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161.
The identification and quantitation of non-method-specific target analytes have greater importance with respect to EPA's current combustion strategy. The risk associated with combustion process emissions must now be characterized. EPA has recently released draft guidance on procedures for the collection of emissions data to support and augment site-specific risk assessments (SSRAs) as part of the hazardous waste incineration permitting process. This guidance includes methodology for quantifying total organic (TO) emissions as a function of compound volatility. The ultimate intent is to compare the amount of organic material identified and quantified by target analyte-specific methodologies to organic emissions quantified by the TO methodology. The greater the amount accounted for by the target analyte-specific methodologies, the less uncertainty may be associated with the SSRAs. A limitation of this approach is that the target analyte-specific methodologies do not routinely quantify compounds of low toxicological interest; nor do they target products of incomplete combustion (PICs). Thus, the analysis can miss both toxic and non-toxic compounds. As a result, it is unknown whether the uncharacterized fraction of the TO emission possesses toxic properties. The hypothesis that we propose to test is that organic emissions and organics extracted from particulate matter (PM) are more complex than standard GC-MS-based instrumentation can currently measure. This complexity can affect quantitation for toxic compounds, thereby potentially affecting risk assessments. There is a pressing need to better characterize these organic emissions from hazardous waste incinerators and PM extracts from various other combustion sources. We will demonstrate that multidimensional gas chromatography-mass spectrometry (MDGC-MS) procedures significantly improve chromatographic separation for complex environmental samples. Sequential repetitive heart-cutting MDGC, with coupled mass spectrometry will be shown to be a complete analysis technique. The ability of this technique to disengage components from complex mixtures taken from hazardous and municipal waste incinerators will be shown. 相似文献
162.
Jamieson RC Joy DM Lee H Kostaschuk R Gordon RJ 《Journal of environmental quality》2005,34(2):581-589
In this study, a tracer bacteria was used to investigate the resuspension and persistence of sediment-associated bacteria in a small alluvial stream. The study was conducted in Swan Creek, located within the Grand River watershed of Ontario, Canada. A 1.1-m2 section of the bed was seeded with a strain of Escherichia coli resistant to nalidixic acid (E. coli NAR). The survival, transport, and redistribution of the tracer bacteria within a 1.7-km river section downstream of the source cell was assessed for a 2-mo period following the introduction of the tracer bacteria. This study has illustrated that enteric bacteria can survive in bed sediments for up 6 wk and that inactivation of the tracer bacteria resembled typical first-order decay. Critical conditions for resuspension, as well as resuspension rates, of sediment-associated bacteria were determined for several storm events. The critical shear stress for E. coli NAR resuspension in Swan Creek ranged from 1.5 to 1.7 N m(-2), which is comparable with literature values for critical shear stresses for erosion of cohesive sediments. Bacteria resuspension was primarily limited to the rising limb of storm hydrographs implying that a finite supply of sediment-associated bacteria are available for resuspension during individual storm events. The information presented in this paper will further the development of representative microbial water quality models. 相似文献
163.
Jack Brondum Kenneth Spitalny Julian A. Waller Joy L. Herndon Richard L. Vogt 《Journal of Safety Research》1985,16(4):143-148
The Vermont Department of Health carried out two studies of snowblower injuries in Vermont during the winters of 1982–1983 and 1983–1984. The first was a case-control study in which we assessed risk factors that predisposed operators to injury during snowblower use. We found 20 persons who had been injured by snowblowers and matched 28 controls to these by neighborhood. In this study, owning a snowblower for 1 year or less and having operated a snowblower for 10 days or less in one's lifetime were significantly associated with injury. The second study was population-based. We estimated that approximately 1.5% of Vermont residents owned snowblowers during the winter of 1982–1983 and that, among snowblower owners, injuries occurred at a rate of 1.3/1,000 person-years of ownership (0.1% chance of injury). 相似文献
164.
ABSTRACTA commoning framework offers a critical lens to fully appreciate the scope and impact of alternative food networks (AFNs). Fieldwork from an AFN in southern China is drawn upon to show how commoning enacts changes in how members contextualise and anchor their social relations to one another with regards to sourcing food as a commons. A commoning framework gives a fuller picture of how the constitutive effects of AFNs reside not in their introduction of a new uniformity but in their navigation of the multiplicity of the social through its proposition and co-construction of a new ‘cognitive praxis’. 相似文献