Defining an ecological baseline for restoration and natural resource damage assessment of contaminated sites: The case of the Department of Energy

Retrospective ecological risk assessment, restoration, natural resource damage assessment (NRDA) and managing ecosystems all require having a baseline. This policy and practice paper explores the factors that influence baseline selection, and it is suggested that ecological resources would best be served by: (1) integrating NRDA considerations into both future land-use planning and remediation/restoration; (2) selecting a baseline for NRDA that approximates the land-use conditions at the time of occupation (or a preferred ecosystem); and (3) integrating both the positive and negative aspects of industrial occupation into restoration decisions, baseline selection and NRDA. Under the Comprehensive Environmental Response and Compensation and Liability Act (CERCLA), natural resource damages are assessed for injuries incurred since 1980 due to releases, but the release itself may have occurred before 1980. The paper uses the Department of Energy as a case study to examine NRDA and the management of ecosystems. Releases occurred at many DOE sites from the 1950s to the 1980s during nuclear bomb production. It is suggested that the DOE has been responsible not only for injuries to natural resources that occurred as a result of releases, but for significant ecosystem recovery since DOE occupation, because some lands were previously farmed or industrialized. Natural resource injuries due to releases occurred simultaneously with ecosystem recovery that resulted from DOE occupation. While the 1980 date is codified in CERCLA law as the time after which damages can be assessed, baseline can be defined as the conditions the natural resources would have been in today, but for the release of the hazardous substance. It is also suggested that NRDA considerations should be incorporated into the remediation and restoration process at DOE sites, thereby negating the need for formal NRDA following restoration, and reducing the final NRDA costs.     

Root causes of unsatisfactory performance of large and complex remediation projects: Lessons learned from the united states department of energy environmental management programs

The Consortium for Risk Evaluation with Stakeholder Participation (CRESP) was asked by the United States Department of Energy (US DOE) to consider the root causes of remediation projects that fail to entirely achieve their goals and then to offer suggestions to assist the Department. To begin this project, CRESP held several meetings at which the group defined problematic outcomes, the early symptoms of problematic outcomes, and the root causes of failing to meet expectations. The five root causes are complex science, engineering, and technology; ambiguous economics; project management shortcomings; political processes and credibility; and history and organizational culture. This article, while focusing on the US DOE, provides a larger context for many remediation projects that have failed to entirely live up to their sponsors' expectations. © 2007 Wiley Periodicals, Inc.     

Manatee Mortality in Puerto Rico

Trichechus manatus ) in Puerto Rico is mortality due to human activities. We assessed 90 cases of manatee strandings in Puerto Rico based on historical data and a coordinated carcass salvage effort from 1990 through 1995. We determined patterns of mortality, including type of event, condition of carcasses, spatial and temporal distribution, gender, size/age class, and the cause of death. The spatial distribution of stranding events was not uniform, with the north, northeast, and south coasts having the highest numbers. Six clusters representing the highest incidence included the areas of Fajardo and Ceiba, Bahía de Jobos, Toa Baja, Guayanilla, Cabo Rojo, and Rio Grande to Luquillo. The number of reported cases has increased at an average rate of 9.6%/yr since 1990. The seasonality of stranding events showed a bimodal pattern, from February through April and in August and September. Most identified causes of death were due to human interaction, especially captures and watercraft collisions. Natural causes usually involved dependent calves. From 1990 through 1995, most deaths were attributed to watercraft collisions. A reduction in anthropogenic mortality of this endangered species can be accomplished only through education and a proactive management and conservation plan that includes law enforcement, mortality assessment, scientific research, rescue and rehabilitation, and inter- and intraagency cooperation.     

Ecotoxicological evaluation of pig slurry

Swine sewage could be source of nutrients and pollutants. This work estimates the environmental risk in nine samples from different farm treatment systems based on the evaluation of their effects in Daphnia magna acute test, and on the assessment of Cu, Zn and ammonia as main contributors. NH3 and Cu were responsible for LC50 results (1-5% of dilution). Organic compounds were quantified through several extraction methods (SPMDs, SPE and solvent extraction). A more exhaustive extraction was performed in an additional sample, which showed indole and phenol recoveries much higher than the previous ones. This method also includes PCBs (430 ppb) and fatty acids (approximately =150 ppm) quantification.     

Red soil geochemistry in a semiarid Mediterranean environment and its suitability for vineyards

A geochemical study of a red soil derived from plioquaternary materials was carried out. The soil was located in a region of complex geomorphology and pedologic evolution, with particular characteristics of a Mediterranean climate associated with processes of alteration, rubification, gleying (hydromorphism) and argillization. The depth distribution of 27 trace elements was studied in order to determine the amounts of these elements in the soil and its tendency. The mineralogy of the clay fraction was also studied along with other physico-chemical properties to elucidate in terms of attributes meaningful for viticulture. The geochemical composition of the horizons was studied. The effect of human activities on the soil was investigated as well as the geographical origin of Mancha wines. It was found that these activities did not give rise to significant variations of trace elements, although a discontinuity related to the accumulation of new materials was detected. Ultimately, using established productivity standards, suitability for the cultivation of vines on these soils was determined.     

Negotiating a flexible work arrangement: How women navigate the influence of power and organizational context

Prior work‐life research has highlighted that while organizations may be introducing more work‐life policies, organizational members are not necessarily using these policies. Empirical research is needed that focuses on the individual and provides insight into who is taking advantage of these policies and how they go about negotiating access. In this study, we explore this issue as we investigate the behavioral dynamics that underlie women's experiences negotiating a flexible work arrangement. Focusing on the individual, we examine the influence that perceptions of power and organizational work‐life support have on flexible work arrangement negotiations. The results of our research indicate that both macro level factors such as perceived work life support and micro level factors such as perceptions of power affect both the process and outcomes of these negotiations. We explore the implications these findings have for work‐life and negotiation research. Copyright © 2011 John Wiley & Sons, Ltd.     

Spatial analysis and land use regression of VOCs and NO2 in Dallas, Texas during two seasons

Passive air sampling for nitrogen dioxide (NO(2)) and select volatile organic compounds (VOCs) was conducted at 24 fire stations and a compliance monitoring site in Dallas, Texas, USA during summer 2006 and winter 2008. This ambient air monitoring network was established to assess intra-urban gradients of air pollutants to evaluate the impact of traffic and urban emissions on air quality. Ambient air monitoring and GIS data from spatially representative fire station sites were collected to assess spatial variability. Pairwise comparisons were conducted on the ambient data from the selected sites based on city section. These weeklong samples yielded NO(2) and benzene levels that were generally higher during the winter than the summer. With respect to the location within the city, the central section of Dallas was generally higher for NO(2) and benzene than north and south. Land use regression (LUR) results revealed spatial gradients in NO(2) and selected VOCs in the central and some northern areas. The process used to select spatially representative sites for air sampling and the results of analyses of coarse- and fine-scale spatial variability of air pollutants on a seasonal basis provide insights to guide future ambient air exposure studies in assessing intra-urban gradients and traffic impacts.     

Smart Growth in a Small Urban Setting: The challenges of building an acceptable solution

Smart growth policies direct development towards existing communities already served by roads, sewer systems and other infrastructure. The increased development in these communities in turn should enable them to benefit from a stronger tax-base, more efficient use of their schools and other public facilities, and the renewed economic vitality of their urban centres. These goals and objectives appear to complement and support the efforts of urban mayors to attract new property tax rateables and better-paying jobs, but they may conflict with the desires of residents to reduce densities and improve the quality of life. We use a visual GIS-based model to assist five small contiguous older suburbs individually and collectively to evaluate their current redevelopment plans and to understand the implications of their land-use decisions on the quality of life in their communities. By bringing them together as a group, and our raising broader redevelopment and impact issues, they have begun to rethink how these properties could be best used to meet the community's needs and to see them in the context of similar redevelopment plans within their mini-region. One of the changes emerging is a greater role for certain types of residential development and a concurrent reduction in the amount of commercial space being considered. The authors would like to thank the Geraldine R. Dodge Foundation for funding this project, the Somerset County Planning Board and mayors of the five towns for actively supporting and participating in the study and the Regional Planning Partnership for its co-operation and assistance in refining its GOZ model to promote regional planning from the bottom up. The authors accept full responsibility for the ideas and recommendations in this report.     

Managing Excessive Methanogenesis During ERD/ISCR Remedial Action

Excessive production of methane has been observed at some remediation sites following the addition of organic hydrogen donors such as (emulsified) oils/lecithin, sugars, and conventional carbon + zero‐valent iron (ZVI) amendments. This is due to the fact that methanogens are commonly the most ubiquitous indigenous microbes in anoxic aquifer settings, and, under enriched environmental conditions, methanogens replicate every one to two hours (whereas Dehalococcoides spp., e.g., double in 24–48 hr). Hence, methanogens often bloom and dominate the microbial ecosystem following the addition of remedial amendments, thereby liberating large amounts of methane gas. There are at least three important consequences of this response:

1. By utilizing hydrogen, the methanogens compete with dechlorinating microbes, thus making inefficient use of the remedial amendment (just 20 ppm methane in groundwater represents an approximate 30 percent “waste” of added fermentable substrate (i.e., hydrogen donor)—this is a common and tangible detriment);
2. Methanogens can methylate heavy metals and their rapid growth consumes alkalinity, while generating acidity, thereby facilitating multiple potential mechanisms for creating secondary contaminant issues (i.e., arsenic plumes); and
3. Elevated methane concentrations can exceed current and pending regulations of <10 to <28 ppm methane in groundwater and/or 0.5 percent by volume methane in soil gas (e.g., 10 percent of the lower explosive limit) and/or indoor air (methane is flammable between 5 percent and 15 percent by volume) and this will induce migration of contaminant vapors potentially causing indoor air issues.

Considering the recent guidelines for indoor air published by the US Environmental Protection Agency, it is increasingly important to prevent excessive methanogenesis associated with remedial actions. From a regulatory perspective, public safety issues are paramount; from a property re‐use or real estate (brownfield) developers’ perspective, project delays are costly and can jeopardize an entire program. The use of antimethanogenic compounds as inhibitors of protein biosynthesis and the activity of enzyme systems unique to Archaea (i.e., methanogens) during in situ remedial action can improve contaminant removal while offering safer, more efficacious treatment, simply by impeding the methanogenic bacteria's ability to proliferate and out compete desired bacterial communities (e.g., Dehalococcoides spp.). ©2016 Wiley Periodicals, Inc.     

Road effects on abundance and fitness of Galápagos lava lizards (Microlophus albemarlensis)

Vehicle collisions with wildlife have the potential to negatively impact species everywhere roads divide natural habitats; this is especially true in areas where roads are a recent addition to the landscape (e.g., in the last decade) and/or where expansion of a road network is underway. This study addresses the impact of traffic fatalities on lava lizards, Microlophus albemarlensis, on the island of Santa Cruz, Galápagos. The main road bisecting the island north to south was added to the island beginning in 1974 but not fully paved until 2000. We assessed impacts occurring due to traffic and vehicle speeds on the island. This study adds impacts to lizard populations to those conducted on birds on Santa Cruz, providing a means to create multi-species recommendations. To quantify impacts to lizard populations, we assessed lizards on randomly chosen transects perpendicular to the road. We used Poisson regression to analyze those data and found a 30% increase in lizard abundance per 100 m distance from the road across vegetation zones. We compared incidence of prior tail loss of road-killed lizards and live animals to comment on additional energetic costs of occupying near-road territories. Tail condition could not be assessed in some road-killed lizards; among those that we could assess, 29% showed evidence of prior tail loss. That rate declined to apparent baseline conditions of only 1% beyond 200 m from the road. By traveling the length of the 40-km road, we identified hot spots for fatalities of both lizards and birds to provide necessary information for developing management and remediation strategies. We offer guidance on Best Management Practices, such as testing overpasses, fencing and underpasses, which might reduce vehicle impacts to lizards from drivers on the current road. This information is essential because of a planned increase in the Santa Cruz road network in areas where lava lizards are most abundant.