首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   594篇
  免费   34篇
  国内免费   251篇
安全科学   48篇
废物处理   46篇
环保管理   58篇
综合类   314篇
基础理论   92篇
污染及防治   243篇
评价与监测   28篇
社会与环境   17篇
灾害及防治   33篇
  2024年   1篇
  2023年   9篇
  2022年   25篇
  2021年   26篇
  2020年   21篇
  2019年   18篇
  2018年   19篇
  2017年   25篇
  2016年   27篇
  2015年   36篇
  2014年   51篇
  2013年   69篇
  2012年   54篇
  2011年   47篇
  2010年   44篇
  2009年   53篇
  2008年   40篇
  2007年   40篇
  2006年   37篇
  2005年   33篇
  2004年   16篇
  2003年   18篇
  2002年   19篇
  2001年   25篇
  2000年   16篇
  1999年   18篇
  1998年   10篇
  1997年   16篇
  1996年   18篇
  1995年   10篇
  1994年   8篇
  1993年   9篇
  1992年   4篇
  1991年   2篇
  1990年   11篇
  1989年   2篇
  1988年   1篇
  1987年   1篇
排序方式: 共有879条查询结果,搜索用时 15 毫秒
861.
The relationship between ecological and socioeconomic systems in ecological function conservation areas (EFCAs) in China is analyzed from a governance perspective. Lashihai watershed in China’s southwestern Yunnan Province was chosen as a case study area, where leaders of 81 villager groups were interviewed through questionnaire surveys and anecdotal evidence was collected from focus group discussions. Our study found that the rehabilitated ecosystems in Lashihai, arising from conservation actions, provided the local communities with increasing natural capital to pursue horseback tourism as an important means of livelihood. Also, bonding social capital, together with unique cultural and ethnic assets, may have been instrumental in the formation of horseback tourism teams in some villager groups. However, the lack of higher-level government involvement and coordination among horseback tourism teams appeared to have led to a situation, where the rapidly developing tourism teams have started to impose threats on the wetland ecosystem. While highlighting some limitations of self-governance in adapting to complex and fast-changing socioeconomic conditions, the study called for the potential importance of fostering adaptive co-management to help modify the emerging undesired interconnectedness in social-ecological systems in Lashihai. For the future’s successful governance of integrated ecosystem management in EFCAs in China, the study also made brief discussion on some key elements of the adaptive co-management.  相似文献   
862.
为测定含大量干扰离子的水样中镍的浓度,提出一种改进的分光光度法。即以多种物质的吸光曲线回归方程,将实时测得的水样吸光度分解成多种物质的吸光度,利用多元一次方程进行求解并计算出浓度的方法。新方法在不进行修正时,对含Cr6+干扰的水样Ni2+测定的结果,误差较小。多组分的水样测量吸光度误差较大,通过引入修正系数修正后误差大幅下降。方法中Ni2+、Fe3+的吸光度与显色时间基本无关;而对于Mn2+、Cu2+和Cr6+,显色时间应控制在0.5~2.5 min内或10 min外,以保证测得吸光度值的稳定与准确。对组成不同的含Mn2+和Fe3+水样测得的Ni2+浓度分析,变异系数(CV)4.74%,检出限为0.275 mg/L,精确度和精密度较好。同时,这种规避方法还具有其他作用,可以在分析组分的同时粗略算出含量。  相似文献   
863.
树脂吸附法处理对氨基苯酚废水   总被引:3,自引:2,他引:1  
采用自制的NDA-99特种复合功能树脂处理对氨基苯酚(PAP)生产废水,考察了各种因素对吸附和脱附效果的影响。小试实验结果得出的工艺条件为:吸附流量2.0BV/h,吸附温度15℃,单柱吸附量10BV;脱附剂为2BV盐酸(质量分数1.5%)+2BV水。中试试验结果表明,在上述工艺条件下,NDA-99树脂处理PAP废水的吸附性能和脱附性能稳定,平均COD去除率约为93%,平均PAP脱附率达98%。  相似文献   
864.
In this study, a rapid and accurate ultra-fast liquid chromatography–tandem quadrupole mass spectrometry (UFLC–MS/MS) method coupled with the isotope internal standard dilution technique was established and validated to determine trace dicyandiamide (DCD) in mussels. The sample was extracted by acetonitrile, and chromatographic separations were performed on an Acquity UPLC BEH Amide column by using water–acetonitrile (9:91, v/v) as the mobile phase within 3 min. DCD was determined by using DCD-15N4 as an internal standard. The results showed that the recoveries were between 96.2 and 103 % with relative standard deviations (RSDs) in the range of 0.6–6.0 %. The limit of quantification (LOQ) was 0.05 μg/kg. This method can be applied to the routine analysis for the rapid and sensitive determination of trace DCD in mussels. Overall, the data reiterate the importance of investigating the presence of DCD in marine biological samples, which can act as food quality controls for human health.  相似文献   
865.
主要利用化学方法对环氧氯丙烷和胺类进行阳离子改性获得阳离子醚化剂,然后与碱化后的淀粉接枝制得一种絮凝性能良好的有机高分子阳离子絮凝荆,并对所得产品作了絮凝性能实验。由实验得知该絮凝剂对悬浮细小颗粒有很好的去除效果,如高岭土溶液(1g/L)产生矾花时间较短,加入絮凝剂后搅拌3min左右即可产生明显絮体,且絮体较大,静置后透光率达90%以上。  相似文献   
866.
A systemic strategy was proposed to improve aerobic granular sludge(AGS)stability and nitrogen(N)removal efficiency by optimizing feeding mode and substrate aiming at complicated wastewater characteristics.Key functional groups at the genus level identified by high-throughput sequencing were evaluated as well.The results showed that anaerobic feeding mode and acetate promoted the compact AGS formation with excellent total nitrogen(TN)removal efficiency(averaging 91.7%±4.1%)at various dissolved oxygen conditions.While the aerobic feeding mode led to a loose AGS structure with a vulnerable anaerobic core and poor TN removal efficiency(averaging58.8%±7.4%).Simultaneous nitrification and denitrification process played the dominant role in N removal in compact AGS over the alternating nitrification and denitrification process.High-concentration glucose undermined feast-famine condition with filamentous bacteria growth out of granule and decreased TN removal efficiency to 67.3%±15.2%.Lower food to microorganism ratio may result in a lower N removal rate attributed to the sharply increased biomass concentration fed by glucose.Ammonia-oxidizing bacteria,nitrite-oxidizing bacteria,denitrifying bacteria,and denitrifying phosphorus accumulation organisms enriched during AGS granulation also contributed to the efficient N removal.The proposed strategy provided insights into the relationship between various factors and stable AGS formation,and systemic operation methods for various complicated wastewater treatment.  相似文献   
867.
• Earthworms increase CO2 and N2O emissions in agricultural and forest soil. • 10% biochar suppresses CO2 and N2O emissions in forest soil. • Biochar interacted with earthworm to significant affect CO2 and N2O emissions. The application of manure-derived biochar offers an alternative to avoid the direct application of manure to soil causing greenhouse gas emission. Soil fauna, especially earthworms, can markedly stimulate carbon dioxide (CO2) and nitrous oxide (N2O) emissions from soil. This study therefore investigated the effect of cattle manure biochar (added at rates of 0, 2%, or 10%, coded as BC0, BC2 and BC10, respectively) application, with or without earthworm Aporrectodea turgida, on emissions of CO2 and N2O and changes of physic-chemical properties of agricultural and forest soils in a laboratory incubation experiment. The BC10 treatment significantly enhanced cumulative CO2 emissions by 27.9% relative to the untreated control in the agricultural soil. On the contrary, the BC2 and BC10 treatments significantly reduced cumulative CO2 emissions by 16.3%–61.1% and N2O emissions by 92.9%–95.1% compared to the untreated control in the forest soil. The addition of earthworm alone significantly enhanced the cumulative CO2 and N2O fluxes in agricultural and forest soils. Cumulative CO2 and N2O fluxes were significantly increased when BC2 and BC10 were applied with earthworm in the agricultural soil, but were significantly reduced when BC10 was applied with earthworm in the forest soil. Our study demonstrated that biochar application interacted with earthworm to affect CO2 and N2O emissions, which were also dependent on the soil type involved. Our study suggests that manure biochar application rate and use of earthworm need to be carefully studied for specific soil types to maximize the climate change mitigation potential of such management practices.  相似文献   
868.
以低温热碱破解低有机质污泥,考察了不同热碱条件下低有机质污泥破解情况,通过DNA释放量分析了污泥细胞破解效果,同时,研究了污泥中磷形态分布与变化。结果表明,从污泥破解程度(DD)与DNA释放量来看,热碱联合可强化污泥破解,而pH比温度起更重要作用,尤其对污泥破解释磷起关键作用。高pH条件下,污泥中有机磷(OP)和非磷灰石无机磷(NAIP)以磷酸盐的形式大量溶解,而磷酸盐与钙离子反应导致磷灰石(AP)含量升高。研究认为,仅加碱pH=13即可有效破解低有机质污泥,操作简单,有利于污泥减量,且磷回收潜力大。  相似文献   
869.
根据重力场非潮汐变化的波长特征讨论了由重复重力测量结果中提取地震前兆场信息的可能性。文中提出并应用场论理论中重力梯度场变化的二维散度可突出与地震有比较直接关系的孕震信息。通过对北祁连河西地区几次强震的分析研究,认为重力散度较好地反映了地震发生前震源区的孕震特征,是一种值得进一步研究的方法。  相似文献   
870.
对于富水地层中深埋圆形巷道,为研究多种因素影响下巷道围岩塑性区范围和洞周位移的变化规律,对巷道围岩进行了弹塑性理论分析。对围岩应力场和渗流场进行耦合分析,基于统一强度理论和非关联流动法则,推导出多种因素影响下深埋圆形巷道围岩应力、位移和塑性区半径的解析计算式。结合工程实例进行计算分析,结果表明:中间主应力参数、围岩侧压系数、初始孔隙水压和剪胀角对围岩塑性区径向位移和塑性区范围均有显著影响,但影响规律各不相同;考虑中间主应力作用时,其他各因素的影响效应减弱。综合考虑以上各因素对围岩稳定性的影响,计算结果更加接近工程实际情况。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号