汉江上游郧县曲远河河口段全新世古洪水水文状态研究

对汉江上游河谷郧县曲远河河口剖面进行了沉积学、粒度、磁化率和烧失量的研究。结果表明：夹在古土壤中的灰白色沉积层是典型的古洪水滞流沉积物，记录了一次特大洪水事件，用地层对比法和OSL方法确定其发生时间为4 950~5 450 a B.P.。用古洪水SWD尖灭点法确定古洪水行洪水位高程为169 m，采用比降法恢复其洪峰流量为60 577 m3/s。根据2011年汉江上游洪水洪痕，用相同的方法对洪峰流量进行了反演，误差为-411％，说明用比降法恢复的古洪水洪峰流量是可靠的     

水电厂设备设施风险的动态分级研究

为保障水电厂安全运行,根据水电厂设备设施构成要素,系统分析其风险,建立涵盖水轮机及其辅助设备、发电机及其辅助设备、计算机监控系统及自动装置、电气一次设备、电气二次设备、水工建筑物及金属结构、机具与防护设施等因素在内的评价指标体系。采用欧氏距离定义样本差异,标准化处理属性特征值,通过聚类迭代,开发水电厂设备设施风险的动态分级方法。研究结果表明:水电厂设备设施故障风险在每年的第2,3季度明显大于第1,4季度,并且随着时间推移,各季度设备设施故障风险同比有增加的趋势,风险分级结果与设备设施故障的变化趋势基本吻合。     

萍乡市农用土壤重金属含量及其分布特征分析

以江西省萍乡地区农用土壤为研究对象,分析研究了萍乡市农用土壤中重金属的含量、分布特征。结果表明:萍乡地区农用土壤中重金属的平均含量均未超过国家土壤环境质量二级标准,但其中锌、镍、铬、铜、镉、砷、铅、锰、汞的含量均超过了江西省土壤重金属相应元素的背景值。从空间分布来看,在全市5个县区布置的29个测点中,有14个测点的重金属含量超标;其中上栗县有8个测点超标,明显多于其他县区,出现了不同的污染特征。     

四氯丙烯对稀有鮈鲫的急性毒性及安全浓度评价

采用半静态试验方式测试了四氯丙烯对稀有鮈鲫(Gobiocypris rarus)的急性毒性,试验浓度分别设定为0.25 mg·L~(-1)、0.30mg·L~(-1)、0.36 mg·L~(-1)、0.42 mg·L~(-1)、0.50 mg·L~(-1)和0.60 mg·L~(-1),同时进行空白对照(试验用水)和分散剂对照(体积分数为0.006%的吐温-80水溶液)试验。采用气相色谱法对试验溶液进行浓度分析,实测浓度分别为0.19 mg·L~(-1)、0.25 mg·L~(-1)、0.34 mg·L~(-1)、0.40 mg·L~(-1)、0.51 mg·L~(-1)和0.64 mg·L~(-1),试验结果以实测浓度表示和统计。结果表明:四氯丙烯致稀有鮈鲫无死亡发生(EC0)的最高浓度为0.25 mg·L~(-1),导致稀有鮈鲫100%死亡(EC100)的最低浓度为0.51 mg·L~(-1)。根据实测浓度,用SPSS(17.0)概率单位法求得四氯丙烯对稀有鮈鲫的半数致死浓度96 h-LC50为0.347 mg·L~(-1),95%置信区间为0.328 mg·L~(-1)~0.361 mg·L~(-1)。     

预测沉积物-水微宇宙系统中化学品浓度变化的多介质模型

沉积物-水微宇宙系统是经济合作发展组织(Organisation for Economic Co-Operation and Development,OECD)颁布的化学品测试准则中推荐的试验系统之一,可用来测试化学品对底栖生物的慢性毒性。为了在试验前对化学品的浓度变化进行预测,进而确定试验方法,以摇蚊慢性毒性试验系统为例,采用环境多介质模型的建模方法,构建了一种可通过化学品理化性质和试验系统参数,对化学品在沉积物-水试验系统中浓度变化进行预测的模型。结合试验数据和文献资料,给出了模型中试验系统参数的推荐取值,并使用Matlab软件中的Simulink工具对模型进行编程和求解。以此模型为基础,给出了模型在3个方面的应用,即预测蓄积时间、预测平衡时间以及拟合试验数据。对80种已有或假想化学品的蓄积时间和平衡时间进行了计算,得出的范围分别为1~204 d和1~73 d。此外,适当修改模型结构和模型参数,也可将其应用于其他暴露场景中。但使用模型对化学品浓度进行预测时发现,模型仅对沉积物中化学品浓度的预测结果较为准确,而对水中化学品浓度的预测结果与实测值相差1~2个数量级。模型对浓度的预测精度未来仍需进一步提高。上述研究结果完善了沉积物-水微宇宙系统试验方法。     

Mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor

In this study, the mercury adsorption characteristics of HBr-modified fly ash in an entrained-flow reactor were investigated through thermal decomposition methods. The results show that the mercury adsorption performance of the HBr-modified fly ash was enhanced significantly. The mercury species adsorbed by unmodified fly ash were HgCl₂, HgS and HgO. The mercury adsorbed by HBr-modified fly ash, in the entrained-flow reactor, existed in two forms, HgBr₂ and HgO, and the HBr was the dominant factor promoting oxidation of elemental mercury in the entrained-flow reactor. In the current study, the concentration of HgBr₂ and HgO in ash from the fine ash vessel was 4.6 times greater than for ash from the coarse ash vessel. The fine ash had better mercury adsorption performance than coarse ash, which is most likely due to the higher specific surface area and longer residence time.     

Integration of chemical and biological methods: A case study of polycyclic aromatic hydrocarbons pollution monitoring in Shandong Peninsula, China

Polycyclic aromatic hydrocarbons(PAHs), as persistent toxic substances(PTS), have been widely monitored in coastal environment, including seawater and sediment. However, scientific monitoring methods, like ecological risk assessment and integrated biomarker response, still need massive researches to verify their availabilities. This study was performed in March, May, August and October of 2018 at eight sites, Yellow River estuary(S1), Guangli Port(S2), Xiaying(S3), Laizhou(S4), Inner Bay(S5), Ou...     

Constitutional tolerance to heavy metals of a fiber crop, ramie (Boehmeria nivea), and its potential usage

It is observed that ramie (Boehmeria nivea), an economic fiber crop, can establish and colonize metal-contaminated sites in China. Metal tolerance and accumulation by ramie originating from 13 metal-contaminated and 4 “clean” sites in China were compared under field and hydroponic conditions. All selected populations and germplasms displayed good growth performance under diverse metal-contaminated habitats; while growth responses, metal accumulation and tolerance were similar among the 8 populations and 2 germplasms when exposed to solutions containing elevated As, Cd, Pb, or Zn in the laboratory. These revealed that ramie possesses a certain degree of constitutional metal tolerance. To our knowledge, this is the first report of constitutional metal tolerance possessed by a fiber crop. Ramie can be considered as a good candidate for both fiber production and phytoremediation of sites contaminated by multi-metals, as it accumulates relative low metal concentrations, but possesses both high biomass and high economic value.