In situ ammonia removal in bioreactor landfill leachate

Although bioreactor landfills have many advantages associated with them, challenges remain, including the persistence of NH(3)-N in the leachate. Because NH(3)-N is both persistent and toxic, it will likely influence when the landfill is biologically stable and when post-closure monitoring may end. An in situ nitrogen removal technique would be advantageous. Recent studies have shown the efficacy of such processes; however, they are lacking the data required to enable adequate implementation at field-scale bioreactor landfills. Research was conducted to evaluate the kinetics of in situ ammonia removal in both acclimated and unacclimated wastes to aid in developing guidance for field-scale implementation. Results demonstrate that in situ nitrification is feasible in an aerated solid waste environment and that the potential for simultaneous nitrification and denitrification (even under low biodegradable C:N conditions) in field-scale bioreactor landfills is significant due to the presence of both aerobic and anoxic areas. All rate data fit well to Monod kinetics, with specific rates of removal of 0.196 and 0.117 mgN/day-g dry waste and half-saturation constants of 59.6 and 147 mgN/L for acclimated and unacclimated wastes, respectively. Although specific rates of ammonia removal in the unacclimated waste are lower than in the acclimated waste, a relatively quick start-up of ammonia removal was observed in the unacclimated waste. Using the removal rate expressions developed will allow for estimation of the treatment times and volumes necessary to remove NH(3)-N from recirculated landfill leachate.     

Long Term Trends in Sulphur and Nitrogen Deposition in Europe and the Cause of Non-linearities

Emissions of sulphur and oxidized nitrogen compounds in Europe have been reduced following a series of control measures during the last two decades. These changes have taken place during a period in which the primary gases and the wet deposition throughout Europe were extensively monitored. Since the end of the 1970s, for example land based sulphur emissions declined by between 90 and 70% depending on the region. Over the same period the total deposition of sulphur and its partitioning into wet and dry deposition have declined, but the spatial pattern in the reduction in deposition differs from that of emission and has changed with time. Such non-linearities in the emission-deposition relationship are important to understand as they complicate the process of assessing the effects of emission reduction strategies. Observed non-linearities in terrestrial sulphur emission-deposition patterns have been identified in north west Europe due to increases in marine emissions, and are currently slowing the recovery of freshwater ecosystems. Changes in the relative amounts of SO₂ and NH₃ in air over the last two decades have also changed the affinity of terrestrial surfaces for SO₂ and have therefore changed the deposition velocity of SO₂ over substantial areas. The consequence of this effect has been the very rapid reduction in ambient SO₂ concentration in some of the major source areas of Europe, where NH₃ did not change much. Interactions between the different pollutants, generating non-linearities are now being incorporated in long-range transport models to simulate the effects of historical emission trends and to provide projections into the future. This paper identifies non-linearities in emission deposition relationships for sulphur and nitrogen compounds in Europe using data from the EMEP long-rang transport model and measured concentration fields of the major ions in precipitation and of SO₂ and NO₂ in surface air.     

METHODOLOGIES FOR CALIBRATION AND PREDICTIVE ANALYSIS OF A WATERSHED MODEL1

ABSTRACT: The use of a fitted parameter watershed model to address water quantity and quality management issues requires that it be calibrated under a wide range of hydrologic conditions. However, rarely does model calibration result in a unique parameter set. Parameter nonuniqueness can lead to predictive nonuniqueness. The extent of model predictive uncertainty should be investigated if management decisions are to be based on model projections. Using models built for four neighboring watersheds in the Neuse River Basin of North Carolina, the application of the automated parameter optimization software PEST in conjunction with the Hydrologic Simulation Program Fortran (HSPF) is demonstrated. Parameter nonuniqueness is illustrated, and a method is presented for calculating many different sets of parameters, all of which acceptably calibrate a watershed model. A regularization methodology is discussed in which models for similar watersheds can be calibrated simultaneously. Using this method, parameter differences between watershed models can be minimized while maintaining fit between model outputs and field observations. In recognition of the fact that parameter nonuniqueness and predictive uncertainty are inherent to the modeling process, PEST's nonlinear predictive analysis functionality is then used to explore the extent of model predictive uncertainty.     

Calibration and Verification of SWMM for Low Impact Development

The Storm Water Management Model was used to simulate runoff and nutrient export from a low impact development (LID) watershed and a watershed using traditional runoff controls. Predictions were compared to observed values. Uncalibrated simulations underpredicted weekly runoff volume and average peak flow rates from the multiple subcatchment LID watershed by over 80%; the single subcatchment traditional watershed had better predictions. Saturated hydraulic conductivity, Manning's n for swales, and initial soil moisture deficit were sensitive parameters. After calibration, prediction of total weekly runoff volume for the LID and traditional watersheds improved to within 12 and 5% of observed values, respectively. For the validation period, predicted total weekly runoff volumes for the LID and traditional watersheds were within 6 and 2% of observed values, respectively. Water quality simulation was less successful, Nash–Sutcliffe coefficients >0.5 for both calibration and validation periods were only achieved for prediction of total nitrogen export from the LID watershed. Simulation of a 100‐year, 24‐h storm resulted in a runoff coefficient of 0.46 for the LID watershed and 0.59 for the traditional watershed. Results suggest either calibration is needed to improve predictions for LID watersheds or expanded look‐up tables for Green–Ampt infiltration parameter values that account for compaction of urban soil and antecedent conditions are needed.     

ECONOMIC EFFECTS OF RIVER RECREATION ON LOCAL ECONOMIES1

ABSTRACT: Outdoor recreation is a major, growing use of water resources in the United States. The economic effects of expenditures by visitors to three recreational river sites on local economies surrounding the sites were estimated using an input-output model (IMPL.AN). Expenditure data were from the Public Area Recreation Visitors Study (PARVS). Results indicate that visitor spending stimulates a considerable amount of economic activity and growth in local economies. Economic effects include increases in total gross output ranging from $2.6 million to $13.4 million, increases in total income ranging from $1.2 million to $5.6 million, and increases in employment ranging from 60 to 292 jobs.     

Health,Environmental and Social Justice

Health is a basic human right. Improving health requires social and environmental justice and sustainable development. The 'health for all' movement embraces principles shared by other social movements—in sustainable development, community safety and new economics. These principles include equity, democracy, empowerment of individuals and communities, underpinned by supportive environmental, economic and educational measures and multi-agency partnerships. Health promotion is green promotion and inequality in health is due to social and economic inequality. This paper shows how health, environmental and economic sustainability are inextricably linked and how professionals of different disciplines can work together with the communities they serve to improve local health and quality of life. It gives examples of how local policy and programme development for public health improvement can fit in with global and national policy-making to promote health, environmental and social justice.     

Garbage in garbage out: the contribution of our industrial advancement to wastewater degeneration

Environmental Science and Pollution Research - Natural water sources are habitually marred by insidious anthropogenic practices and municipal wastewater discharges that contain either of xenobiotic...     

Utilizing sustainability criteria to evaluate river basin decision-making: the case of the Colorado River Basin

Regional Environmental Change - Increasing demands, climate change and variability, and over-allocation pose tremendous challenges for the sustainable management of water resources. Federal river...     

Nanomaterials in Biology

Environmental Science and Pollution Research -