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101.
The evaluation of a novel prototype instrument designed for on-site determinations of VOC mixtures found in indoor working environments is described. The instrument contains a miniature multi-stage preconcentrator, a dual-column separation module with pressure-tunable retention capabilities, and an integrated array of three polymer-coated surface acoustic wave sensors. It was challenged with dynamic test-atmospheres of a set of 15 common indoor air contaminants at parts-per-billion concentrations within a stainless-steel chamber under a range of conditions. Vapours were reliably identified at a known level of confidence by combining column retention times with sensor-array response patterns and applying a multivariate statistical test of pattern fidelity for the chromatographically resolved vapours. Estimates of vapour concentrations fell within 7% on average of those determined by EPA Method TO-17, and limits of detection ranged from 0.2 to 28 ppb at 25 degrees C for 1 L samples collected and analyzed in <12 min. No significant humidity effects were observed (0-90% RH). Increasing the chamber temperature from 25 to 30 degrees C reduced the retention times of the more volatile analytes which, in turn, demanded alterations in the scheduling of column-junction-point pressure (flow) modulations performed during the analysis. Reductions in sensor sensitivities with increasing temperature were predictable and similar among the sensors in the array such that most response patterns were not altered significantly. Short-term fluctuations in concentration were accurately tracked by the instrument. Results indicate that this type of instrument could provide routine, semi-autonomous, near-real-time, multi-vapour monitoring in support of efforts to assess air quality in office environments. 相似文献
102.
Kyu Tae Lee Seongjin Hong Jung Suk Lee Kyu Hyuck Chung Klara Hilscherová John P. Giesy Jong Seong Khim 《Environmental science and pollution research international》2013,20(12):8590-8599
While the World Health Organization 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) equivalency factors are useful estimates of relative potencies of mixtures when conducting risk assessments, they are not useful when comparing the results of bioassays such as the H4IIE-luc to concentrations of TCDD equivalents calculated from instrumental analyses. Since there are thousands of dioxin-like compounds (DLCs), one use of screening assays is to determine if all of the aryl hydrocarbon receptor (AhR) active DLCs in a mixture have been accounted for in instrumental analyses. For this purpose, bioassay-specific relative potency (ReP) values are needed. RePs of 21 polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, and dioxin-like polychlorinated biphenyls that exhibit effects mediated through the AhR were determined by use of the H4IIE-luc assay. Different values of RePs are derived, depending on the statistical, curve-fitting methods used to derive them from the dose–response relationships. Here, we discuss the various methods for deriving RePs from in vitro data and their assumptions and effects on values of RePs. Full dose–response curves of 2,3,7,8-TCDD and other representative DLCs were used to estimate effective concentrations at multiple points (e.g., EC20-50-80), which were then used to estimate ReP of each DLC to 2,3,7,8-TCDD. 相似文献
103.
Levels and patterns of polycyclic aromatic hydrocarbons (PAHs) in soils after forest fires in South Korea 总被引:1,自引:0,他引:1
Kim EJ Choi SD Chang YS 《Environmental science and pollution research international》2011,18(9):1508-1517
Introduction
To investigate the influence of biomass burning on the levels of polycyclic aromatic hydrocarbons (PAHs) in soils, temporal trends and profiles of 16 US Environmental Protection Agency priority PAHs were studied in soil and ash samples collected 1, 5, and 9 months after forest fires in South Korea. 相似文献104.
Performance of an immobilized cell biofilter for ammonia removal from contaminated air stream 总被引:3,自引:0,他引:3
The performance of a lab scale biofilter packed with biomedia, encapsulated by sodium alginate and polyvinyl alcohol was used for treating ammonia (NH(3)) gas at different loading rates. The metabolic end products during NH(3) oxidation were NH(4)(+), NO(3)(-) and NO(2)(-). It is noteworthy to mention that the immobilized cell biofilter required no separate acclimatization period and showed high removal efficiencies during the start of continuous experiments. The removal efficiency was nearly 100% when ammonia loading was 4.5gm(-3)h(-1) and the maximum elimination capacity achieved in this study was 5.5gNH(3)m(-3)h(-1) at a loading rate of 7.5gm(-3)h(-1). Shock loading studies were carried out to ascertain the response of the immobilized cells to fluctuations in inlet concentration and flow rate. The inlet loading rates were varied between 0.05 and 6gNH(3)m(-3)h(-1) during this phase of operation. The biofilter responded effectively to these shock loading conditions and recovered rapidly within 4-8h. Pressure drop values were consistently less and insignificant. The results from this study indicated that this immobilized cell biofilter could be considered as a potential option to treat NH(3) under steady and transient state operation. 相似文献
105.
106.
107.
Human health risk assessment of explosives and heavy metals at a military gunnery range 总被引:1,自引:0,他引:1
In this research, a risk assessment was undertaken in order to develop the remediation and management strategy of a contaminated
gunnery site, where a nearby flood controlling reservoir is under construction. Six chemicals, including explosives and heavy
metals, posing potential risk to environmental and human health, were targeted in this study. A site-specific conceptual site
model was constructed, based on effective, reasonable exposure pathways, to avoid any overestimation of the risk. Also, conservative
default values were adapted to prevent underestimation of the risk when site-specific values were not available. The risks
posed by the six contaminants were calculated using the API’s Decision Support System for Exposure and Risk Assessment, with
several assumptions. In the crater-formed-area (Ac), the non-carcinogenic risks (i.e., HI values) of tri-nitro-toluene (TNT)
and Cd were slightly larger than 1, but for RDX (Royal Demolition Explosives) was over 50. The total non-carcinogenic risk
of the whole gunnery range was calculated to be 62.5, which was a significantly high value. The carcinogenicity of Cd was
estimated to be about 10−3, while that for Pb was about 5 × 10−4, which greatly exceeded the generally acceptable carcinogenic risk level of 10−4–10−6. It was concluded from the risk assessment that there is an immediate need for remediation of both carcinogens and non-carcinogens
before construction of the reservoir. However, for a more accurate risk assessment, further specific estimations of the changes
in environmental conditions due to the construction of the reservoir will be required; and more over, the effects of the pollutants
to the ecosystem will also need to be evaluated. 相似文献
108.
Food and Environmental Virology - Retail foodservice establishments (FSE) frequently utilize washes with sanitizing agents during fresh produce preparation. This study evaluated the efficacy of... 相似文献
109.
Youngjae Yu Keun-Young Park Jaehyun Jung Wonjung Song Jaehyeok Kim Junhee Ryu Harshad Lade Jihyang Kweon 《环境科学学报(英文版)》2019,31(4):247-256
A monitoring method of biofouling in reverse osmosis (RO) system was proposed based on the fluorescent signal of resorufin, which is reduced by nicotinamide adenine dinucleotide released from viable cells during aerobic respiration. The fluorescent signal of resorufin reduced by planktonic cells and microorganisms of biofilm showed linearity, indicating its feasibility to monitor biofouling in a RO system. For the application of the method to the lab-scale RO system, the injection concentration of resazurin and the injection flow rate were optimized. Biofilm on RO membranes continuously operated in a lab-scale RO system was estimated by resorufin fluorescence under optimized detection condition. As a result, resorufin fluorescence on RO membrane showed a significant increase in which the permeability of RO system decreased by 30.48%. Moreover, it represented the development of biofilm as much as conventional biofilm parameters such as adenosine triphosphate, extracellular polymeric substances, and biofilm thickness. The proposed method could be used as a sensitive and low-cost technology to monitor biofouling without autopsy of membranes. 相似文献
110.
Sungwoon Jung Jaehyun Lim Sangil Kwon Sangwoo Jeon Jeongsoo Kim Jongtae Lee Sunmoon Kim 《环境科学学报(英文版)》2017,29(4):21-32
Emission characterization of particle number as well as particle mass from three diesel passenger cars equipped with diesel particulate filter(DPF), diesel oxidation catalyst(DOC)and exhaust gas recirculation(EGR) under the vehicle driving cycles and regulatory cycle.Total particle number emissions(PNEs) decreased gradually during speed-up of vehicle from 17.3 to 97.3 km/hr. As the average vehicle speed increases, the size-segregated peak of particle number concentration shifts to smaller size ranges of particles. The correlation analysis with various particulate components such as particle number concentration(PNC),ultrafine particle number concentration(UFPNC) and particulate matter(PM) mass was conducted to compare gaseous compounds(CO, CO_2, HC and NOx). The UFPNC and PM were not only emitted highly in Seoul during severe traffic jam conditions, but also have good correlation with hydrocarbons and NOxinfluencing high potential on secondary aerosol generation. The effect of the dilution temperature on total PNC under the New European Driving Cycle(NEDC), was slightly higher than the dilution ratio. In addition, the nuclei mode(DP: ≤ 13 nm) was confirmed to be more sensitive to the dilution temperature rather than other particle size ranges. Comparison with particle composition between vehicle speed cycles and regulatory cycle showed that sulfate was slightly increased at regulatory cycle, while other components were relatively similar. During cold start test, semivolatile nucleation particles were increased due to effect of cold environment. Research on particle formation dependent on dilution conditions of diesel passenger cars under the NEDC is important to verify impact on vehicular traffic and secondary aerosol formation in Seoul. 相似文献