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741.
Jesse H. Bennett A. Clyde Hill David M. Gates 《Journal of the Air & Waste Management Association (1995)》2013,63(11):957-962
A model simulating pollutant exchange with isolated leaves that integrates factors which have been found to be important in regulating pollutant uptake by leaves is presented. The model is patterned after an electrical analogue simulator and was designed to emphasize the effects of pollutant and leaf properties on the process. The article discusses the relative significance of factors affecting gas transfer, sorption of pollutants by leaf surfaces, and pollutant solubility and fate on the uptake process. Data is presented showing uptake of ozone by exposed mesophyll and several epidermal surfaces chosen for their different surface characteristics. The model was used to derive a mathematical expression for the exchange process which was rearranged to define internal (average) pollutant solute concentration in terms of external concentration, leaf and boundary layer diffusion resistance, surface sorption and pollutant solubility. The importance of estimating internal solute concentration is discussed. 相似文献
742.
H.P. Schuchmann K.J. Laidler 《Journal of the Air & Waste Management Association (1995)》2013,63(1):52-53
Recent studies of organic pyrolyses in the presence of nitric oxide have shown that various nitogen compounds, such as hydrogen cyanide (HCN) and aceto-nitrile (CH3CN) are formed. This suggests the possibility that such compounds will be found in internal combustion processes, and may be present in automobile exhaust gases. The present paper describes some gas-chromatographic and wet analyses of exhaust gases. It is concluded that the amounts of hydrogen cyanide are less than 1 ppm, but that various organic nitrogen compounds may reach a level of about 100 ppm. The significance of these results is discussed. 相似文献
743.
J.N. Driscoll A.W. Berger J.H. Becker J.T. Funkhouser J.R. Valentine 《Journal of the Air & Waste Management Association (1995)》2013,63(2):119-122
The nitrate ion selective electrode was investigated as an alternative approach to the present colorimetric determination of nitrate resulting from oxidative absorption of nitrogen oxides from combustion effluents. The electrode offers advantages of speed and relatively simple experimental procedure. Replicate measurements of 10?4–10?2M nitric acid solutions using bracketing standards show that the electrode approach is capable of good precision (coefficient of variation = ±4%). Comparison of a method utilizing the nitrate electrode with the more laborious phenol disulfonic acid method for the measurement of nitrogen oxides in both oil and gas fired combustion effluents showed agreement within 4% of the mean even in the presence of high levels of SO2. The correlation coefficient found for PDS vs nitrate electrode is 0.987. 相似文献
744.
Jesse H. Bennett A. Clyde Hill 《Journal of the Air & Waste Management Association (1995)》2013,63(3):203-206
Concentration profiles for hydrogen fluoride(HF), sulfur dioxide(SO2), ozone (O3), nitrogen dioxide(NO2), and nitric oxide(NO) generated in a standardized alfalfa canopy are presented. Wind, light, temperature, and carbon dioxide(CO2) profiles, canopy pollutant uptake rates, and canopy structural data are also given. Canopy pollutant concentration profile characteristics were studied to evaluate the relative potentials for major air pollutants to penetrate into canopies. The study was conducted in an environmental growth chamber equipped to control automatically environmental conditions and monitor continuously gas exchange rates. HF, SO2, and NO2 profiles suggested that these gases were removed efficiently by the upper portion of the canopy as well as by the immediate subsurface vegetation. The steady state HF profile showed the greatest displacement within the canopy. The NO profile was displaced the least. The uptake rate of NO by plants was apparently too slow in comparison with gas transport and mixing within the canopy to affect the internal profile substantially. O3 appeared to be readily deposited on the surface tissues, but the deeper tissues in the canopy had less effect on the concentration profile. Data are also presented to show the relationship between NO2 concentration within the canopy and changes in the air concentration above the vegetation. The results indicated that gas transport between the atmosphere and canopy interior was rapid. The data presented should be of current interest to agriculturists, researchers, administrators, and environmental planners concerned with effects of air pollutants on plants and on the fate of pollutants in the microenvironment. 相似文献
745.
This is the fourth in the series of Critical Reviews commissioned by the APCA Board of Directors. The first Critical Review "Regulations for the Control of Particulate and Sulfur Oxides Emissions" was published in 1974 and the topic is still timely. The second Critical Review "Regulations for the Control of Hydrocarbon Emissions (from Stationary Sources) and Odorous Pollutants" was published in 1975. In light of recent developments concerning hydrocarbon emissions from stationary sources, this Critical Review is again very timely. The third Critical Review "The Effect of Air Pollution Control Regulations on Land Use Planning" will soon be published in final form. Now we have the fourth in the series, "A Critical Review of Air Pollution Index Systems in the United States and Canada" and "Status Report on Federal Regulations for New Source Performance Standards". 相似文献
746.
R. L Derham G. Peterson R. H. Sabersky F.H. Shair 《Journal of the Air & Waste Management Association (1995)》2013,63(2):158-161
Simultaneous measurements were made of the concentrations of NO, NO2, and CO inside and outside of a building. The building is located in the Los Angeles area, which is heavily polluted by photochemical smog, and the experiments were conducted at a time of the year when the pollutants in question tend to be high. The results shows that there is a direct relationship between the inside and outside concentrations, and that the phase lag between the concentrations depends principally on the ratio of the building volume to the ventilation rate. Although the outside concentrations of the pollutants in question did not follow the same pattern every day, peak concentrations seemed to be related to “rush-hour” traffic. By reducing ventilation rates during these periods, it may be possible to reduce the concentration peaks inside of the building. The building involved in the current study was not located in the immediate vicinity of heavy traffic, and the indoor concentrations of NO, NO2, and CO did not appear to be very severe when compared to those defined by present air quality standards. Finally, the results support the belief that NO and O3 do not co-exist indoors except in very small quantities. 相似文献
747.
Noel de Nevers Albert H. Wehe 《Journal of the Air & Waste Management Association (1995)》2013,63(3):211-215
A natural gas curtailment procedure designed to improve air quality is proposed and discussed. Computer simulations of this approach, in comparison with an approach which ignores environmental factors, shows that the air-quality approach will produce significant improvements in air quality over the non-environmental approach. 相似文献
748.
N.C.G. Freeman T. Wainman P.J. Lioy A.H. Stern S.I. Shupack 《Journal of the Air & Waste Management Association (1995)》2013,63(8):604-605
Honorary Memberships are conferred by the Air Pollution Control Association on persons of widely recognized eminence in some part of the field of air pollution control or who have rendered especially meritorious service to the Association. Honorary Memberships were awarded this year to Dr. Leonard Greenburg and Mr. Milton Reizenstein, both past presidents of APCA. 相似文献
749.
B. R. Hubble Stanley Siegel L. H. Fuchs H. R. Hoekstra B. Tani P. T. Cunningham 《Journal of the Air & Waste Management Association (1995)》2013,63(4):343-346
Abstract Inspection and maintenance programs for motor vehicles in the United States increasingly use loaded mode mass emissions testing (IM240). A method was developed to predict mass emission rates and mass emission changes, particularly from repair benefits, using a low-cost, portable four-gas non-dispersive infrared (NDIR) vehicle exhaust gas analyzer. A single vehicle was tested several times with the analyzer while on the dynamometer and undergoing successive repairs. Excellent correlations for CO and HC were observed. Five vehicles were measured using an on-road driving loop before and after emissions-related repairs, while another three vehicles were tested with no repairs performed. The on-road concentration data used to guide the repair process were converted to grams per gallon; when divided by estimated miles per gallon, this gave grams per mile emissions for comparison to IM240. Correlation coefficients (r2) of 0.87 for CO and 0.76 for HC were achieved for the 13 tests. The linear correlations between IM240 and emissions measured by this method would allow repair facilities to perform a relatively inexpensive test for diagnostic purposes and to estimate repair effectiveness without the need for a dynamometer. 相似文献
750.
August H. Auer Jr. 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1188-1191
Under the auspices of Project METROMEX, studies of visibility de-teoration downwind of St. Louis were conducted during July-August 1974-1975. Estimates of horizontal visual range, standard meteorological data, and aerosol characteristics within the mixing layer were acquired upwind, over, and downwind of the metropolitan area by means of airborne transects. Aerosol number, surface, and volume distributions for particles between 0.025-2.5 µm were generated from the airborne measurement of Aitken nucleus concentrations, cloud condensation nuclei, and aerosols detected in situ with optical probes. Visibility reduction amounting to 50% of prevailing regional upwind visibilities consistently occurs at a distance corresponding to 2-3 hours travel time downwind for an air parcel moving with the mean transport wind. The regions of visibility minimum do not coincide with locations of maximum Aitken nucleus concentrations, but rather correspond in space and time to increased values of cloud condensation nuclei and increased numbers of particles in the 0.1-2.5 µm diameter range. Comparisons of observed aerosol evolution with similar laboratory studies suggest that most of the light scattering aerosols are of secondary origin. 相似文献