PH玻璃电极对比观测及误差研究

经过对PH玻璃电极对比观测实验，总结其在日常观测中衰减变化规律，以及PH电极失效前所具有的特征；讨论了对现有PH观测数据进行修正的方法，并编著相关修正程序；分析日常存在的测量误差，提出提高观测精度的措施。     

苏州市经济发展与环境污染耦合关系的实证研究

选取苏州市1990-2004年经济与环境数据, 通过分析经济因子与环境因子相互关系,探究苏州市经济增长与环境质量演替轨迹,建立经济增长与环境污染水平计量模型.根据模型结果分析了苏州市环境库兹涅茨曲线的特征及产生的原因,并提出了相应的改进建议.实证研究表明,苏州市部分环境指标与人均GDP演替轨迹呈现一定的环境库兹涅茨曲线特征,但大部分环境指标尚未达到转折点.产生这种现象的主要原因是产业结构的不合理.     

Integrated assessment for aerobic biodegradability of organic substances

In this paper, the amount of oxygen consumption, end products and activities of microorganisms are considered as the three factors which affect the biodegradability of organic substances in water. Two integrated assessment methods for biodegradability of organic substances, fuzzy clustering integrated assessment and weighted integrated assessment, have been developed. Simultaneously, the detail steps for assessing a new organic substance biodegradability with these two integrated assessment methods are proposed.     

The influence of pH on the degradation of phenol and chlorophenols by potassium ferrate

This paper presents information concerning the influence of solution pH on the aqueous reaction between potassium ferrate and phenol and three chlorinated phenols: 4-chlorophenol (CP), 2,4-dichlorophenol (DCP), 2,4,6-trichlorophenol (TCP). The redox potential and aqueous stability of the ferrate ion, and the reactivity of dissociating compounds, are known to be pH dependent. Laboratory tests have been undertaken over a wide range of pH (5.8-11) and reactant concentrations (ferrate:compound molar ratios of 1:1 to 8:1). The reactivity of trichloroethylene was also investigated as a reference compound owing to its non-dissociating nature. The extent of compound degradation by ferrate was found to be highly pH dependent, and the optimal pH (maximum degradation) decreased in the order: phenol/CP, DCP, TCP; at the optimal pH the degree of degradation of these compounds was similar. The results indicate that for the group of phenol and chlorophenols studied, the presence of an increasing number of chlorine substituent atoms corresponds to an increasing reactivity of the undissociated compound, and a decreasing reactivity of the dissociated compound.     

Progress in developing an ANN model for air pollution index forecast

An air pollution index (API) reporting system is introduced to selected cities of China for public communication on air quality data. Shanghai is the first city in China providing daily average API reports and forecasts. This paper describes the development of an artificial neural network (ANN) model for the API forecasting in Shanghai. It is a multiple layer perceptron (MLP) network, with meteorological forecasting data as the main input, to output the next day average API values. However, the initial version of the MLP model did not work well. To improve the model, a series of tests were conducted with respect to the training method and structure optimization. Based on the test results, the training algorithm was modified and a new model was built. The new model is now being used in Shanghai for API forecasting. Its performance is shown reasonably well in comparison with observation. The application of the old model was only weakly correlated with observation. In 1-year application, the correlation coefficients were 0.2314, 0.1022 and 0.1710 for TSP, SO₂ and NO_x, respectively. But for the new model, for over 8 months application, the correlation coefficients are raised to 0.6056, 0.6993 and 0.6300 for PM₁₀, SO₂, and NO₂. Further, the new algorithm does not rely on manpower intervention so that it is now being applied in several other Chinese cities with quite different meteorological conditions. The structure of the model and the application results are presented in this paper and also the problems to be further studied.     

农药污染地下水的微生物治理及含水层渗透性变化研究

采用了从农药厂阿特拉津生产车间排污口污泥中分离出的菌种AT菌 ,进行了农药阿特拉津污染地下水微生物治理的模拟实验研究 ,在实验条件 (T =10℃ ,pH =7.5 )与野外含水层的条件基本一致情况下 ,难于生物降解的污染质阿特拉津的一次投菌降解率可达 3 1.0 8% ;设计了两种有效细菌的投放方式以模拟野外条件下的菌种投加条件。另外 ,AT菌的作用会造成被治理含水层的渗透性能降低 ,两种投菌方式下 ,实验后含水层的渗透系数分别下降 60 .5 4%和 3 4 5 6%。清水冲洗 10d的渗透性恢复率分别为 48.96%及 81.3 6% ,说明清水渗透恢复的方法效果明显     

微波加热对活性炭表面基团及其对SO2吸附性能的影响

采用了微波加热技术,通过在不同微波功率和辐射时间条件下对不同粒径活性炭进行改性,研究了改性前后活性炭的表面化学基团、元素组成的变化,以及对SO2吸附性能的影响.结果表明,经过微波改性后活性炭的SO2吸附性能大为提高,微波功率是影响改性活性炭脱硫性能的主要因素.活性炭经微波热处理后,酸性基团发生分解,表面含氧量减少,碱性特征增强,是吸附性能增加的主要原因之一.     

油泥废弃物的生物修复技术研究

本文利用正交试验 ,探讨了堆腐法处理油泥废弃物过程中调控因子 (肥料、客土、水分和 pH)的影响。结果发现 ,投加一定量的客土是影响处理效果的重要因子。通过正交试验选择和确定的最佳处理条件为 :在自然温度 >2 0℃的情况下 ,客土投加量 2 0 %、肥料 10 %、菌剂 5 %、控制水分 30 % (烘干基 )和pH 7。优化条件的建立为油泥废弃物的深度处理提供了理论依据     

预处理对城市固体有机垃圾厌氧发酵的影响

对近年来城市固体有机垃圾厌氧消化的各种预处理技术和发展趋势进行了综合分析和评述.研究认为,通过预处理能够改善城市固体有机物的物化性质,提高微生物对难降解有机物的降解,优化垃圾的厌氧消化过程.     

骆马湖水体氮污染特征分析

2005年通过对骆马湖水质监测，并结合近几年的监测资料进行了分析，结果表明，氮是骆马湖水体的主要污染物，包括总氮、氨氮和硝酸盐氮，其主要特征是入湖河流、降水、围网养殖和点源带来的污染。