Modeling of metal binding in tropical Fluvisols and Acrisols treated with biosolids and wastewater

There is growing concern about the accumulation of metals in tropical agricultural soils. In this study, experimental results from batch studies were used to test whether multi-surface geochemical models could describe metal binding in selected Vietnamese soils. The multi-surface models considered metal binding to iron hydroxides (using the diffuse layer model), organic matter (Stockholm Humic model and NICA-Donnan model), and phyllosilicate clay (Gaines-Thomas equation) as well as complexation to dissolved organic and inorganic ligands in the solution phase. We found that for total dissolved Cd, Cu and Zn the two multi-surface models being tested provided very good model fits for all soils, as evidenced by low root-mean square errors between model predictions and observations. These results suggest that organic matter is an important sorbent for many metals in these soils. However, poor fits were obtained for Cr(III), Mn and Pb for all soils. The study also suggests that the pH is the main factor that controls the solubility of metals in tropical Fluvisols and Acrisols subjected to application of biosolids and wastewater, and that advanced multi-surface models can be used to simulate the binding and release of many trace metals.     

Ten Key Questions About the Management of Water in the Yellow River Basin

Water is scarce in many regions of the world, clean water is difficult to find in most developing countries, there are conflicts between irrigation needs and urban demands, and there is wide debate over appropriate means of resolving these problems. Similarly, in China, there is limited understanding of the ways in which people, groups, and institutions contribute to, are affected by, and respond to changes in water quantity and quality. We use the example of the Yellow River basin to argue that these social, managerial, and policy dimensions of the present water problems are significant and overshadow the physical ones. Despite this, they receive relatively little attention in the research agenda, particularly of the lead agencies in the management of the Yellow River basin. To this end, we ask ten research questions needed to address the policy needs of water management in the basin, split into two groups of five. The first five relate to the importance of water in this basin and the changes that have affected water problems and will continue to do so. The second five questions represent an attempt to explore possible solutions to these problems.     

IMPLICATIONS OF FEEDBACK PROCESSES IN PLANT WATER USAGE AND RESULTING CLIMATE CHANGE1

ABSTRACT: Increased carbon dioxide in the atmosphere has the secondary effect on plants of reducing transpiration. The degree of reduction in transpiration has been studied mostly at the leaf scale and as such, has not taken feedbacks into account that come into play when the plant canopy or the atmosphere as a whole is considered. The objective of this paper is to examine the role of negative feedback processes that act through the dynamics of the canopy and the atmosphere. This is done through the application of two canopy models, one of which is later coupled to a full Atmospheric General Circulation Model (AGCM) called GENESIS. The results suggest that the reduction in transpiration in a double CO₂ environment compared to present day will not be as considerable as the leaf scale experiments suggest ‐ a 7 percent reduction compared to 15 to 57 percent when feedbacks are considered. At the regional scale, precipitation patterns appear to be the primary factor in determining evapotranspiration. The implications for agriculture, in terms of water usage, would therefore not seem to be as acute as the leaf scale experiments depict. Regarding climate change, there is a suggestion that regional water usage may vary from present day values in certain areas.     

Sexual dimorphism and the mating ecology of polar bears (Ursus maritimus) at Svalbard

We assessed the role of size, mass, and age in mating and non-mating polar bears (Ursus maritimus) at Svalbard, Norway, during the spring breeding season. The ratio of male to female mass, in male-female pairs, ranged from 1.00 to 3.02 ([`(x)] = 1.99 \overline x = 1.99 ) indicating that mating males were larger than mating females but with substantial variation. Paired males were older than unpaired males and male mass was related to age. However, males paired with females were not significantly different in body mass from those males caught alone. Wounds and scars resulting from fights between males began at about 6 years of age and peaked at about 17 and 20 years of age, respectively. The frequency of broken canines in males, presumably due to increased male-male conflicts, increased with age but showed little increase in females. The wide range of male size in male-female pairs and the age-related signs of injury suggest that male polar bears engage in both scramble competition and contest competition for access to breeding females. The mating system of polar bears is variable but is best described as female defense polygyny or serial monogamy.     

Research note: Job design and technology: A sociotechnical systems perspective

This study is a constructive replication of investigations into the technology-job design relationship. It is hypothesized that the utilization of a preprogrammed/system controlled technology reduces environmental variance resulting in routine (simple) versus non-routine (complex) job designs. Empirically it was noted that employees perceive and describe their jobs as routine when they interact with a system controlled technology.     

Bioeconomic models of marine recreational fishing

The theory of recreational fishing is developed and conditions are derived for optimal management policy, with special attention given to functional relationships that must be empirically verified. Determinants of the optimal allocation between commercial and recreational fishing effort are derived. The theory is extended to include selected peculiar features of recreational fishing: Some anglers sell their catch; a small proportion of the fishing population accounts for a large proportion of the catch; and anglers throw back a fraction of what they catch. Optimal policies are derived under these more realistic conditions.     

Psychological ownership and feelings of possession: three field studies predicting employee attitudes and organizational citizenship behavior

An increasing number of scholars and practitioners have emphasized the importance of ‘feelings of ownership’ for the organization (even when employees are not legal owners). In this exploratory study, we examine the relationships of psychological ownership with work attitudes and work behaviors. We start by developing hypotheses based on the psychology of possession and psychological ownership literatures. We then test these hypotheses with data from three field samples, using responses from over 800 employees, as well as manager and peer observations of employee behavior. Results demonstrate positive links between psychological ownership for the organization and employee attitudes (organizational commitment, job satisfaction, organization‐based self‐esteem), and work behavior (performance and organizational citizenship). More important, psychological ownership increased explained variance in organization‐based self‐esteem and organizational citizenship behavior (both peer and supervisor observations of citizenship), over and above the effects of job satisfaction and organizational commitment. Contrary to prior theoretical work on psychological ownership, results, however, fail to show an incremental value of psychological ownership in predicting employee performance. Copyright © 2004 John Wiley & Sons, Ltd.     

OPTIMAL CAPACITIES OF WATER SUPPLY RESERVOIRS IN SERIES AND PARALLEL1

ABSTRACT: The planning of water supply reservoirs has traditionally been based on the Rippl or sequent peak analysis which applies to the design of a single reservoir. This paper incorporates the sequent peak method as the central feature in establishing a procedure for determining the sizes of several potential reservoirs located in a system of one or more rivers. Separate algorithms are developed for sites on parallel streams and for sites on the same stream. In both cases the approach is to find the combination of reservoirs which can satisfy a given constant monthly demand at a minimum total construction cost. It is shown that both problems can be cast in the form of a dynamic programming problem. A more complex system is then a combination of reservoirs in parallel and in series. An extension is given if the monthly demand is not constant but each reservoir satisfies a constant fraction of the monthly demand.