重金属-多氯联苯复合污染土壤同步洗脱

电子垃圾拆解区土壤具有重金属与有机物复合污染的特性,尤其以Cu、Pb、Cd和多氯联苯(PCBs)的复合污染较为突出。为了同步脱除土壤中重金属与PCBs,选用增溶物质:Tween 80、TX-100、SDBS、β-环糊精与螯合剂柠檬酸依次组合进行复合污染土壤淋洗实验,应用批量平衡震荡法研究它们对重金属(Cu、Pb、Cd)与PCBs(Aroclor 1254)的洗脱效果。通过比较洗脱效果、环境友好性等方面,得出非离子表面活性剂Tween 80与天然螯合剂柠檬酸2种淋洗剂复合最佳;进一步研究两者的淋洗先后顺序、浓度配比、洗脱时间及淋洗剂pH对污染土壤洗脱效果的影响,结果表明,在Tween 80和柠檬酸均为10 g/L、pH=6、淋洗时间12 h时淋洗效果达到最佳,对Cu、Pb、Cd及PCBs的洗脱率分别达到98.77%、55.92%、66.82%和58.01%。因此,利用Tween80和柠檬酸组合可同时有效去除土壤重金属和PCBs,是复合污染土壤淋洗修复的有效淋洗剂。     

Trihalomethane reactivity of water- and sodium hydroxide-extractable organic carbon fractions from peat soils

Certain organic carbon moieties in drinking source waters of the Sacramento-San Joaquin Delta can react with chlorine during disinfection to form potentially carcinogenic and mutagenic trihalomethanes. The properties of reactive organic carbon in Delta waters, particularly those of soil origin, have been poorly understood. This study attempts to characterize trihalomethane reactivity of soil organic carbon from three representative Delta peat soils. Soil organic carbon was extracted from all three soils with either deionized H2O or 0.1 M NaOH and sequentially separated into humic acids, fulvic acids, and nonhumic substances for quantitation of trihalomethane formation potential. Water-extractable organic carbon represented only 0.4 to 0.7% of total soil organic carbon, whereas NaOH extracted 38 to 51% of total soil organic carbon. The sizes and specific trihalomethane formation potential (STHMFP) of individual organic carbon fractions differed with extractants. Fulvic acids were the largest fraction in H2O-extractable organic carbon, whereas humic acids were the largest fraction in NaOH-extractable organic carbon. Among the fractions derived from H2O-extractable carbon, fulvic acids had the greatest specific ultraviolet absorbance and STHMFP and had the majority of reactive organic carbon. Among the fractions from NaOH-extractable organic carbon, humic acids and fulvic acids had similar STHMFP and, thus, were equally reactive. Humic acids were associated with the majority of trihalomethane reactivity of NaOH-extractable organic carbon. The nonhumic substances were less reactive than either humic acids or fulvic acids regardless of extractants. Specific ultraviolet absorbance was not a good predictor of trihalomethane reactivity of organic carbon fractions separated from the soils.     

化学清洗技术在安钢D900风机冷却系统的应用

利用化学清洗技术，对风机循环系统、油冷却系统进行杀灭微生物、除垢、去锈、管壁钝化、预膜处理，既保证了高炉的正常生产，又延长了风机的使用寿命。     

社会主义市场经济条件下企业环境保护形势分析及改革建议

在社会主义市场经济条件下如何做好企业的环境保护工作是目前企业环保部门需要探讨的重要问题,通过阐述市场经济对企业环境保护产生的积极影响,分析了当前企业环保的基本状况和存在的问题,并提出了目前企业环保改革的思路。     

Water‐Yield Reduction After Afforestation and Related Processes in the Semiarid Liupan Mountains,Northwest China1

Abstract: The increase of coverage of forest/vegetation is imperative to improve the environment in dry‐land areas of China, especially for protecting soil against serious erosion and sandstorms. However, inherent severe water shortages, drought stresses, and increasing water use competition greatly restrict the reforestation. Notably, the water‐yield reduction after afforestation generates intense debate about the correct approach to afforestation and forest management in dry‐land areas. However, most studies on water‐yield reduction of forests have been at catchment scales, and there are few studies of the response of total evapotranspiration (ET) and its partitioning to vegetation structure change. This motivates us to learn the linkage between hydrological processes and vegetation structure in slope ecosystems. Therefore, an ecohydrological study was carried out by measuring the individual items of water balance on sloping plots covered by different vegetation types in the semiarid Liupan Mountains of northwest China. The ratio of precipitation consumed as ET was about 60% for grassland, 93% for shrubs, and >95% for forestland. Thus, the water yield was very low, site‐specific, and sensitive to vegetation change. Conversion of grassland to forest decreased the annual water yield from slope by 50‐100 mm. In certain periods, the plantations at lower slopes even consumed the runon from upper slopes. Reducing the density of forests and shrubs by thinning was not an efficient approach to minimize water use. Leaf area index was a better indicator than plant density to relate ET to vegetation structure and to evaluate the soil water carrying capacity for vegetation (i.e., the maximum amount of vegetation that can be supported by the available soil water for an extended time). Selecting proper vegetation types and plant species, based on site soil water condition, may be more effective than the forest density regulation to minimize water‐yield reduction by vegetation coverage increase and notably by reforestation. Finally, the focuses in future research to improve the forest‐water relations in dry‐land areas are recommended as follows: vegetation growth dynamics driven by environment especially water conditions, coupling of ecological and hydrological processes, further development of distributed ecohydrological models, quantitative relation of eco‐water quota of ecosystems with vegetation structures, multi‐scaled evaluation of soil water carrying capacity for vegetation, and the development of widely applicable decision support tools.     

微波诱导过硫酸盐修复萘污染土壤的模拟优化

微波 (microwave,MW) 诱导过硫酸盐 (persulfate,PS) 去除土壤中的有机污染物是一种有效的土壤修复手段。以萘为土壤中典型的多环芳烃 (polycyclic aromatic hydrocarbons,PAHs) 有机污染物,利用COMSOL Multiphysics多物理场计算软件模拟,结合电磁耦合理论分析探索了微波电磁辐照过程中土壤有机物消解过程机制,并考察了PS浓度、MW辐照时间、MW温度、土壤含水率等工艺参数对萘去除效果的影响。结果表明,根据仿真优化后,微波反应器具有更好的加热均匀性。在微波谐振腔内,萘的降解过程符合伪一级反应动力学模型,MW诱导PS反应速率常数是常规电加热的1.6倍,这可能是因为极性过硫酸盐分子在微波交变电场的作用下胶体运动趋势增加;同时,多环芳烃有机物在微波场中的土壤传质性能得到优化,降低反应所需的活化能。当PS浓度为1.0 mol·L⁻¹、MW温度为80 ℃、土壤含水率为15%、MW处理时间为60 min时,萘的去除率最高可达到96.5%。本研究结果可为微波诱导过硫酸盐技术在多环芳烃污染土壤修复中的应用提供参考。     

深圳市光环境功能区监管模式研究

根据深圳市地区特点。首先,划分光环境功能区,针对每个光环境功能区,再分成子区域,并提出区域光环境质量标准制定模式;然后,根据光环境的区域划分,结合具体区域功能,对不同光污染源进行划分和规范。提出光污染防护标准制定模式。通过区域光环境质量标准和光污染防护标准的制定,建立相应光环境监管模式,以达到防治光污染,保护和改善光环境,保障人类健康以及生态平衡,保证光的有效利用,构建一个绿色和谐可持续发展的光环境。     

超声波协同纳米铁对偶氮染料橙黄G的脱色研究

采用液相还原法合成出纳米零价铁颗粒,并将其应用于水体中偶氮染料橙黄G的脱色。以橙黄G的脱色率为指标,研究了在超声波协同作用下纳米铁还原脱色偶氮染料橙黄G的过程,并对反应机理进行了初步探讨。结果表明：在无氧环境、室温和中性条件下纳米铁在0.5 h内对橙黄G的脱色率可达99%以上。脱色率随纳米铁用量的增加、pH的降低和反应温度的升高而增大。紫外可见光谱显示,在脱色反应过程中,染料分子中的共轭体系遭到一定程度的破坏。     

城市生态学评价——方法和实例研究

通过对城市生态系统的分析,提出了城市生态学评价的内容、目标和程序。以新建城市博达为例,具体说明了该评价程序的使用方法。     

长江中游盆地地质环境系统演变与防治对策

在构造沉降,泥沙淤积及人工围的相互的相互作用下,长江中游盆地质环境系统分割为演变化方向不同的两部分,堤外水域成为人工过饱盆地,堤内垸地成人为人工饥饿盆地。,长江某些区段及洞庭湖 水位抬升,垸地高程不断降低,洪涝渍害不断加剧。