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151.
Unai Iriarte-Velasco Jon I. Álvarez-Uriarte Juan R. González-Velasco 《Environmental Chemistry Letters》2006,4(4):243-247
Ultraviolet (UV) spectroscopy is a valid surrogate for monitoring the formation of disinfection by-products (DBPs). Sodium thiosulphate is commonly used to remove disinfectant residual. However, it produces interferences with absorbance in the UV region. Relationship between trihalomethane (THM) formation and differential UV absorbance (−ΔA
λ
) was explored in the presence of sodium thiosulphate. Chlorination of two synthetic and five natural waters was carried out. Sodium thiosulphate showed high UV absorption at 254 nm. This effect can be overcome selecting a higher wavelength. Optimum wavelength varied being about 290 nm for fulvic acid and 300 nm for humic acid type natural organic matter. Correlation between THMs formation and −ΔA
λ
was linear for all the analysed samples. Regression curves do not pass through zero indicating the existence of a threshold absorbance decreasment. Once it is surpassed THM release begins. Chlorination of surface waters showed that the presence of bromide significantly increases THMs vs. −ΔA
λ
slope. Furthermore, slope decreased with the aromaticity–hydrophobicity of organic matter. 相似文献
152.
The geographic distribution of the animals of Venezuela was analyzed as a basis for a series of guidelines to help develop strategies for their conservation. A total of 313 animal taxa is distributed among 24 geographic units, corresponding to the political divisions of the country. Three different criteria were considered in analyzing these data: (1) the number and density of threatened taxa were used to define a ranking system for geographic units; (2) "hotspots" were identified using the distribution of threatened endemics, and (3) a "critical faunas analysis" was used to determine the minimum number of geographic units needed to maximize the number of sampled taxa. The first two criteria emphasize the importance of protecting habitat in the northern portion of the country, where most human intervention has already taken place. But the southern portion of the country is where most of the undisturbed habitat remains. We suggest that the conservation of the animals of Venezuela must follow a mixed strategy, based on two principles: one, aimed mainly at threatened endemics, should focus on the protection of critical habitat north of the Orinoco river, the second, aimed at all threatened animals— particularly high-risk taxa—should focus on assuring the long-term persistence of the pristine habitat in the south. 相似文献
153.
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156.
Hronn Egilsdottir Fanny Noisette Laure M.-L. J. Noël Jon Olafsson Sophie Martin 《Marine Biology》2013,160(8):2103-2112
Marine organisms inhabiting environments where pCO2/pH varies naturally are suggested to be relatively resilient to future ocean acidification. To test this hypothesis, the effect of elevated pCO2 was investigated in the articulated coralline red alga Corallina elongata from an intertidal rock pool on the north coast of Brittany (France), where pCO2 naturally varied daily between 70 and 1000 μatm. Metabolism was measured on algae in the laboratory after they had been grown for 3 weeks at pCO2 concentrations of 380, 550, 750 and 1000 μatm. Net and gross primary production, respiration and calcification rates were assessed by measurements of oxygen and total alkalinity fluxes using incubation chambers in the light and dark. Calcite mol % Mg/Ca (mMg/Ca) was analysed in the tips, branches and basal parts of the fronds, as well as in new skeletal structures produced by the algae in the different pCO2 treatments. Respiration, gross primary production and calcification in light and dark were not significantly affected by increased pCO2. Algae grown under elevated pCO2 (550, 750 and 1000 μatm) formed fewer new structures and produced calcite with a lower mMg/Ca ratio relative to those grown under 380 μatm. This study supports the assumption that C. elongata from a tidal pool, where pCO2 fluctuates over diel and seasonal cycles, is relatively robust to elevated pCO2 compared to other recently investigated coralline algae. 相似文献
157.
Scott Elliott Gerald E. Streit Jeffrey S. Gaffney James E. Bossert Michael Brown Jon Reisner Laurie A. McNair 《Environmental science and pollution research international》1999,6(2):103-105
The nerve agent sarin has recently been deployed by terrorists in a major city. The molecule is volatile and made its way
to many victims by passing as vapor through a highly reactive medium. Here we estimate rates and pathways for the removal
of gas phase sarin from a generalized urban atmosphere. Only information from the open scientific literature is used. By structure
reactivity comparisons with the organophosphorus pesticides, hydroxyl radical hydrogen abstraction may occur in as little
as one hour. Decomposition of side chains after hydroxyl attack leads to organic oxygenates which preserve the phosphonofluoridate
and so toxicity. The aqueous aerosol surface is contacted in minutes and offers access to a range of dissolved nucleophiles.
Substitution displaces the fluoride leaving group, giving safe phosphoric acid analogs. Because of uncertainties in the electron
distribution and in aqueous decay mechanisms, the time constants must be viewed as lower limits. 相似文献
158.
Li Maotian Finlayson Brian Webber Michael Barnett Jon Webber Sophie Rogers Sarah Chen Zhongyuan Wei Taoyuan Chen Jing Wu Xiaodan Wang Mark 《Regional Environmental Change》2017,17(4):1153-1161
Regional Environmental Change - Many of the world’s major cities are expected to face significant water shortages in coming decades, largely due to increased demand arising from economic and... 相似文献
159.
This paper studies the practice of semi-domestic reindeer (Rangifer t. tarandus) herding in Finnmark county in northern Norway. In this area, the Saami reindeer herders compete for space and grazing areas and keep large herds, while at the same time, the reindeer population is heavily exposed to carnivore predation by the lynx (Lynx lynx), the wolverine (Gulo gulo), and the golden eagle (Aquila chrysaetos). It is demonstrated that predation actually may improve the economic lot of livestock holders in this unmanaged local common setting. There are ecological as well as economic reasons as to why this happens. The ecological reason is that predation compensates for natural mortality; that is, increased predation reduces natural mortality, indicating that the net loss due to predation actually may be quite small. When predation reduces livestock density, the feeding conditions of the animals will improve, resulting in increased livestock weight and higher per animal slaughter value. At the same time, a smaller stock reduces the operating costs of the herders. 相似文献
160.
Andrew O. Hughes Jon M. Olley Jacky C. Croke Ian T. Webster 《Journal of environmental radioactivity》2009,100(10):858-865
Fallout 137Cs has been widely used to determine floodplain sedimentation rates in temperate environments, particularly in the northern hemisphere. Its application in low fallout, tropical environments in the southern hemisphere has been limited. In this study we assess the utility of 137Cs for determining rates of floodplain sedimentation in a dry-tropical catchment in central Queensland, Australia. Floodplain and reference site cores were analysed in two centimetre increments, depth profiles were produced and total 137Cs inventories calculated from the detailed profile data. Information on the rates of 137Cs migration through local soils was obtained from the reference site soil cores. This data was used in an advection–diffusion model to account of 137Cs mobility in floodplain sediment cores. This allowed sedimentation rates to be determined without the first year of detection for 137Cs being known and without having to assume that 137Cs remains immobile following deposition. Caesium-137 depth profiles in this environment are demonstrated to be an effective way of determining floodplain sedimentation rates. The total 137Cs inventory approach was found to be less successful, with only one of the three sites analysed being in unequivocal agreement with the depth profile results. The input of sediment from catchment sources that have little, or no, 137Cs attached results in true depositional sites having total inventories that are not significantly different from those of undisturbed reference sites. 相似文献