Persistent organic pollutants in water and surface sediments of Taihu Lake,China and risk assessment

Organic pollutants, especially persistent organic pollutants were examined in the water and surface sediments of Taihu Lake, China. Both 12 water and 12 sediment samples were collected over the lake. C-18 solid-phase extraction technique was applied to extract organic pollutants in collected water samples. Soxhlet extraction procedure was used to extract organic pollutants in sediment samples. The analysis was performed by GC-MS controlled by a Hewlett Packard chemstation. Two hundred and seventy-three kinds of organic chemicals in water were examined, 200 more than that detected in 1985; 188 kinds of chemicals in sediments were detected as well. Among them 21 kinds of chemicals belong to priority pollutants as well as 17 kinds to be the endocrine disruptors. The concentrations of the pollutants were more than 2 times higher than that in 1985. The possible source and relation to anthropogenic activity were discussed.     

Inactivation of fungi associated with barley grain by gaseous ozone

The use of gaseous ozone as a fungicide to preserve stored barley was studied. The effects of the following operating parameters on the fungicidal efficacy of ozone were examined: 1) the applied ozone dose, 2) ozonation time, 3) water activity of barley, and 4) temperature of barley. The effect of ozonation on germination of barley was also investigated. The experimental results showed that ozone was very effective in inactivation of fungi associated with the barley regardless of whether the fungi were in the forms of spores or mycelia. However, the mycelia were less resistant to ozone. With 5 minutes of ozonation, 96% of inactivation were achieved for spores as well as for mixtures of spores and small amount of mycelia by applying 0.16 and 0.10 mg of ozone/(g barley) x min, respectively. In addition, for sealed storage silos, inactivation of fungi continued when the ozone-containing gas was held inside the silos following a continuous ozone supply. The experimental results also revealed that increases in water activity and temperature of barley enhanced the fungicidal efficacy of ozone. Results of this study also indicated that the inactivation processes could be controlled by simply monitoring the exit ozone from the reactor instead of performing the time-consuming microbial examination. This finding would make the application of ozone in the preservation of cereal grains easier, simpler, and more practically applicable. The experimental results demonstrated that although ozonation above certain strength may reduce barley germination, inactivation of fungi was achieved with ozonation strengths far below the critical point.     

粘土矿物与重金属界面反应的研究进展

介绍了3种粘土吸附剂：蒙脱石、高岭石和伊利石对重金属的吸附、脱附等界面反应机理，以及粘土矿物对重金属的选择性及对吸附的影响因素。另外，还探讨了为提高其吸附性能而进行的改性方法。     

Seasonal variation of the distribution of PCBs in sediments and biota in a PCB-contaminated estuary

To elucidate the effects of seasonal variation of precipitation on the distribution of polychlorinated biphenyls (PCBs) in estuarine sediments and benthic feeders, PCB concentrations of river surface sediments and mullet fish (Liza macrolepis) were investigated in the estuary of Er-Jen River near former PCB contamination sites before and after each wet season from 2002 to 2004. Analyses of grain size distribution and organic matter revealed that the pre-existing surface sediments were covered by and mixed with the soil particulates brought by surface runoff after each wet season. Obvious increment of PCB content and significantly elevated fraction (p < 0.005) of light PCBs of the river mouth’s sediments after each wet season indicated that the invading particles were rich in unweathered PCBs. PCBs previously buried in the surface soil of heavily contaminated sites were flushed into this estuary through surface runoff. The precipitation altered the PCB patterns in sediment organic matter, the dietary source of mullet, and consequently changed that of mullets accordingly, which all possessed significant greater fraction of light PCBs. In this study, it was demonstrated that seasonal summer precipitation affected the distribution of PCBs on surface sediments and the mullets of this estuary. PCB residuals retained in this region still pose potential threats to biota resided here.     

Effects of EDTA and low molecular weight organic acids on soil solution properties of a heavy metal polluted soil

A pot experiment was conducted to study the effects of EDTA and low molecular weight organic acids (LMWOA) on the pH, total organic carbon (TOC) and heavy metals in the soil solution in the rhizosphere of Brassica juncea grown in a paddy soil contaminated with Cu, Zn, Pb and Cd. The results show that EDTA and LMWOA have no effect on the soil solution pH. EDTA addition significantly increased the TOC concentrations in the soil solution. The TOC concentrations in treatments with EDTA were significantly higher than those in treatments with LMWOA. Adding 3 mmol kg(-1) EDTA to the soil markedly increased the total concentrations of Cu, Zn, Pb and Cd in the soil solution. Compared to EDTA, LMWOA had a very small effect on the metal concentrations. Total concentrations in the soil solution followed the sequence: EDTA > citric acid (CA) approximately oxalic acid (OA) approximately malic acid (MA) for Cu and Pb; EDTA > MA > CA approximately OA for Zn; and EDTA > MA > CA > OA for Cd. The labile concentrations of Cu, Zn, Pb and Cd showed similar trends to the total concentrations.     

废水中2,6-二硝基酚厌氧毒性和降解动力学研究

在中温(35℃±1℃)厌氧条件下,以葡萄糖为共基质,采用间歇实验方法,研究了2,6-二硝基酚(2,6-DNP)的厌氧产甲烷毒性和厌氧降解动力学.厌氧毒性试验(ATA)以累计产甲烷量和相对活性(RA)为指标,评价了不同浓度2,6-DNP对产甲烷菌的抑制程度;结果表明,2,6-DNP浓度＜20 mg/L时,对产甲烷菌没有抑制作用,浓度为40 mg/L时产生轻度抑制,浓度为80～120 mg/L时产生重度抑制;24 h 2,6-DNP的75%、50%、25%相对抑制浓度分别为30、70和＞120 mg/L.2,6-DNP降解动力学可用Haldane方程来描述,利用非线性拟合求得动力学参数Ks、Rm、Ki分别为179.7 mg/L、4.84 mg/g VSS·h、206.5 mg/L,方差R2=0.94,拟合效果很好.     

Sequential coupling of bio-augmented permeable reactive barriers for remediation of 1,1,1-trichloroethane contaminated groundwater

Sequential coupling of high-density luffa sponge (HDLS) immobilized microorganism and permeable reactive barriers (IM Bio-PRBs) was superior to intimate coupling of free microorganism and permeable reactive barriers (FM Bio-PRBs) for remediation of 1,1,1-trichloroethane contaminated groundwater. IM Bio-PRBs had much better performance to removal 1,1,1-trichloroethane (1,1,1-TCA) and prevent the transport of 1,1,1-TCA and inorganic ions (NO₃^?, PO₄^3?, and SO₄^2?). The majority of them were prevented and accumulated in upgradient of IM Bio-PRBs. 1,1,1-TCA and inorganic ions in there contributed to the much faster growth of microorganism in upgradient aquifer. Therefore, the removal of 1,1,1-TCA and consumption of inorganic ions in upgradient of Bio-PRBs played a constructive role in reducing the processing load of following zero-valent iron (ZVI) PRBs and the negative effect of free microorganism cells (biological clogging) and inorganic ions (chemical clogging) on Bio-PRB permeability. In addition, IM Bio-PRBs were more conducive to accelerate the removal of 1,1,1-TCA in long-term remediation and 1,1,1-TCA residual concentration significantly lower than the safety standard of 0.2 mg L^?1. The change of terminal by-products of 1,1,1-TCA contaminated groundwater in Bio-PRBs showed that 1,1,1-TCA could be effectively de-chlorinated and mineralized in Bio-PRBs. The reductant H₂S (prolong the service life of ZVI-PRBs) was much more produced and utilized in IM Bio-PRBs. Taken together, sequentially coupled IM Bio-PRBs had a better overall performance, and its service life could be prolonged. It was a different design and idea to update conventional PRB remediation technology and theory.

     

汽车尾气催化转化器模型研究进展

本文主要介绍汽车尾气催化转化器模型的研究进展 ,包括反应器内气体流动特性、单通道反应器内的传递现象和反应动力学、通道间的热传递和反应行为的模拟 ;并指出认识反应器内的各种特性和规律对设计汽车尾气催化转化器的必要性和意义     

地下水环境中反硝化作用

地下水氮污染已是全球性的环境问题 ,反硝化作用是地下水脱氮的主要机制。本文综述了地下水环境中反硝化作用的判据、速率、影响因素以及人工强化措施 ,指出了存在的问题和今后的发展方向     

白腐菌对芳香族化合物的降解途径

白腐菌 (Whiterotfungi)是目前所发现的对芳香族化合物有很强降解能力的一类微生物。本文探讨了降解芳香族化合物的白腐菌种及其代谢化合物的主要类型 ,分析了对不同化合物的不同代谢途径 ,同时展望了其应用前景