Determination of the dissociation constants of polyepoxysuccinic acid

The dissociation constants of polyepoxysuccinic acid (PESA) were investigated in this study. Based on the potentiometric titration and the BEST program, the dissociation constants of PESA were determined. Considering the complexity of the dissociation of PESA in aqueous solution, several models were constructed to simulate the dissociation process of PESA. By comparison, the dissociation constants of PESA were obtained with model 4. The species distribution of PESA in aqueous solution as a function of pH was also presented according to the experimental and calculation results. It showed that the H₂L model with five basic structure units to describe the dissociation of PESA was reasonable, and the relevant constants had less error and better matching between the experimental and calculation data. The corresponding values of pK _ai were 4.68 and 4.92, respectively, for H₂L at 35°C with ionic strength of 0.1 mol/L.     

低压电网中电力设备保护方式的安全性评价及其对策

对低压电网中电力设备选择接地保护或接零保护时的安全性进行了评价，并针对存在问题提出了改善措施     

试论高压水射流清洗系统的合理匹配

随着高压水射流清洗的应用领域日益广泛， 高压水射流清洗系统的合理匹配已成为急待解决的问题。因为只有高压水射流清洗系统的合理匹配，才能充分发挥高压水射流的高效、高质量清洗及节能、污染小的特点。笔者利用系统分析的方法，从实际应用角度出发，结合理论与实验，从高压泵技术指标的选择、清洗设备的选择及参数简析、清洗压力的选择等几个方面，分析了合理匹配高压水射流清洗系统主要参数的一般方法和原则，并将其应用于铁路罐车的高压水射流清洗系统的匹配。实际应用结果表明，这种方法是行之有效的     

乌鲁木齐市水泥行业污染现状分析

根据乌鲁木齐市水泥行业的验收监测结果,对其污染现状进行了分析。     

听力防护装备为健康筑起安全防线

随着我国工业的发展,噪声危害的分布范围越来越广,人们接触噪声的机会日益增多。长期接触噪声会对人体多个系统产生不良影响,其中尤以对听觉器官的损害最为突出。本文针对噪声的概念及噪声作业听力防护,分析了噪声对人体健康的影响因素及其主要损害,阐述了预防和控制噪声的个体防护装备,提出了噪声性听力损伤的自身防护早发现早防治措施。     

RCM模式在钻探设备维修管理中的应用

引入RCM模式用于钻探设备维修管理,将先进的检测技术与经济意识贯穿设备维修管理环节之中,以可靠性为前提,以经济实用性为原则,以动态管理为主,不断指导设备使用者采取措施,适时改善薄弱部件,实现低投入、高产出,发挥钻探设备的最大效能,进而提高地质勘探单位整体的经济效益。     

火灾消防服装的有效选择

1 前言 自美国"911事件"以来,世界众多国家遭受了恐怖主义疯狂地攻击,使得人们对于安全防护装备的要求越来越严格,不仅需要对各种防护装备的性能重新进行评估,并且提高了对于产品穿着功能的验证要求,尤其是市场抢购的防毒面具及化学防护服,这些个体防护装备的品质要求更需要严守把关.另一方面,因美国市场对于防护服需求骤升的原因,进而创造全球市场商机,使得从事防护服原料、布料开发、服饰制作及检测评估的行业准入者必须重新整合各环节的价值链,共同创造商机.     

全氟异丁烯的毒性和检测防护技术

本文介绍了全氟异丁烯(PFIB)物化性质及产生;总结了其毒性;分析了气相色谱法分析PFIB方法:讨论了人员和环境防护技术.     

2009国际工业安全用品及健康用品（A＋A）展见闻

南中国纺织品商业协会安全健康防护用品委员会陈海达秘书长为团长,国内劳保行业内的部分企业组成的的赴欧洲考察团共13人于2009年10月26日从上海出发抵达巴黎,先后途经法国、比利时、荷兰,于11月4日到达德国杜塞尔多夫,参观了2009国际工业安全用品及健康用品展(A+A).     

Phosphorus release from phosphate rock and iron phosphate by low-molecular-weight organic acids

Low-molecular-weight(LMW) organic acids widely exist in soils, particularly in the rhizosphere. A series of batch experiments were carded out to investigate the phosphorus release from rock phosphate and iron phosphate by low-molecular-weight organic acids.Results showed that citdc acid had the highest capacity to solubilize P from both rock and iron phosphate. P solubUization from rock phosphate and iron phosphate resulted in net proton consumption. P release from rock phosphate was positively correlated with the pκa values. P release from iron phosphate was positively correlated with Fe-organic acid stability constants except for aromatic acids, but was not correlated with pκa. Increase in the concentrations of organic acids enhanced P solubilization from both rock and iron phosphate almost linearly. Addition of phenolic compounds further increased the P release from iron phosphate. Initial solution pH had much more substantial effect on P release from rock phosphate than from iron phosphate.