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81.
Understanding the fate and transport of petroleum hydrocarbons from coal tar within gasholders 总被引:1,自引:0,他引:1
Coal tars have been identified as posing a threat to human health due to their toxic, mutagenic and carcinogenic characteristics. Workers involved in former gasholders decommissioning are potentially exposed to relevant concentrations of volatile and semi-volatile hydrocarbons upon opening up derelict tanks and during tar excavation/removal. While information on contaminated sites air-quality and its implications on medium-long term exposure is available, acute exposure issues associated with the execution of critical tasks are less understood. Calculations indicated that the concentration of a given contaminant in the gasholder vapour phase only depends on the coal tar composition, being only barely affected by the presence of water in the gasholder and the tar volume/void space ratio. Fugacity modelling suggested that risk-critical compounds such as benzene, naphthalene and other monocyclic and polycyclic aromatic hydrocarbons may gather in the gasholder air phase at significant concentrations. Gasholder emissions were measured on-site and compared with the workplace exposure limits (WELs) currently in use in UK. While levels for most of the toxic compounds were far lower than WELs, benzene air-concentrations where found to be above the accepted threshold. In addition due to the long exposure periods involved in gasholder decommissioning and the significant contribution given by naphthalene to the total coal tar vapour concentration, the adoption of a WEL for naphthalene may need to be considered to support operators in preventing human health risk at the workplace. The Level I fugacity approach used in this study demonstrated its suitability for applications to sealed environments such as gasholders and its further refining could provide a useful tool for land remediation risk assessors. 相似文献
82.
Gergely Vodila Mihály Molnár Mihály Veres Éva Svingor István Futó István Barnabás Sándor Kapitány 《Journal of environmental radioactivity》2009
Püspökszilágy Radioactive Waste Treatment and Disposal Facility (RWTDF) is a typical near-surface engineered repository designated to store low- and intermediate-level wastes from various institutes, research facilities and hospitals in Hungary. Two automatic combined 14C–tritium sampling units installed at the facility sample the air 2 m above surface. The one installed near the vaults detects tritium (T) activities two orders of magnitude higher than the far reference sampling unit. To localize the T emissions, 19 small absorption vapour samplers filled with silica gel were settled onto the ground surface. After the saturation of the silica gel, the water was recovered and its T concentration was measured with a low-background liquid scintillation counter. The absorption vapour samplers are cheap, simple and easy-to-use. We present the samplers and the T distribution map constructed from the data, which helps to localize the T emission. 相似文献
83.
L. León Vintró P.I. Mitchell A. Omarova M. Burkitbayev H. Jiménez Nápoles N.D. Priest 《Journal of environmental radioactivity》2009
New data are reported on the concentrations, isotopic composition and speciation of americium, plutonium and uranium in surface and ground waters in the Sarzhal region of the Semipalatinsk Test Site, and an adjacent area including the settlement of Sarzhal. The data relate to filtered water and suspended particulate from (a) streams originating in the Degelen Mountains, (b) the Tel′kem 1 and Tel′kem 2 atomic craters, and (c) wells on farms located within the study area and at Sarzhal. The measurements show that 241Am, 239,240Pu and 238U concentrations in well waters within the study area are in the range 0.04–87 mBq dm−3, 0.7–99 mBq dm−3, and 74–213 mBq dm−3, respectively, and for 241Am and 239,240Pu are elevated above the levels expected solely on the basis of global fallout. Concentrations in streams sourced in the Degelen Mountains are similar, while concentrations in the two water-filled atomic craters are somewhat higher. Suspended particulate concentrations in well waters vary considerably, though median values are very low, at 0.01 mBq dm−3, 0.08 mBq dm−3 and 0.32 mBq dm−3 for 241Am, 239,240Pu and 238U, respectively. The 235U/238U isotopic ratio in almost all well and stream waters is slightly elevated above the ‘best estimate’ value for natural uranium worldwide, suggesting that some of the uranium in these waters is of test-site provenance. Redox analysis shows that on average most of the plutonium present in the microfiltered fraction of these waters is in a chemically reduced form (mean 69%; 95% confidence interval 53–85%). In the case of the atomic craters, the proportion is even higher. As expected, all of the americium present appears to be in a reduced form. Calculations suggest that annual committed effective doses to individual adults arising from the daily ingestion of these well waters are in the range 11–42 μSv (mean 21 μSv). Presently, the ground water feeding these wells would not appear to be contaminated with radioactivity from past underground testing in the Degelen Mountains or from the Tel′kem explosions. 相似文献
84.
Cristiano V.M. Araújo Fernando R. Diz Irene Laiz Luís M. Lubián Julián Blasco Ignacio Moreno-Garrido 《Environment international》2009,35(6):831-841
This study consisted of the sediment toxicity assessment of the Bay of Cádiz based on two endpoints: growth inhibition for Cylindrotheca closterium (benthic microalgae) and fecundity inhibition for Tisbe battagliai (harpacticoid copepod). A new methodology to eliminate (but not as storage technique) the autochthonous biota present in the sediment samples by immersing them in liquid nitrogen (? 196 °C) was also assessed. Sediment toxicity data showed different toxicity levels for both organisms. In general, T. battagliai was more sensitive; however a good correlation (r = 0.75; p < 0.05) between sediment toxicity results for both species was found. Data in pore water (pH, redox potential, and toxicity for microalgae and copepod) and sediment (pH, redox potential, organic carbon, and metal concentrations) demonstrated that ultra-freezing did not alter sample characteristics; thus, this technique can be adopted as a pre-treatment in whole-sediment toxicity tests in order to avoid misleading results due to presence of autochthonous biota. Multivariate statistical analysis such as cluster and principal component analysis using chemical and ecotoxicological data were employed. Silt and organic matter percentage and lead concentration were found to be the factors that explain about 77% of sediment toxicity in the Bay of Cádiz. Assay methodology determined in this study for both assayed species is considered adequate to be used in sediment toxicity monitoring programs. Results obtained using both species show that the Bay of Cádiz can be considered a moderately polluted zone. 相似文献
85.
Vo Thi Thanh Loc Simon R. Bush Le Xuan Sinh Nguyen Tri Khiem 《Environment, Development and Sustainability》2010,12(6):889-908
This paper investigates the structure, function and wealth distribution within the Pangasius hypophthalmus and Henicorhynchus spp./Labiobarbus spp. value chains in the Mekong Delta of Vietnam. The analysis is driven by key questions relating to the form and function
of value chains, their contribution to the livelihoods of farmers and fishers, the effectiveness of government policy and
the potential for value chain governance mechanisms, such as contracts and certification, to steer towards sustainable production.
The results indicate that actors in the high value Pangasius hypopthalmus export chain have a higher potential income, but face considerably higher economic vulnerability from global markets. Alternatively,
Henichorhychus/Labiobarbus spp. fishers are severely constrained in their ability to negotiate higher prices for their fish but appear to be less vulnerable
to economic and environmental change. The paper concludes that for value chain governance to improve the livelihoods of fishers
and farmers in both high and low value chains, new arrangements are needed that better accommodate customary institutions
and informal market relations. 相似文献
86.
Research into national innovation systems (NISs) has received extensive academic and policy attention, and is especially relevant
with latecomer countries seeking to innovate in challenging industrial environments. In playing catch up with their early
industrializing counterparts, methods of learning take on increased importance in determining industrial success for latecomers.
The wind turbine technology innovation system is one that is highly dependent on both the extent of the national learning
processes and the strength of the national social-institutional setting. This research investigates the case of Taiwan, a
country which has embarked on a program to build its national innovative capacity in wind turbine technologies with specific
emphasis on Taiwan’s social sector. Within this system, the spotlight will be on four types of learning processes that interplay
during wind turbine development: learning by searching, learning by doing, learning by using, and learning by interacting. Through a case study of the emergence of Taiwan’s burgeoning large-scale wind power technology initiatives, the paper aims
to add to the understanding on how methods of learning impact upon the success of innovation systems. The findings show that
the industry’s future prospects are constrained because of the limited learning by interacting processes between turbine component producers, turbine owners, and researchers and because of weaknesses in the institutional
framework. This research also recognizes the importance that culture has on dominant forms of learning. 相似文献
87.
J. Ram Pillarisetti Jeroen C. J. M. van den Bergh 《Environment, Development and Sustainability》2010,12(1):49-62
What is a ‘sustainable nation’ and how can we identify and rank ‘sustainable nations?’ Are nations producing and consuming in a sustainable way? Although several aggregate indexes have been proposed to answer such questions, comprehensive and internationally comparable data are not available for most of these. This paper quantitatively compares three aggregate indexes of sustainability: the World Bank’s ‘Genuine Savings’ measure, the ‘Ecological Footprint,’ and the ‘Environmental Sustainability Index.’ These three indexes are available for a large number of countries and also seem to be the most influential among the aggregate indexes. This paper first discusses the main limitations and weaknesses of each of these indexes. Subsequently, it shows that rankings of sustainable nations and aggregate assessments of unsustainable world population and world GDP shares vary considerably among these indexes. This disagreement leads to suggestions for analysis and policy. One important insight is that climate change, arguable the most serious threat currently faced by humanity, is not or arbitrarily captured by the indexes. 相似文献
88.
This article considers a planner’s optimum control exercise with environmental pollution and derives a testable link between
the growth rates of consumption and pollution. The link is then empirically estimated for the case of CO2 emissions for a sample consisting of the union of top 25 countries in terms of CO2 emissions, population and per capita GNP. The analysis suggests that the interrelationship between the growth rates of CO2 emission and economic development is mostly significant for countries that have a high level of CO2 emissions and population. 相似文献
89.
Developed countries are major markets for developing country fresh produce. Demand by developed country consumers for spotless
produce has encouraged developing country consumers to rely increasingly on pesticides in producing fresh export vegetables.
However developed country pesticide standards enacted in response to reports of increased farmer and farm worker pesticide
poisoning and the food safety scandals of the 1980s and 1990s require changes in the way growers use pesticides. The EU has
especially developed stringent food safety standards relating to, among other things, pesticide usage. Under EU pesticide
standards (EU-PS) farmers are trained by their buyers on safe use of pesticides and then closely monitored under contract.
This paper looks at the impact of these standards on developing country farmers’ use of alternative pest management practices,
pesticide protective clothing and the actual usage of pesticides. It finds that compliance with EU-PS increases the use of
alternative pest management practices and protective clothing. However, EU-PS has mixed effect on the quantity of pesticides
used. The paper also finds that farmer’s education and access to information play an important role in the use of alternative
pest management practices. The paper concludes that EU-PS encourage the use of alternative pest management practices and pesticide
protective gear in production of fresh export vegetables. The findings imply that EU-PS promote environmentally-friendly methods
of production of fresh export vegetables in developing countries. 相似文献
90.
Qinhua Fang Luoping Zhang Huasheng Hong Liyu Zhang Frances Bristow 《Environment, Development and Sustainability》2008,10(1):41-49
Environmental planning at different levels has been called for by environmental departments in China during last years to integrate environment consideration to economic development. Based on the accomplished environmental planning practice in Xiamen China, the paper suggests a general environmental planning process with ecological function zoning as its key steps, at the same time an effective method for ecological function zoning was formulated. The case studies of Dongfu suburban town environmental planning and Xiamen eco-city conceptual planning indicate that scientifically sound results of ecological function zoning can contribute to improving not only the adaptability and acceptability of environmental planning, also the environmental management and the decision-making. The experience shows that the ecological function zoning methods should be applied according to the principles of adaptive management, resource-based and community-based, so that it can integrate science into decision-making process, avoiding both narrow-minded viewpoints of planners and natural resource use conflicts among variety of stakeholders. Problems to be resolved in the future are also pointed out in the ending part. 相似文献