Influence of root-exudates concentration on pyrene degradation and soil microbial characteristics in pyrene contaminated soil

The effect of ryegrass (Lolium perenne L.) root-exudates concentration on pyrene degradation and the microbial ecological characteristics in the pyrene contaminated soil was investigated by simulating a gradually reducing concentration of root exudates with the distance away from root surface in the rhizosphere. Results showed that, after the root-exudates were added 15 d, the pyrene residue in contaminated soil responded nonlinearly in the soils with the same pyrene contaminated level as the added root-exudates concentration increased, which decreased first and increased latter with the increase of the added root-exudates concentration. The lowest pyrene concentration appeared when the root exudates concentration of 32.75 mg kg(-1) total organic carbon (TOC) was added. At the same time, changes of microbial biomass carbon (MBC, C(mic)) and microbial quotient (C(mic)/C(org)) were opposite to the trend of pyrene degradation as the added root-exudates concentration increased. Phospholipid fatty acid (PLFA) analysis revealed that bacteria was the dominating microbial community in pyrene contaminated soil, and the changing trends of pyrene degradation and bacteria number were the same. The changing trend of endoenzyme-dehydrogenase activity was in accordance with that of soil microbe, indicating which could reflect the quantitative characteristic of detoxification to pyrene by soil microbe. The changes in the soils microbial community and corresponding microbial biochemistry characteristics were the ecological mechanism influencing pyrene degradation with increasing concentration of the added root-exudates in the pyrene contaminated soil.     

凹凸棒石粘土固定辣根过氧化物酶处理含酚废水

采用凹凸棒石粘土、可溶性淀粉和工业水玻璃作为制备凹凸棒石粘土基颗粒的材料,并将制备的凹凸棒石粘土基颗粒进行改性,得到了改性后的凹凸棒石基多孔材料,并将其作为固定辣根过氧化物酶的载体,再应用于含酚废水的处理研究,取得了良好的效果。实验结果表明,辣根过氧化物酶的最佳固定化条件为:单位酶活载体量1 mg、固定化时间1.5小时、固定pH值5。并且在固定化酶循环使用6次后,苯酚去除率仍能达到62.3%。     

Emission factors and particulate matter size distribution of polycyclic aromatic hydrocarbons from residential coal combustions in rural Northern China

Coal consumption is one important contributor to energy production, and is regarded as one of the most important sources of air pollutants that have considerable impacts on human health and climate change. Emissions of polycyclic aromatic hydrocarbons (PAHs) from coal combustion were studied in a typical stove. Emission factors (EFs) of 16 EPA priority PAHs from tested coals ranged from 6.25 ± 1.16 mg kg^?1 (anthracite) to 253 ± 170 mg kg^?1 (bituminous), with NAP and PHE dominated in gaseous and particulate phases, respectively. Size distributions of particulate phase PAHs from tested coals showed that they were mostly associated with particulate matter (PM) with size either between 0.7 and 2.1 μm or less than 0.4 μm (PM_0.4). In the latter category, not only were more PAHs present in PM_0.4, but also contained higher fractions of high molecular weight PAHs. Generally, there were more than 89% of total particulate phase PAHs associated with PM_2.5. Gas-particle partitioning of freshly emitted PAHs from residential coal combustions were thought to be mainly controlled by absorption rather than adsorption, which is similar to those from other sources. Besides, the influence of fuel properties and combustion conditions was further investigated by using stepwise regression analysis, which indicated that almost 57 ± 10% of total variations in PAH EFs can be accounted for by moisture and volatile matter content of coal in residential combustion.     

A Comparison of Mass,Lead, Sulfate,and Nitrate Concentrations in a Field Study Using Dichotomous,Size-Selective,and Standard Hi-Vol Samplers

Air monitoring In the San Francisco Bay Area was carried out to measure outdoor community air concentrations of poly cyclic aromatic hydrocarbons (PAH) and mutagenlc activity (mutagenlclty) In participate organic matter (POM). Monitoring began In 1979 and Is currently conducted at six stations. PAH and mutagenlclty tests were performed on organic extracts prepared from high volume (hl-vol) filters composited every four months, by meteorological season. PAH were determined by high pressure liquid chromatography (HPLC) with fluorescence and ultraviolet detection. Mutagenlclty was measured In the Ames Salmonella bloas-say using strain TA98 with and without metabolic activation. The nine-year mean concentration of benzo(a)pyrene (BaP) was 0.4 ng/m³. The mutagenlcfty of this amount of BaP accounted for only about 0.2% of the observed mutagenicity In POM and other measured PAH accounted for even less. Concentrations of PAH and mutagenlclty were three to nine times higher during the winter than during other seasons. Year-to-year wintertime trends In several PAH were also seen. Early In the 1980s, winter concentrations of BaP and benzo (g,h,i)perylene Increased. However since the mld-1980’s, their concentrations have fallen. The decrease In PAH concentrations may be the result of an Increasing proportion of vehicles with relatively low organic emissions. In contrast to PAH, mutagenlcfty did not show significant year-to-year time trends.     

城市污水雌激素活性研究进展——毒性评估、致毒物解析及毒性削减

城市污水成分复杂,含有多种有毒有害物质,使其能对生物体产生各种不良生物效应,其中,内分泌干扰物,尤其是雌激素类物质以及具有雌激素活性的污染物,因能影响生物的生殖系统并造成受纳水体鱼类性别转变等危害而备受关注,城市污水的雌激素活性也一直是污水处理领域的研究热点.当前,城市污水回用是缓解全球水资源危机的重要途径之一,在此背...     

用固体力学化学理论研究岩土的力学化学行为——以成都龙泉紫色土为例

根据固体力学化学理论 ,提出用化学动力学方法研究岩土破坏及滑坡形成的机理 ,并以成都龙泉紫色土为例研究了在力与水协同作用下易滑土层的力学化学行为。实验表明 ,土长期抗剪强度降低的幅度与溶液的pH值有关 ,土的溶解速度与易溶盐含量有关 ,且溶解曲线略呈“S”型。这初步证明了龙泉紫色土破坏的力学 化学效应及其可能存在的自催化趋势。通过实验了解了力与水协同作用导致土破坏的力学化学规律 ,并将定量求解滑面长期抗剪强度与反应机理研究结合起来 ,为定量评价地下水和应力对岩土破坏机理这一滑坡学关键问题打下基础。     

上海人口自然变动负增长与社会经济发展

1993年上海人口自然变动在全国率先进入负增长,自然增长率为-0.78‰,并将持续一个较长的时期。这是长期以来本市经济和社会发展以及计划生育工作共同作用的必然结果,其中计划生育政策的成功推行起着重要的作用。上海除了继续控制人口增长的数量外,还要调节人口规模和人口结构,大力提高人口素质,不断使人口与社会经济发展、生态平衡、资源利用等方面达到协调发展。由负增长引发的劳动力短缺和老龄化程度加剧要采取相应的对策。     

长时间单调模拟驾驶对疲劳的影响研究

通过模拟驾驶实验,综合评估长时间驾驶以及单调环境对驾驶员疲劳程度的影响是笔者研究的主要课题内容。借助于在模拟驾驶座舱上,4个健康样本分别参加高速公路(单调环境)和一般公路(非单调环境)的两组驾驶仿真实验,每组测试均持续两小时,一共进行10次实验。实验过程中,样本的操控数据(车速和方向盘转角)、反应时间、心电信号、主观疲劳状况等都同步记录并保存。实验结果表明长时间驾驶对操控能力、反应时间、心率、主观疲劳都有显著性影响(p<0.050),单调环境(高速公路)和非单调环境(一般公路)相比,车速方差区别显著,而尽管被试在高速公路的单调环境下驾驶后主观感觉更疲劳一些,但反应时间、心率等因素并没有显著性差异。     

西藏食物保障度分析及对策

食物保障是西藏社会性经济可持续发展重要问题之一。分析表明，西藏食物保障度及目标因食物种类而异。尽管粮食总产及单产均持续增长，但结构性短缺问题难以解决，粮食保障不应过分强调自给率目标；肉类中羊肉自给，但猪肉基本依靠内地；蔬菜保障存在生产不稳定问题，如何提高生产的稳定性是问题的关键。对居民营养摄入量及结构的分析表明，城乡居民食物消费结构及来源结构有较大差异，城镇居民食物消费与内地差异不大，而乡村居民的食物消费呈现极显著的本地化特征；分析还表明，城乡居民生活支出中有一半以上用于食物，表明收入和生活水平还不高，特别要关注低收入居民的食物问题。为此，粮食不应继续作为食物保障的重点，重点应在鲜活食物的保障；建立包括开放食物流通系统和开放食物生产系统在内的开放的食物保障系统；改善交通运输条件、增进食物空间可达性，包括增进食物生产资料空间可达性和改善畜产品外销通径；增强储备意识和能力：保障贫困人口食物供给：广辟食物来源。     

阵性泥石流运动与堆积的欧拉─拉格朗日模型──Ⅰ.理论

自然界中的泥石流具有突发性和非恒定性的特点。为了模拟典型泥石流现象,在流团模型的 基础上,进一步完善了基于欧拉─拉格朗日（Ｅ—Ｌ）观点的ＰＩＣ（Ｐａｒｃｅｌ　Ｉｎ　Ｃｅｌｌ）算法,细化了流元结 构,建立了能够模拟典型阵性泥石流发生、运动和堆积的准结构两相流模型。求解该模型不仅可以 模拟泥石流运动过程,而且可以对泥石流的堆积过程、停积形态、冲刷特征及泥石流中多组分颗粒 的分选特征进行定量描述。