红外光度法测定石油类和动植物油常见问题探讨

根据石油类在波数为2930cm-1、2960 cm-1、3030 cm-1全部或部分谱带处有物征吸收的原理,采用红外光度测油仪和水样絮凝富集技术测定石油类、动植物油。     

我国安全学科学历教育的困境与对策

我国安全形势严峻的重要原因是安全科技人才缺乏。安全学科学历教育作为我国安全科技高级人才培养的主要渠道之一,为国家造就和输送了大批安全科技人才。但是,由于安全学科学历教育体制没有很好适应市场经济的发展,遇到了不少难以解决的问题。依据对高校和煤炭企业调查所获得的资料,统计发现:目前我国安全学科学历教育所面临的主要问题是专业设置的局限性、培养目标的雷同性和课程设置的低通用性;社会对安全人才需求与目前高校安全专业招生和毕业生就业之间存在的突出矛盾。在详细调研和分析的基础上,提出了相应的安全人才后备队伍建设应采取的对策,即加大政府调控力度、实施“人才兴安”战略,深化教育教学改革、培养高素质安全人才。     

Using consequence analysis on some chlorine operation hazards and their possible effects on neighborhoods in central Taiwan

The applications of chlorine have been broadly used in many industrial products, such as bleaching agents, synthetic rubbers, plastics, disinfectants, iron chlorides, fire refractory materials, insecticides, and anti-freezers, etc. According to the Taiwan Environmental Protection Administration (TEPA), more than 30 thousand tons were used in the year 2000. In addition, there were more than 12 reported incidents from 2000 to 2003—mostly on using chlorine as disinfectants (five) and as process agents (four).

This study investigated 15 chlorine operation plants in central Taiwan. These chlorine usages included bleaching agents, disinfectants, iron chloride, synthesizing rubber plastics, and others. Thirteen plants were located in the industrial parks and two were in or near residential zones. The consequence analysis were used three different methods to analyze the worst-case scenarios (WCSs) and alternative release case scenarios (ACSs) in order to compare impact zones for applying various active and passive mitigation systems, such as confined space, scrubber, water-spray, and so no. For two plants in or near residential zones, multi-layers mitigation systems and operation limits should be implemented in order to enforce more stringent protection measures. However, there was no specific regulation for chlorine plants operated at different locations, such as industrial parks or residential zones. In order to reduce chemical accidents and their impacts on public safety, our results suggest that source mitigation/management and warning systems should be adopted simultaneously.     

操作条件对UF&RO工艺制取纯水效率的影响

采用UF＆RO膜组合工艺制取纯水,考察各项操作条件对系统效率的影响.结果表明,自来水经UF＆RO膜组合工艺装置的出水满足试验纯水水质要求.对于UF系统,冲洗频率、过滤方式和操作压力均影响系统的制水效率.冲洗频率越大,制水效率越高;各种过滤方式中,死端过滤效率最高;在一定范围内,操作压力升高,制水效率反而下降.对于RO系统,应根据出水水质要求,选择合适的回收率和操作压力.     

A comparative study of US EPA 1996 and 1999 emission inventories in the west Gulf of Mexico coast region, USA

Emission inventory is one of the required inputs to air quality models. To assist in the urban and regional modeling efforts, United States Environmental Protection Agency (EPA) has compiled a National Emission Inventory (NEI) for criterion pollutants, and the precursors of ozone and particulate matter (PM). In December 2002, EPA released the 1999 NEI estimates (NEI99), which represent the most recent national emission data. However, the data sets are not in model-ready format for air quality simulations. This present work converts the NEI99 Final Version 2 data sets into Inventory Data Analyzer (IDA) format and processes the data using the Sparse Matrix Operator Kernel Emissions (SMOKE) modeling system to generate a gridded emission inventory in a domain covering the west Gulf Coast Region, USA. The spatial and diurnal emission characteristics of the gridded emission inventories are then assessed and compared with those of the National Emission Trend 1996 (NET96). The NEI99 database contains more complete emission records in both area and point sources. It is also found that NEI99 data exhibit greater emissions with respect to point and mobile sources but smaller emissions with respect to area sources when compared to the corresponding gridded NET96 data in the same study domain. The most distinct differences between the NEI99 and NET96 databases are CO emission of mobile sources, SO2 emissions of point sources, and VOC/PM/NH3/NOx emissions of area and non-road sources. The gridded NEI99 data show low VOC/NOx ratios (<2-5) in the urban areas of the study domain.     

Impact of chemical leaching on permeability and cadmium removal from fine-grained soils

The aim of this study was to investigate the influence of chemical leaching on permeability and Cd removal from fine-grained polluted soils. Column leaching experiments were conducted using two types of soils (i.e., artificially Cd-polluted loam and historically polluted silty loam). Chemical agents of CaCl₂, FeCl₃, citric acid, EDTA, rhamnolipid, and deionized water were used to leach Cd from the soils. Results showed that organic agents reduced permeability of both soils, and FeCl₃ reduced permeability of loam soil, compared with inorganic agents and deionized water. Entrapment and deposition of colloids generated from the organic agents and FeCl₃ treatments reduced the soil permeability. The peak Cd effluence from the artificially polluted loam columns was retarded. For the artificially polluted soils treated with EDTA and the historically polluted soils with FeCl₃, Cd precipitates were observed at the bottom after chemical leaching. When Cd was associated with large colloid particles, the reduction of soil permeability caused Cd accumulation in deeper soil. In addition, the slow process of disintegration of soil clay during chemical leaching might result in the retardation of peak Cd effluence. These results suggest the need for caution when using chemical-leaching agents for Cd removal in fine-grained soils.

     

Effects of productivity on biodiversity in forest ecosystems across the United States and China

In the global campaign against biodiversity loss in forest ecosystems, land managers need to know the status of forest biodiversity, but practical guidelines for conserving biodiversity in forest management are lacking. A major obstacle is the incomplete understanding of the relationship between site primary productivity and plant diversity, due to insufficient ecosystem‐wide data, especially for taxonomically and structurally diverse forest ecosystems. We investigated the effects of site productivity (the site's inherent capacity to grow timber) on tree species richness across 19 types of forest ecosystems in North America and China through 3 ground‐sourced forest inventory data sets (U.S. Forest Inventory and Analysis, Cooperative Alaska Forest Inventory, and Chinese Forest Management Planning Inventory). All forest types conformed to a consistent and highly significant (P < 0.001) hump‐shaped unimodal relationship, of which the generalized coefficients of determination averaged 20.5% over all the forest types. That is, tree species richness first increased as productivity increased at a progressively slower rate, and, after reaching a maximum, richness started to decline. Our consistent findings suggest that forests of high productivity would sustain few species because they consist mostly of flat homogeneous areas lacking an environmental gradient along which a diversity of species with different habitats can coexist. The consistency of the productivity–biodiversity relationship among the 3 data sets we examined makes it possible to quantify the expected tree species richness that a forest stand is capable of sustaining, and a comparison between the actual species richness and the sustainable values can be useful in prioritizing conservation efforts.     

Research status,challenges and future prospects of renewable synthetic fuel catalysts for CO2 photocatalytic reduction conversion

Environmental Science and Pollution Research - In recent years, with global climate change, the utilization of carbon dioxide as a resource has become an important goal of human society to achieve...     

云技术在石油行业应急管理中的思考

面对石油行业突发事件全过程,利用大数据云处理技术,以应急管理4阶段为划分标准,将云技术运用到应急管理四大阶段当中,为解决缺乏合理的信息技术手段、应急信息搜集不全面、数据挖掘分析技术落后、决策支持模型构建不完善等落后的临时性应急管理模式,找寻到一种高效应急管理模式的新方向。     

Partition of Volatile Organic Compounds in Activated Sludge and Wastewater

Abstract

The Henry’s law constant is important in the gas-liquid mass transfer process. Apparent dimensionless Henry’s law constant, or the gas-liquid partition coefficient (K’ _H), for both hydrophilic (methanol, isopropyl alcohol, and acetone) and hydrophobic (toluene and p-xylene) organic compounds in deionized (DI) water, a wastewater with a maximum total dissolved organic carbon (DOC) content of 700 mg/L, and DI water mixed with a maximum activated sludge suspended solid (SS) concentration of 40,000 mg/L were measured using the single equilibrium technique at 293 K.

Experimental results demonstrate that the K’ _H of any of the test volatile organic compounds varied among three situations. First, the K’_H of the hydrophilic compounds in mixed liquor with the maximum SS concentration was 9–21% higher than those in DI water. Second, those for toluene and p-xylene were 77% and 93% lower, respectively, in the mixed liquor with the maximum SS concentration. Third, the K’_H values of all of the test compounds in the wastewater were only 10% lower than those in DI water.

A model was developed to relate K’ _H with wastewater DOC and the SS concentration in the activated sludge using an organic carbon-water partition coefficient and activated sludge-water partition coefficient as model parameters. The model was verified and model parameters for test compounds estimated.