Assessment of the Effectiveness of Environmental Dredging in South Lake,China

Environmental dredging is a primary remedial option for removal of the contaminated material from aquatic environment. Of primary concern in environmental dredging is the effectiveness of the intended sediment removal. A 5-year field monitoring study was conducted to assess the effectiveness of the environmental dredging in South Lake, China. The concentrations of total nitrogen (TN), total phosphors, and heavy metals (Zn, Pb, Cd, Cu, Cr, Ni, Hg, and As) before and after dredging in sediment were determined and compared. Multiple ecological risk indices were employed to assess the contamination of heavy metals before and after dredging. Our results showed that the total phosphorus levels reduced 42% after dredging. Similar changes for Hg, Zn, As Pb, Cd, Cu, Cr, and Ni were observed, with reduction percentages of 97.0, 93.1, 82.6, 63.9, 52.7, 50.1, 32.0, and 23.6, respectively, and the quality of sediment improved based on the criterion of Sediment Quality Guidelines by USEPA and contamination degree values (C_d) decreased significantly (paired t-test, p < 0.05). Unexpectedly, the TN increased 49% after dredging compared to before dredging. Findings from the study demonstrated that the environmental dredging was an effective mechanism for removal of total phosphorus and heavy metals from South Lake. Nevertheless, the dredging was ineffective to remove total nitrogen from sediment. We conclude that the reason for the observed increase in TN after dredging was likely ammonia release from the sediment impairing the dredging effectiveness.     

不同施肥方式对东北旱田黑土nirK和nirS型反硝化细菌群落结构的影响及黑土保护建议

反硝化过程是土壤氮素循环的重要过程之一,与土壤氮肥损失和温室气体排放紧密相关。通过分析不同施肥方式对东北旱田黑土nirK型和nirS型反硝化细菌群落结构的影响及其与N₂O排放的关系,证实黑土中nirK型比nirS型反硝化细菌多样性丰富,且更易受土壤理化性质的影响。施入化肥会降低东北旱田黑土反硝化细菌多样性、N₂O释放量和土壤养分含量,而有机肥的施入虽然可提高土壤养分含量,但是也会显著增加土壤反硝化作用,存在潜在的负面环境效应。因此对黑土地的保护要积极推行种养结合,建立可循环农业体系;适当配施有机肥料,调节黑土微生物活力;大力完善相关制度,营造科学管理新规范,从而构建我国黑土保护的立体格局。     

Cultivar-dependent rhizobacteria community and cadmium accumulation in rice: Effects on cadmium availability in soils and iron-plaque formation

The association between the rhizospheric microbial community and Cd accumulation in rice is poorly understood. A field trial was conducted to investigate the different rhizobacterial communities of two rice cultivars with high Cd accumulation (HA) and low Cd accumulation (LA) at four growth stages. Results showed that the Cd content in the roots of the HA cultivar was 1.23 - 27.53 higher than that of the LA cultivar (0.08 - 10.5 µg/plant) at four stages. The LA cultivar had a significantly lower Cd availability in rhizosphere and a higher quantity of iron plaque (IP) on the root surface than the HA cultivar at four stages. This resulted in the reduction of Cd concentration in IPs and Cd translocation from IP-to-root. Microbial analysis indicated that the LA cultivar formed a distinct rhizobacterial community from the HA cultivar and had less α-diversity. The rhizosphere of the LA cultivar was enriched in specific bacterial taxa (e.g., Massilia and Bacillus) involved in Cd immobilization by phosphate precipitation and IP formation by iron oxidization. However, the rhizosphere in the HA cultivar assembled abundant sulfur-oxidizing bacteria (e.g., Sulfuricurvum) and iron reduction bacteria (Geobacter). They promoted Cd mobilization and reduced IP formation via the metal redox process. This study reveals a potential approach in which specific rhizobacteria decrease or increase Cd accumulation in rice on contaminated soil and provides a new perspective for secure rice production.     

两级A/O工艺处理焦化废水有机污染物转化特征及细菌群落响应

为探究两级缺氧/好氧(anoxic/oxic, A/O)工艺处理焦化废水有机污染物转化和细菌群落结构之间的关系,以实际运行的焦化废水处理厂为研究对象,采用傅里叶变换红外光谱和三维荧光光谱对废水中有机污染物官能团与溶解性有机物(dissolved organic matter, DOM)进行分析,并采用高通量测序技术,分析两级A/O工艺中细菌群落结构及其功能的沿程变化. 结果表明:①两级A/O工艺对化学需氧量(COD)、氨氮(NH₄+-N)、硫氰酸盐(SCN?)、苯并[a]芘(BaP)、苯酚、挥发酚的去除率均在90%以上. ②各有机污染物的去除与醇类、脂类、醚类、多糖类及羧酸类等物质的C≡N、C—N、C=C、—CO—伸缩振动,以及—NH₂和N—H弯曲振动等官能团运动有关,原水中大部分DOM被去除. ③微生物分析表明,硫杆菌(Thiobacillus)为两级A/O工艺的优势菌属(相对丰度为18.85%~31.06%),Fluviicola和norank_f_JG30-KF-CM45的相对丰度与BaP浓度均呈负相关,Arenimonas的相对丰度与挥发酚、苯酚浓度均呈正相关,Bradyrhizobium、Nakamurella、Nitrospira、norank_f_NS9_marine_group、unclassified_f_Rhizobiaceae的相对丰度与挥发酚、苯酚浓度均呈负相关. ④两级A/O工艺中有机污染物的去除与氟苯甲酸酯降解、多环芳烃降解、苯甲酸酯降解等多种代谢途径有关. 研究显示,经两级A/O工艺处理后,焦化废水中的主要污染物均显著去除,并且有机污染物变化均会影响功能微生物相对丰度的改变.      

不同施肥措施下长江经济带地区农田土壤有机碳含量的变化分析

收集整理1992年1月至2022年5月长江经济带地区长期定位施肥试验文献,提取并整合了其中农田土壤有机碳的资料.采用归一化处理和变化速率的分析方法,研究长期不同施肥措施下长江经济带地区农田土壤有机碳含量的总体变化,并比较3种耕作模式及不同土壤类型下土壤有机碳含量的变化差异,判断分析试验持续年限长短对土壤有机碳动态的影响.结果表明,在长期不同施肥措施下,我国长江经济带地区农田土壤有机碳含量整体呈上升趋势,无机氮肥磷肥配施(NP)、无机氮磷钾肥配施(NPK)、单独施用有机肥(O)和有机无机肥配施(NPKO)处理均能增加农田土壤的有机碳含量,其中以NPKO处理为最大,而单独施用无机氮肥(N)则会降低土壤有机碳含量.旱田、水田和水旱轮作农田土壤有机碳含量变化速率分别为0.22、 0.24和0.16g·(kg·a)^-1,3种耕作模式在土壤固碳效果方面并无显著性差异.O和NPKO处理下所带来的有机碳相对快速增加效应在旱田土壤中的持续年限最高不超过28 a,而在水田及水旱轮作土壤中依然可以持续到28 a以上.在不同的土壤类型下,土壤有机碳含量的变化速率存在着一定的差异,平均有机...     

Precise and Economical Dredging Model of Sediments and Its Field Application: Case Study of a River Heavily Polluted by Organic Matter,Nitrogen, and Phosphorus

Environmental dredging is an efficient means to counteract the eutrophication of water bodies caused by endogenous release of nitrogen and/or phosphorus from polluted sediments. The huge operational cost and subsequent disposal cost of the dredged polluted sediments, as well as the adverse effect on the benthic environment caused by excessive dredging, make the currently adopted dredging methods unfavorable. Precise dredging, i.e., determining the dredging depth based on the pollution level, not only significantly decreases the costs but also leaves a uniform favorable environment for benthos. However, there is still no feasible process to make this promising method executable. Taking a river heavily polluted by organic compounds as an example, we proposed an executable precise dredging process, including sediment survey, model establishment, data interpolation, and calculation of dredging amount. Compared with the traditional dredging method, the precise one would save 16 to 45 % of cost according to different pollutant removal demands. This precise dredging method was adopted by the National Water Project of China to treat the endogenous pollution of Nanfei River in 2010. This research provides a universal scientific and engineering basis for sediment dredging projects.     

Estimation of Nonpoint Source Nitrate Concentrations in Indiana Rivers Based on Agricultural Drainage in the Watershed

Subsurface tile‐drained agricultural fields are known to be important contributors to nitrate in surface water in the Midwest, but the effect of these fields on nitrate at the watershed scale is difficult to quantify. Data for 25 watersheds monitored by the Indiana Department of Environmental Management and located near a U.S. Geological Survey stream gage were used to investigate the relationship between flow‐weighted mean concentration (FWMC) of nitrate‐N and the subsurface tile‐drained area (DA) of the watershed. The tile DA was estimated from soil drainage class, land use, and slope. Nitrate loads from point sources were estimated based on reported flows of major permitted facilities with mean nitrate‐N concentrations from published sources. Linear regression models exhibited a statistically significant relationship between annual/monthly nonpoint source (NPS) nitrate‐N and DA percentage. The annual model explained 71% of the variation in FWMC of nitrate‐N. The annual and monthly models were tested in 10 additional watersheds, most with absolute errors within 1 mg/l in the predicted FWMC. These models can be used to estimate NPS nitrate for unmonitored watersheds in similar areas, especially for drained agricultural areas where model performance was strongest, and to predict the nitrate reduction when various tile drainage management techniques are employed.     

芹菜农药残留监测结果分析

为了解芹菜质量安全现状,对蔬菜批发市场、农贸市场、超市销售的芹菜进行了农药甲胺磷、氧乐果等50项农药的专项抽样调查分析,共抽检芹菜样本213个,通过采用GB2763--2012（食品中农药最大残留限量》进行判定,结果表明：引起芹菜农药残留超标的农药主要为毒死蜱、甲拌磷、多菌灵等,其中由这3种农药引起芹菜超标的比例占农残超标总批次的78．1％,芹菜质量安全状况还需进一步加强。     

贮存寿命评价工具箱设计研究

作为装备贮存可靠性与贮存寿命评价的关键技术,加速寿命试验和加速退化试验已在工程中广泛应用,基于物理分析的贮存寿命特征检测技术也逐步在贮存寿命评价工程中开展。贮存寿命评价技术已有一套完整的理论基础并积累了大量的工程实践经验,但行业内至今仍缺少专门针对贮存寿命评价的软件工具。本文通过对贮存寿命评价工具箱的需求分析研究工作,构建了工具箱的技术框架,并给出工具箱各主要模块的业务流程图和业务概念图,为贮存寿命工具箱的开发提供了支撑。     

Spatial distribution and source identification of persistent pollutants in marine sediments of Hong Kong

A data matrix, obtained during a 3-year monitoring period (2007–2009) from 45 sampling sites in Hong Kong marine, was subjected to determine the spatial characterization and identify the sources of main pollutants. Indicator analyses indicated that polycyclic aromatic hydrocarbons (PAHs), nickel, manganese, and arsenic (As) were at safe levels. Five heavy metals (zinc, lead, cupper, cadmium, chromium (Cr)) were moderate to severe enrichment at some sites. Inner Deep Bay and Victoria Harbor were considered as hot spots for PAHs and the heavy metals, while Tolo Harbor was highly polluted by the heavy metals. Cluster analysis classified the 45 sampling sites into three groups, representing different pollution levels. Principal component analysis/factor analysis identified four principal components (PCs) and explained 84.9 % of the total variances, standing for persistent pollution, N factor, P and Cr factor, and As factor, respectively. Group A was highly polluted by persistent pollution, group B was the less polluted group, and subgroup B1 was less affected by PC3 and PC4 than subgroup B2. Group C, considered as the moderately polluted group, was greatly affected by N factor or persistent pollution, while subgroup C2 received more N pollution than subgroup C1.