a large decrease. Under the joint influence of precipitation change and human activity, the mean annual runoff decreased by 35 million m³ from the baseline period (1960–1985) to the change period (1986–2000), which accounted for 60.9% and 39.1% of the total runoff decrease, respectively. Precipitation change played a primary role in the decrease of annual runoff whereas human activity, particularly water and soil conservation construction, also had remarkable impacts on runoff variation.     

长江上游向家坝库区鸟类多样性研究及生境价值评估

2011年利用样线法对长江上游向家坝库区夏、秋季鸟类进行了实地考察,共记录110种鸟类,隶属15目39科。通过5个调查点、2个对照点不同生境鸟类的多样性研究发现：（1）夏、秋季库区不同生境鸟类的Shannon Wiener 指数较低,几乎均未超过1.5,鸟类物种多样性相对贫乏;（2）库区各生境鸟类Pielou指数均超过了0.75,说明库区环境虽以人工植被为主,但并不单调;（3）阶地疏林灌丛、竹林与常绿落叶阔叶混交林的鸟类相似性差异最小〖JP2〗,而二者与芦苇、荩草丛滩地的差异最大,库区鸟类在不同生境中的分布存在着显著不同。在上述研究的基础上,从物种多样性和河流景观保护的角度,对库区鸟类的不同生境类型进行多要素综合分析,结果显示: 山地森林生境的物种多样性相对丰富,生态价值最高,而河滩和阶地疏林灌丛、竹林生境具备一定的景观特色,也有相当的生态价值     

基于耕作半径分析的县域农村居民点空间布局优化——以安徽省埇桥区为例

分析了安徽省埇桥区农村居民点与耕地的空间邻接特征和数量结构关系,通过“均等”和“耕聚比”的方法分别求算耕作半径并构造缓冲区,得出两种耕作压力系数的分布,对其进行比较并提出了农村居民点布局优化策略。结果表明：耕地是皖北平原地区影响农村居民点布局的主要因子,基于各乡（镇）统计的耕地与农村居民点面积存在较好的线性相关;基于“耕聚比”的计算模型较好地解决了农村居民点规模因素对耕作半径计算造成的影响;基于“耕聚比”的方法计算的耕作压力分布在评价耕地与农村居民点的分布合理性上更为实用;耕作压力系数分布对农村居民点合理布局具有一定的指导意义,布局调整中应将压力系数高的地区的拆旧和压力系数低的地区的建新相挂钩     

汉江上游郧县曲远河河口段全新世古洪水水文状态研究

对汉江上游河谷郧县曲远河河口剖面进行了沉积学、粒度、磁化率和烧失量的研究。结果表明：夹在古土壤中的灰白色沉积层是典型的古洪水滞流沉积物,记录了一次特大洪水事件,用地层对比法和OSL方法确定其发生时间为4 950~5 450 a B.P.。用古洪水SWD尖灭点法确定古洪水行洪水位高程为169 m,采用比降法恢复其洪峰流量为60 577 m3/s。根据2011年汉江上游洪水洪痕,用相同的方法对洪峰流量进行了反演,误差为-411％,说明用比降法恢复的古洪水洪峰流量是可靠的     

Function of Agricultural Land Use and Its Evolvement in Peri-urban Area: A Case Study of Beijing

Abstract

Rapid urbanization in Beijing stimulates the urban land expansion and diminishes available agricultural land. Monofunctional agricultural land use can not meet the demand of the development of the multifunctional agriculture and urbanization any more, so multifunctional agricultural land use is going to be promoted in the city. This article proposes the evolvement of the land use change from 1992 to 2004 and discusses some evolvement views.     

Chemisorption and Physical Adsorption Roles in Cadmium Biosorption by Chlamydomonas Reinhardtii

The aim of this study was to investigate the mechanism of cadmium (Cd) adsorbed by microalgae Chlamydomonas reinhardtii (C.reinhardtii). The kinetic and adsorption isotherm of the process could be well described by mathematical models. Chemical modification experiments and Fourier transform infrared spectra indicated that carboxyl and amine groups were the important functional groups for adsorption of Cd. The maximum contribution of physical adsorption in the overall adsorption process was evaluated as 5.5%...     

自然资源、技术进步与环境库兹涅茨曲线

不可再生自然资源的约束和环境质量的不断恶化是经济可持续发展必须要面对的挑战。就环境问题而言,现实中一个特征事实是,在不同的收入水平下人们对环境质量的需求不同,只有当收入达到一定水平之后,人们才会注重生活质量的改善。基于现有研究,在考虑非再生自然资源的约束条件下,本研究将环境质量作为生产要素的一部分引入最优增长理论的分析框架,探讨了在环境污染和自然资源双重约束下的长期经济增长问题。在非再生自然资源和环境污染的双重约束下,本研究表明解决环境问题必须要采用的手段是促使技术进步的创新研发,因为技术进步是环境库兹涅茨曲线出现拐点的不可或缺的一个必要条件。在市场竞争的环境下,由于知识的非竞争性质使得研究部门的研究是次优的。因此,政府应当通过适当的财政政策和法制安排以激励私人投资者研究与开发新技术的积极性。     

电除尘器电源交流分量对PM_(2.5)等细微颗粒物除尘效率的影响

除尘器对颗粒物的除尘效率与颗粒物的荷电量密切相关,PM2.5等细小颗粒物由于其荷电量不足而导致其吸收效率较低,对环境造成危害。为了增加粒子的荷电量,以粒子荷电原理为理论依据,从离子电流密度和通过电凝并扩大尘粒中位径2个方面研究了电除尘电源中交流电压分量对PM2.5等细小颗粒物荷电特性的影响,得出了电除尘器电源中交流电压分量可从以上2个方面提高装置对PM2.5等微小颗粒物的荷电量,且频率越高,幅值越大,荷电效果越好,从而可以提高装置对细小颗粒物的除尘效率。