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961.
962.
Removal of SO2 from O2-containing flue gas by activated carbon fiber (ACF) impregnated with NH3 总被引:1,自引:0,他引:1
Adsorption of SO(2) from the O(2)-containing flue gas by granular activated carbons (GACs) and activated carbon fibers (ACFs) impregnated with NH(3) was studied in this technical note. Experimental results showed that the ACFs were high-quality adsorbents due to their unique textural properties. In the presence of moisture, the desulphurization efficiency for the ACFs was improved significantly due to the formation of sulfuric acid. After NH(3) impregnation of ACF samples, nitrogen-containing functional groups (pyridyl C(5)H(4)N- and pyrrolyl C(4)H(4)N-) were detected on the sample surface by using an X-ray photoelectron spectrometer. These functional groups accounted for the enhanced SO(2) adsorption via chemisorption and/or catalytic oxidization. 相似文献
963.
964.
965.
以计算流体力学软件FLACS为工具,研究了10万m3外浮顶储油罐在处于低液位发生沉顶事故后,油面挥发生成的油气爆炸后在罐区产生的超压、高温及火焰发展状况。研究证明,罐内油气首次爆炸产生的高温并不能对其他罐体造成显著的破坏,但是对罐周平台温度影响较大;由于大型储罐特殊的高径比,爆炸产生的超压较小,不足以形成破坏;首次爆炸产生的火球广度基本在事故罐体直径范围以内,不能对罐外其他罐体形成直接接触。罐区火灾爆炸破坏的主要原因应为多米诺效应产生的池火、泄漏所产生的流淌火、浓烟等次生灾害。 相似文献
966.
Removal of nitric oxide from simulated flue gas via denitrification in a hollow-fiber membrane bioreactor 总被引:1,自引:0,他引:1
Xinyu Zhang Ruofei Jin Guangfei Liu Xiyang Dong Jiti Zhou Aijie Wang 《环境科学学报(英文版)》2013,25(11):2239-2246
A hollow-fiber membrane bioreactor(HMBR) was studied for its ability to treat nitric oxide(NO) from simulated flue gas. The HMBR was operated for 9 months and showed a maximum elimination capacity of 702 mg NO/(m2·day) with a removal efciency of 86%(gas residence time of 30 sec, inlet NO concentration of 2680 mg/m3, pH 8). Varying operation parameters were tested to determine the stability and response of the HMBR. Both the inlet NO concentration and gas residence time influenced the removal of NO in the HMBR. NO elimination capacity increased with an increase in inlet NO concentration or a shortening of gas residence time. Higher removal efciency of NO was obtained at a longer gas residence time or a lower inlet NO concentration. Microbial communities of the HMBR were sensitive to the variation in pH value and alkalescence corresponding to an optimum pH value of 8. In addition, NO elimination capacity and removal efciency were inversely proportional to the inlet oxygen concentration. Sulfur dioxide had no great influence on elimination capacity and removal efciency of NO. Product analysis was performed to study N2O and N2 production and confirmed that the majority of the microorganisms were denitrifying bacteria in the HMBR. Compared to other bioreactors treating NO, this study showed that the denitrifying HMBR was a good option for the removal of NO. 相似文献
967.
铅染毒导致小鼠DNA损伤与氧化损伤 总被引:5,自引:6,他引:5
为了研究亚急性铅暴露对小鼠的遗传毒性及氧化损伤的诱导,将不同剂量的醋酸铅对小鼠隔日灌胃4周,用彗星实验检测其外周血淋巴细胞DNA损伤,并测定肝组织中活性氧自由基(ROS)的水平和脂质过氧化主要终产物丙二醛(MDA)的含量.结果显示,随染铅剂量的增加,小鼠肝线粒体中的ROS水平明显升高,染铅剂量为500 mg·kg-1组与对照组相比有显著性差异;肝MDA含量以及淋巴细胞尾长和尾相显著增加,染铅剂量为50、100、500 mg·kg-1组与对照组相比均有显著性差异;MDA与尾长和尾相的变化趋势一致.诱导产生自由基并导致脂质过氧化作用增强及DNA损伤是铅引起机体损伤的主要机制之一. 相似文献
968.
969.
Whole effluent toxicity (WET) tests, with Daphnia magna and Selenastrum capricornutum, were introduced to evaluate the biological toxicities of effluents from the wastewater treatment plants (WWTPs) in Korea.
In WET tests of WWTPs effluents, 33.3% (33/99) for D. magna and 92.6% (75/81) for S. capricornutum revealed greater than 1 toxic unit (TU), even though all the treatment plants investigated were operating in compliance with
the regulations, as assessed using conventional monitoring methods (i.e., BOD and total concentration of N or P, etc). There
were only minor differences in toxicities according to the types of influents (municipal and agro-industrial) in all treatment
plants. However, the effluents treated by an activated sludge treatment process were found to exhibit significantly lower
toxicity than those treated by rotating biological contactor (RBC) and extended aeration processes. The seasonal variations
in the toxicity were lower in the summer compared to winter, which may have been due to the rainfall received to the sewage
intake system during the former period. The impact of WET on river water was also investigated based on the discharge volume.
At sites A and B, the total impact of toxicity to stream and river waters was observed to be 70.9% and 90.4% for D. magna and S. capricornutum, respectively. The other four small treatment plants (sites F, G, H and I), with relative discharging volumes between 0.001
and 0.002, contribute less than 1% to the total toxicity. 相似文献
970.
三唑酮是一种普遍使用的唑类杀菌剂,其对水生生物的危害已经引起广泛关注。为探讨三唑酮对无脊椎动物的毒性效应和致毒机理,以大型溞为模式生物,开展多代试验,评估不同浓度(5、12.5、25、50、100和200μg·L(-1))的三唑酮对大型溞生长和繁殖以及每代时间间隔的影响。结果表明,暴露21 d后,200μg·L(-1))的三唑酮对大型溞生长和繁殖以及每代时间间隔的影响。结果表明,暴露21 d后,200μg·L(-1)的三唑酮显著降低了大型溞的体长和繁殖能力。转录组分析发现,三唑酮暴露后,F1代和F2代的处理组与对照组的差异表达基因分别为376个和422个,而两代间的差异表达基因共2 604个。通过对差异表达基因的功能富集发现,三唑酮对大型溞F1代影响的主要通路有蛋白质吸收消化、视黄醇新陈代谢、氧化应激和甾类激素生物合成等,对F2代影响的主要通路有抗原处理和呈递、类固醇生物合成和谷胱甘肽代谢等。三唑酮对大型溞可能的毒性作用有氧化应激、内分泌干扰效应、神经毒性和免疫毒性,且可能会存在传代效应。 相似文献