稻草及稻草循环利用后的废弃物还田效益研究

本文针对中南丘陵水稻产区农田稻草经过稻草直接还田(鲜稻草)、稻草过腹还田(新鲜牛粪)、稻草栽培食用菌后还田(新鲜菌渣)、稻草产沼气后还田(新鲜沼渣)等几种主要的循环利用方式后的废弃物还田,结合化肥配施对水稻产量及土壤基本理化性状影响的研究,以期寻找一种既能达到有机废弃物的循环再利用,改善生态环境,又能够改良土壤理化性状并达到水稻丰产的目的.试验结果显示:相对于常规的化肥施用,几种有机废弃物还田加化肥配施均有利于土壤有机质(1.71%～6.98%),碱解氮(4.30%～15.05%),有效磷(11.22%～21.43%)等养分的提高;增加了土壤团聚体R0.25(干筛6.60%～8.74%,湿筛2.64%～45.06%)、平均质量直径(干筛26.91%～52.69%,湿筛4.55%～32.73%)及几何平均直径(干筛17.88%～35.56%,湿筛3.08%～6.15%);在产量方面,虽较常规施肥有所下降,但经济效益却是增加的,较常规施肥增收75.6元·hm2到1 057.0元·hm2,其中沼渣还田的增益率最高达8.59%.     

Mechanism of limestone corrosion by Gongronella butleri NL-15北大核心CSCD

The key to soil spray-sowing technology is the use of the highly-effective rock-corroding strains, and the mechanism of rock corrosion will provide theoretical references to screen the strains. To investigate the corrosion mechanism of limestone by microorganisms, the dominant and highly-effective limestone-corroding strain Gongronella butleri NL-15 was isolated and purified from the microorganisms on the rock surface. The concentration of calcium (Ca), magnesium (Mg), potassium, and phosphorus was analyzed by ICP. The pH of the fermentation broth of the strain at different intervals was measured using a precise pH instrument. The content of organic acids (critic, succinic, lactic, fumaric, acetic, and propanoic acids) and the scanning electron microscope feature of rock particles in the fermentation broth at different intervals were also analyzed by HPLC. The results showed that the concentration of Ca2+ and Mg2+ in the fermentation broth correlated negatively with the pH value (P < 0.01). The pH of control was 6.87, and that of the fermentation broth after 15 days dropped to 5.12. The concentration of Ca and Mg was 38.96 and 10.85 mg/L respectively, whereas that of the fermentation broth after 15 days increased to 367.56 and 76.16 mg/L respectively. The content of the total organic acids and lactic acid increased with increase in fermentation time. The content of the total organic acids on days 2, 5, 9, and 15 in the fermentation broth was 3.43, 5.40, 6.63, and 7.26 mg/mL, respectively, and the content of lactic acid was 1.79, 2.85, 5.16, and 5.04 mg/mL, respectively. The mycelium of the G. butleri NL-15 adhered to the surface of rock particles and threaded into unconsolidated rocks. Thus, the organic acids, especially lactic acid produced by the fungi G. butleri NL-15, caused unconsolidation of rock and improved the growth of fungi mycelium into the unconsolidated rock. This was the primary cause for limestone corrosion, and the release of Ca and Mg from the rock and its disintegration. © 2018 Science Press. All rights reserved.     

Pyrolysis behaviors of oil sludge based on TG/FTIR and PY-GC/MS

Pyrolysis is an alternative technology for oil sludge treatment. Thermogravimetric Analysis-Fourier Transform Infrared Spectroscopy and Pyrolysis-Gas Chromatography/Mass Spectrometry were employed to investigate the pyrolysis process and products of oil sludge. The pyrolysis process was divided into five stages: drying and gas desorption, oil volatilization, main pyrolysis, semi-coke charring, and mineral decomposition. The main reaction temperatures ranged from 497.6 K to 753.2 K. The products were mainly composed of pairs of alkane and alkene (carbon number ranges from 1 to 27). The mechanisms consisted of random chain scission followed by end chain scission at high temperatures with volatilization occurring during the whole process. This study is useful not only for the proper design of a pyrolysis system, but also for improving the utilization of liquid oil products.     

挥发性有机硫化合物释放及对全球环境的影响

介绍了几种挥发性有机硫化合物：甲硫醚（DMS）、羰基硫（COS）、甲硫醇（MSH或CH3SH）、二硫化碳（CS2）和二甲基二硫（DMDS)从各种自然源（主要是生物源）释放的情况，并论述了有机硫气体释放对全球环境和气候的影响。着重阐述了在海洋、陆地生态系统中，各种生物硫源的释放情况和有机硫气体的迁移、转化规律。讨论了大气中痕量有机硫气体的分析方法，并提出一些建议。     

黄磷乳浊液脱硝及改性研究

采用黄磷乳浊液为吸收剂,考察了黄磷浓度、反应温度、搅拌速度、氧气浓度、烟气流量等影响因素对脱硝率的影响,并且通过添加碳酸钙进行改性,提高了体系的脱硝率。结果表明,脱硝率随黄磷浓度增大、反应温度升高、搅拌速度增大而升高;随烟气流量的增大而下降;加入碳酸钙改性可以明显提高体系脱硝效果;烟气流量400 m L/min,反应温度50℃,搅拌速度1 200 r/min,氧气浓度12%,黄磷浓度6 g/L,碳酸钙浓度2 g/L的条件下,处理NO浓度为0.06%的烟气,反应30 min体系脱硝率可达到84.76%。     

水稻土中半胱氨酸分解产生含硫气体的研究

在室内培养条件下,测定了水稻土中含硫气体的释放．结果表明,该土壤中有硫化氢(Ｈ２Ｓ),羰基硫(ＣＯＳ),二甲基硫(ＤＭＳ)三种气体释放．当土壤中加入半胱氨酸后,ＣＯＳ和Ｈ２Ｓ气体的浓度有了明显增加,并有ＣＳ２和ＣＨ３ＳＨ测出,而ＤＭＳ的浓度变化不大．这些结果表明半胱氨酸的分解可能是 ＣＯＳ,Ｈ２Ｓ,ＣＳ２和 ＣＨ３ＳＨ的产生源之一．在好氧(正常大气)条件下,Ｈ２Ｓ,ＣＯＳ,ＣＳ２和ＣＨ３ＳＨ的释放量低于厌氧(氮气氛围)条件下的释放量,ＤＭＳ则高于厌氧条件下．这表明水稻土中半胱氨酸分解产生 Ｈ２Ｓ,ＣＯＳ,ＣＳ２和 ＣＨ３ＳＨ需较强的还原条件,产生这四种气体的微生物需要严格的厌氧条件．产生ＤＭＳ的微生物则比前者需要高一些的含氧量．在光照条件下,各含硫气体的释放量普遍高于无光照条件下的释放量．释放含硫气体的大多数微生物适宜的含水率为５０%且对土壤的ｐＨ值有一定要求．     

Effect of organic compositions of aerobically pretreated municipal solid waste on non-methane organic compound emissions during anaerobic degradation

Odor pollution caused by municipal solid waste (MSW) treatment plants has become a growing public concern. Although aerobic pretreatment of MSW has advantages in accelerating landfill stabilization, the property of non-methane organic compound (NMOC) emissions from aerobically pretreated MSW (APMSW) during landfilling is unknown. To investigate NMOC emissions from anaerobic degradation of APMSW and to study the impact of organic compositions of APMSW and their decomposition stages, five simulative anaerobic bioreactors (R1-R5) were filled up with APMSW of different original organic compositions in a laboratory. For NMOC analysis, samples were collected from the gas that accumulated separately during two successive independent stages of the whole experiment. The results showed that the cumulative quantities of NMOCs from R1 to R5 were 1.11, 0.30, 0.18, 0.28, and 0.31 mg/kg DM, respectively, when volatile solid was degraded by 34.8-47.2%. As the organic content of the original waste was lower, the proportion of NMOCs generated in the early stage of anaerobic degradation became higher. Multiple linear regression analyses of the relationship between the quantities of degraded organics and generated NMOCs showed that lipid and protein have a strong effect on NMOC amount. The effect of lipid on NMOC quantity lasts longer than that of protein. This observation suggests that controlling the lipid and protein contents in MSW can reduce the odor from landfills.     

采用正交实验优化湿热法处理厨余垃圾的工艺条件

实验采用3因素3水平的正交实验设计方法,研究了湿热法处理厨余垃圾并使其饲料化的加工工艺中,时间、温度、加水量对厨余垃圾饲用价值的影响,选取粗蛋白、粗脂肪、粗纤维、粗灰分、钙和盐分为评价指标,确定反应的最佳工艺条件.实验结果表明,反应的最佳工艺条件为温度100℃、加水量50%、反应时间30 min.     

Mitigation of nutrient losses via surface runoff from rice cropping systems with alternate wetting and drying irrigation and site-specific nutrient management practices

Resource-conserving irrigation and fertilizer management practices have been developed for rice systems which may help address water quality concerns by reducing N and P losses via surface runoff. Field experiments under three treatments, i.e., farmers’ conventional practice (FCP), alternate wetting and drying (AWD), and AWD integrated with site-specific nutrient management (AWD + SSNM) were carried out during two rice seasons at two sites in the southwest Yangtze River delta region. Across site years, results indicated that under AWD irrigation (i.e., AWD and AWD + SSNM), water inputs were reduced by 13.4?~?27.5 % and surface runoff was reduced by 30.2?~?36.7 % compared to FCP. When AWD was implemented alone, total N and P loss masses via surface runoff were reduced by 23.3?~?30.4 % and 26.9?~?31.7 %, respectively, compared to FCP. However, nutrient concentrations of surface runoff did not decrease under AWD alone. Under AWD + SSNM, total N and P loss masses via surface runoff were reduced to a greater extent than AWD alone (39.4?~?47.6 % and 46.1?~?48.3 % compared to FCP, respectively), while fertilizer inputs and N surpluses significantly decreased and rice grain yields increased relative to FCP. Therefore, by more closely matching nutrient supply with crop demand and reducing both surface runoff and nutrient concentrations of surface runoff, our results demonstrate that integration of AWD and SSNM practices can mitigate N and P losses via surface runoff from rice fields while maintaining high yields.     

珠江入海河口经济鱼类重金属含量分析

1999年5－6月和10－11月对珠江三角洲虎门、蕉门、磨刀门3大入海河口的经济鱼类肌肉中重金属残留水平进行了调查分析，结果表明在采集的24个种类鱼样中，Zn、Pb、As3种重金属含量分别为5.789mg/kg、0.987mg/kg、0.207mg/kg，超标率分别为45％、50％、44％。在3大入海口采集的鱼样中，肌肉内重金属含量经方差分析表明，各地点无显著差异，与80年代河口鱼类肌肉重金属含量相比，Zn、Pb、Cr含量有显著差异。