Catalytic bubble-free hydrogenation reduction of azo dye by porous membranes loaded with palladium nanoparticles

Catalytic bubble-free hydrogenation reduction of azo dye by porous membranes loaded with palladium （Pd） nanoparticles was studied for the first time. The effects of Pd loading, dye concentration and reuse repetitions of membranes were investigated. In reduction, the dye concentration decreased whereas the pH rose gradually. An optimal Pd loading was found. The catalytic membranes were able to be reused more than 3 times.     

Primary neuronal-astrocytic co-culture platform for neurotoxicity assessment of di-(2-ethylhexyl) phthalate

Plastics such as polyvinyl chlorides （PVC） are widely used in many indoor constructed environments; however, their unbound chemicals, such as di-（2-ethylhexyl） phthalates （DEHP）, can leach into the surrounding environment. This study focused on DEHP＇s effect on the central nervous system by determining the precise DEHP content in mice brain tissue after exposure to the chemical, to evaluate the specific exposure range. Primary neuronal-astrocyte co-culture systems were used as in vitro models for chemical hazard identification of DEHP. Oxidative stress was hypothesized as a probable mechanism involved, and therefore the total reactive oxygen species （ROS） concentration was determined as a biomarker of oxidative stress. In addition, NeuriteTracer, a neurite tracing plugin with ImageJ, was used to develop an assay for neurotoxicity to provide quantitative measurements of neurological parameters, such as neuronal number, neuron count and neurite length, all of which could indicate neurotoxic effects. The results showed that with 1 nmol/L DEHP exposure, there was a significant increase in ROS concentrations, indicating that the neuronal-astrocyte cultures were injured due to exposure to DEHP. In response, astrocyte proliferation （gliosis） was initiated, serving as a mechanism to maintain a homeostatic environment for neurons and protect neurons from toxic chemicals. There is a need to assess the cumulative effects of DEHP in animals to evaluate the possible uotake and effects on the human neuronal system from exoosure to DEHP in the indoor environment.     

Dyes adsorption using a synthetic carboxymethyl cellulose-acrylic acid adsorbent

Removal of noxious dyes is gaining public and technological attention. Herein grafting polymerization was employed to produce a novel adsorbent using acrylic acid and carboxymethyl cellulose for dye removal. Scanning electron microscopy and Fourier-transform infrared spectroscopy verified the adsorbent formed under optimized reaction conditions. The removal ratio of adsorbent to Methyl Orange, Disperse Blue 2BLN and malachite green chloride reached to 84.2%, 79.6% and 99.9%, respectively. The greater agreement between the calculated and experimental results suggested that pseudo second-order kinetic model better represents the kinetic adsorption data. Equilibrium adsorptions of dyes were better explained by the Temkin isotherm. The results implied that this new cellulose-based absorbent had the universaiity for removal of dyes through the chemical adsorption mechanism.     

汞分析仪直接测定土壤中总汞的方法研究

建立了利用RP91C-RA915M汞分析仪直接测定土壤中总汞的方法。该方法直接固体进样,省去了常规方法加酸消解、赶酸、定容等繁琐的前处理步骤;利用标准土壤绘制工作曲线,无需反复稀释标准储备液配制标准溶液,测定了方法检出限、精密度及准确度。结果表明此方法准确、可靠,是一个比较理想的分析方法。本方法的检出限为0.25μg/kg,相对标准偏差为1.98%~4.92%,标准样品测定准确,加标回收率为92.8%~106%。     

生物物种信息平台建设进展研究

信息技术的突飞猛进和互联网的迅速扩张,为生物多样性信息的收集、存储、提交、检索、分析、传播和使用带来了革命性的发展。生物多样性数据和信息服务的内容逐步从单一的名录数据库建设转向为多学科交叉的综合信息服务平台。本文结合国家生物多样性保护专项,在介绍国内外主流生物多样性信息平台建设现状的基础上,分析了我国现有平台存在的问题,并对下一步如何完善和推进平台应用进行探讨。     

危化品企业安全生产标准化与其他管理体系的对比研究

分析了安全生产标准化与其他管理体系的关系,并结合当前推进安全生产标准化工作的具体要求,阐述了安全生产标准化的作用。     

油品装卸过程静电特性研究

为了研究油品装卸过程中的静电危险性,在两个城市的油库和加油站对油品的装油、卸油过程,以及装油的油罐车从油库向加油站行驶的过程中,油罐车内油品的油面电位进行了静电检测。通过对大量油罐车内油面电位的检测数据分析可以看出,在正常装卸油过程中,油罐车内油品的油面电位远远小于标准所规定安全油面电位,有缩短稳油时间的可能性。     

都匀毛尖茶土壤中总磷含量的调查研究

目的:调查都匀毛尖茶土壤中总磷的含量;方法:以贵州省都匀市毛尖茶产地--螺丝壳山的土壤为研究对象,采用酸法消解,用钼酸铵分光光度法于700 nm波长处测定土壤中总磷含量;结果:都匀螺丝壳山中土壤中总磷含量在177.58 mg·kg-1~353.92 mg·kg-1之间;结论:都匀毛尖茶土壤中的总磷含量在全国基本水平范围以内,总磷含量与土壤的类型、土壤所处海拔高度无明显关系。     

松花江(黑龙江省段)流域水环境承载力指标体系构建研究

针对流域水环境承载力指标体系亟待解决的问题,介绍了流域水环境承载力指标体系构建进展与存在的问题,提出了流域水环境承载力指标体系构建的改进措施,对松花江流域水环境承载力指标体系构建,提出了改进指标体系的构建原则、构建程序,分析影响因素,提出流域水环境承载力内涵,从水资源量、水资源消耗量、水资源质量影响三方面出发选取了指标,构建了松花江流域水环境承载力的三层递阶层次结构的指标体系,为评价与预测该流域水环境承载力奠定理论基础。     

阳澄湖浮游植物群落结构与环境因子的典范对应研究

2013年4月（春季）和10月（秋季）对阳澄湖6个点位的浮游植物群落结构进行了调查,共发现浮游植物8门91属184种,其中硅藻门为阳澄湖的主要优势门类,硅藻门中的小环藻属占主要优势种.对六个点位的浮游植物结构组成与9个环境因子的关系进行典范对应分析,结果表明东湖南与中湖北的浮游植物群落结构与其他4个点位差异性较大,pH、高锰酸盐指数、总磷、氨氮、水温是影响浮游植物分布的主要环境因子.