Altitudinal distributions of BDE-209 and other polybromodiphenyl ethers in high mountain lakes

The present study shows the occurrence of 2,2′,3,3′,4,4′,5,5′,6,6′-decabromodiphenyl ether (BDE-209) in microbial biofilms of Pyrenean and Tatra high mountain lakes despite its low vapor pressure and high hydrophobicity. Aerosol air transport is therefore a feasible mechanism for BDE-209 accumulation in sites up to 2688 m above sea level. This compound and other PBDEs exhibit altitudinally-dependent distribution involving higher concentrations with increasing mountain lake elevation. However, the apparently very high enthalpies of the concentration gradients observed, including BDE-209, suggest that bacterial anaerobic debromination also plays a significant role in the resulting altitudinal distributions. This microbial mechanism explains the relative abundances of PBDEs and their within lake differences between rocky and sediment microbial biofilms, thereby showing that the altitudinal pattern observed is not purely due to water temperature control on bacterial activity but also to changes in the availability of anaerobic microenvironments which increase with increasing lake productivity at lower altitudes.     

A methodology to determine gaseous emissions in a composting plant

Environmental impacts associated to different waste treatments are of interest in the decision-making process at local, regional and international level. However, all the environmental burdens of an organic waste biological treatment are not always considered. Real data on gaseous emissions released from full-scale composting plants are difficult to obtain. These emissions are related to the composting technology and waste characteristics and therefore, an exhaustive sampling campaign is necessary to obtain representative and reliable data of a single plant. This work proposes a methodology to systematically determine gaseous emissions of a composting plant and presents the results obtained in the application of this methodology to a plant treating source-separated organic fraction of municipal solid waste (OFMSW) for the determination of ammonia and total volatile organic compounds (VOC). Emission factors from the biological treatment process obtained for ammonia and VOC were 3.9 kg Mg OFMSW⁻¹ and 0.206 kg Mg OFMSW⁻¹ respectively. Emissions associated to energy use and production were also quantified (60.5 kg CO₂ Mg OFMSW⁻¹ and 0.66 kg VOC Mg OFMSW⁻¹). Other relevant parameters such as energy and water consumption and amount of rejected waste were also determined. A new functional unit is presented to relate emission factors to the biodegradation efficiency of the composting process and consists in the reduction of the Respiration Index of the treated material. Using this new functional unit, the atmospheric emissions released from a composting plant are directly related to the plant specific efficiency.     

Water consumption in Barcelona and its regional environmental imprint: a long-term history (1717–2008)

We present the evolution of urban water withdrawal and consumption of Barcelona from the eighteenth to the twenty-first centuries. The boundaries of the urban system have been set into the limits of the current municipality, adjusting the data of earlier periods to include the estimated consumption in former municipalities aggregated to the city. Different sorts of water flows have been either recorded or estimated from scant and indirect information, such as local groundwater extractions obtained from a hydrological model calibrated with historical data on variations in the water table. The changes experienced in catching infrastructures, the regional ecological imprint of the domestic or industrial water consumed together with the rates of growth in population, economic activity and water intensity have been taken into account as driving forces. The series obtained reveal an overall increase in accessibility to safe freshwater, and a corresponding extension of water terrestrial imprints of Barcelona over the Catalan river basins, up to the peak reached in 1967?C1970 both for per capita and total water withdrawn. The subsequent downward trend, mainly driven by a lesser water intensity of the local economy, a halt in population growth, and a recently link to the emergence of a New Sustainable Water Culture in Catalan society, stands out against the alleged need for new transfers from farthest basins such as the Ebro or Roine rivers.     

Community Capacity for Watershed Conservation: A Quantitative Assessment of Indicators and Core Dimensions

Community capacity for watershed management has emerged as an important topic for the conservation of water resources. While much of the literature on community capacity has focused primarily on theory construction, there have been few efforts to quantitatively assess community capacity variables and constructs, particularly for watershed management and conservation. This study seeks to identify predictors of community capacity for watershed conservation in southwestern Illinois. A subwatershed-scale survey of residents from four communities located within the Lower Kaskaskia River watershed of southwestern Illinois was administered to measure three specific capacity variables: community empowerment, shared vision and collective action. Principal component analysis revealed key dimensions of each variable. Specifically, collective action was characterized by items relating to collaborative governance and social networks, community empowerment was characterized by items relating to community competency and a sense of responsibility and shared vision was characterized by items relating to perceptions of environmental threats, issues with development, environmental sense of place and quality of life. From the emerging factors, composite measures were calculated to determine the extent to which each variable contributed to community capacity. A stepwise regression revealed that community empowerment explained most of the variability in the composite measure of community capacity for watershed conservation. This study contributes to the theoretical understanding of community capacity by quantifying the role of collective action, community empowerment and shared vision in community capacity, highlighting the need for multilevel interaction to address watershed issues.     

Evaluating the Performance of Volunteers in Mapping Invasive Plants in Public Conservation Lands

Citizen science programs are touted as useful tools for engaging the public in science and for collecting important data for scientists and resource managers. To accomplish the latter, it must be shown that data collected by volunteers is sufficiently accurate and reliable. We engaged 119 volunteers over three years to map and estimate abundance of invasive plants in New York and New Jersey parklands. We tested their accuracy via collected pressed samples and by subsampling their transect points. We also compared the performances of volunteers and botanical experts. Our results support the notion that volunteer participation can enhance the data generated by scientists alone. We found that the quality of data collected might be affected by the environment in which the data are collected. We suggest that giving consideration to how people learn can not only help to achieve educational goals but can also help to produce more data to be used in scientific study.     

Population characteristics of young African women influencing prenatal exposure to DDT (Manhiça, Mozambique)

The concentrations of dichlorodiphenyltrichloroethane (DDT) compounds in cord blood of 214 children born between 2003 and 2006 in Manhiça (Mozambique) have been determined. In this time interval, corresponding to the period before DDT reintroduction for indoor residual spraying, the observed values averaged 0.8 and 0.4 ng/ml for 4,4′-dichlorodiphenyldichloroethylene (4,4′-DDE) and 4,4′-DDT, respectively, and were similar to those found in western countries. However, the 4,4′-DDT/4,4′-DDE ratio was high indicating that the inputs of these compounds arriving to children in utero originated from recent uses of the insecticide. The strongest factor affecting DDT concentration was parity. A well-defined decreasing concentration trend was observed for the cord blood concentrations in the period of study. The trend was also observed for multiparae and primiparae mothers independently. Children from multiparae women showed much lower concentrations than primiparae women. Children from mothers with secondary school level exhibited lower concentrations of these pesticides than mothers with lower degree of education.     

An Efficient Gaussian-Plume Multiple-Source Air Quality Algorithm

The information presented in this paper is directed to air pollution scientists with an interest in applying air quality simulation models. RAM is the three letter designation for this efficient Gaussian-plume multiple-source air quality algorithm. RAM is a method of estimating short-term dispersion using the Gaussian steady-state model. This algorithm can be used for estimating air quality concentrations of relatively stable pollutants for averaging times from an hour to a day in urban areas from point and area sources. The algorithm is applicable for locations with level or gently rolling terrain where a single wind vector for each hour is a good approximation to the flow over the source area considered. Calculations are performed for each hour. Hourly meteorological data required are wind direction, wind speed, stability class, and mixing height. Emission information required of point sources consists of source coordinates, emission rate, physical height, stack gas volume flow and stack gas temperature. Emission information required of area sources consists of south-west corner coordinates, source area, total area emission rate and effective area source height. Computation time is kept to a minimum by the manner in which concentrations from area sources are estimated using a narrow plume hypothesis and using the area source squares as given rather than breaking down all sources to an area of uniform elements. Options are available to the user to allow use of three different types of receptor locations: 1 ) those whose coordinates are input by the user, 2) those whose coordinates are determined by thé model and are downwind óf significant point and area sources where maxima are likely to occur, and 3) those whose coordinates are determined by the model to give good area coverage of a specific portion of the region. Computation time is also decreased by keeping the number of receptors to a minimum.     

Comment on “A Comparative Validation of the RAM and PTMTP Models for Short-Term S02 Concentrations in Two Urban Areas”

The purpose of this paper is to describe oxidant production and transport along the western shore of Lake Michigan. Air quality and meteorological data were collected in this area of the midwest during the summers of 1976–1978 using a ground-based laboratory and an Instrumented aircraft. Ozone, oxides of nitrogen, hydrocarbons (both total and individual), halocarbons, and numerous meteorological parameters were monitored continuously at the ground site near Kenosha, WI. Aircraft measurements included ozone, oxides of nitrogen, condensation nuclei, visual range (nephelometer), sulfur dioxide, temperature, and relative humidity.     

Assessment of lead uptake in reptilian prey species

As part of an investigation determining the trophically available fraction of metals in a model terrestrial food web, i.e., invertebrate prey to Western fence lizards (Sceloporus occidentalis), we evaluated the ability of several invertebrate prey to bioaccumulate lead and to form metals-rich granules, which are hypothesized to be non-available to predators. Crickets (Acheta domestica), tenebroid beetle larvae (Tenebrio molitor), and isopods (Porcellio scaber) were selected as model prey organisms. Lack of standard exposure methodologies for these species has presented a barrier to trophic transfer evaluations, as each species has particular requirements that create challenges for designing exposure conditions. We were able to devise exposure conditions for all three species that allow long-term exposure studies. All prey organisms accumulated lead from contaminated food, and for all species the majority of the accumulated Pb was associated with the exoskeleton (>50%), with metals-rich granules accounting for most of the remaining accumulated lead.     

Field evaluation of digital optical method to quantify the visual opacity of plumes

Visual Determination of the Opacity of Emissions from Stationary Sources (Method 9) is a reference method established by U.S. Environmental Protection Agency (EPA) to quantify plume opacity. However, Method 9 relies on observations from humans, which introduces subjectivity. In addition, it is expensive to teach and certify personnel to evaluate plume opacity on a semiannual basis. In this study, field tests were completed during a "smoke school" and a 4-month monitoring program of plumes emitted from stationary sources with a Method 9 qualified observer to evaluate the use of digital photography and two computer algorithms as an alternative to Method 9. This Digital Optical Method (DOM) improves objectivity, costs less to implement than Method 9, and provides archival photographic records of the plumes. Results from "smoke school" tests indicate that DOM passed six of eight tests when the sun was located in the 140 degrees sector behind one of the three cameras, with the individual opacity errors of 15% or less and average opacity errors of 7.5% or less. DOM also passed seven of the eight tests when the sun was located in the 216 degrees sector behind another camera. However, DOM passed only one of the eight tests when the sun was located in the 116 degrees sector in front of the third camera. Certification to read plume opacity by a "smoke reader" for 6 months requires that the "smoke reader" pass one of the smoke school tests during smoke school. The average opacity errors and percentage of observations with individual opacity errors above 15% for the results obtained with DOM were lower than those obtained by the smoke school trainees with the sun was located behind the camera, whereas they were higher than the smoke school trainee results with the sun located in front of the camera. In addition, the difference between plume opacity values obtained by DOM and a Method 9 qualified observer, as measured in the field for two industrial sources, were 2.2%. These encouraging results demonstrate that DOM is able to meet Method 9 requirements under a wide variety of field conditions and, therefore, has potential to be used as an alternative to Method 9.