全文获取类型
收费全文 | 4303篇 |
免费 | 38篇 |
国内免费 | 24篇 |
专业分类
安全科学 | 88篇 |
废物处理 | 268篇 |
环保管理 | 365篇 |
综合类 | 518篇 |
基础理论 | 849篇 |
环境理论 | 6篇 |
污染及防治 | 1586篇 |
评价与监测 | 396篇 |
社会与环境 | 275篇 |
灾害及防治 | 14篇 |
出版年
2023年 | 54篇 |
2022年 | 110篇 |
2021年 | 165篇 |
2020年 | 74篇 |
2019年 | 68篇 |
2018年 | 154篇 |
2017年 | 166篇 |
2016年 | 237篇 |
2015年 | 129篇 |
2014年 | 252篇 |
2013年 | 409篇 |
2012年 | 294篇 |
2011年 | 319篇 |
2010年 | 238篇 |
2009年 | 161篇 |
2008年 | 255篇 |
2007年 | 267篇 |
2006年 | 202篇 |
2005年 | 172篇 |
2004年 | 124篇 |
2003年 | 108篇 |
2002年 | 97篇 |
2001年 | 53篇 |
2000年 | 41篇 |
1999年 | 24篇 |
1998年 | 17篇 |
1997年 | 12篇 |
1996年 | 12篇 |
1995年 | 18篇 |
1994年 | 14篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1982年 | 3篇 |
1978年 | 3篇 |
1970年 | 2篇 |
1967年 | 4篇 |
1966年 | 4篇 |
1965年 | 2篇 |
1964年 | 5篇 |
1962年 | 3篇 |
1959年 | 4篇 |
1958年 | 15篇 |
1957年 | 5篇 |
1955年 | 2篇 |
排序方式: 共有4365条查询结果,搜索用时 15 毫秒
241.
Daniel Arenas-Lago Flora A. Vega Luis Felipe O. Silva María Luisa Andrade 《Environmental science and pollution research international》2014,21(18):10997-11008
The horizons of four natural soils were treated with Cu2+ in an acid medium to study the retention capacity of Cu. The possible mineralogical changes arising because of the treatment were also studied. The soil properties and characteristics with the greatest influence on the metal retention and its distribution among the different soil fractions were determined. Crystalline phases of each horizon were determined by X-ray diffraction (XDR). The morphology, structural distribution and particle chemical composition of soil samples were investigated using field emission scanning electron microscopy. Cu distribution in the different geochemical phases of the soil was studied using a sequential extraction. The treatment led to an increase in the amorphous phases and the formation of new crystalline phases, such as rouaite (Cu2(NO3)(OH)3) and nitratine (NaNO3). Cu was also found superficially sorbed on amorphous hydroxy compounds of Fe that interact with albite, muscovite and gibbsite, and also on spherical and curved particles of aluminium clays. The largest amount of Cu retained was in an exchangeable form, and the smallest amount associated with the crystalline Fe oxides and residual fraction. In the surface horizons, the predominant Cu retention process is complexation in organomineral associations, while in the subsurface horizons it is adsorption. 相似文献
242.
Vanina A. Angelini Elizabeth Agostini María I. Medina Paola S. González 《Environmental science and pollution research international》2014,21(4):2531-2539
2,4-Dichlorophenol (2,4-DCP) is widely distributed in wastewaters discharged from several industries, and it is considered as a priority pollutant due to its high toxicity. In this study, the use of different peroxidase extracts for 2,4-DCP removal from aqueous solutions was investigated. Tobacco hairy roots (HRs), wild-type (WT), and double-transgenic (DT) for tomato basic peroxidases (TPX1 and TPX2) were used to obtain different peroxidase extracts: total peroxidases (TPx), soluble peroxidases (SPx), and peroxidases ionically bound to the cell wall (IBPx). All extracts derived from DT HRs exhibited higher peroxidase activity than those obtained from WT HRs. TPx and IBPx DT extracts showed the highest catalytic efficiency values. The optimal conditions for 2,4-DCP oxidation were pH 6.5, H2O2 0.5 mM, and 200 U mL?1 of enzyme, for all extracts analyzed. Although both TPx extracts were able to oxidize different 2,4-DCP concentrations, the removal efficiency was higher for TPx DT. Polyethylene glycol addition slightly improved 2,4-DCP removal efficiency, and it showed some protective effect on TPx WT after 2,4-DCP oxidation. In addition, using Lactuca sativa test, a reduction of the toxicity of post removal solutions was observed, for both TPx extracts. The results demonstrate that TPx extracts from both tobacco HRs appear to be promising candidate for future applications in removing 2,4-DCP from wastewaters. This is particularly true considering that these peroxidase sources are associated with low costs and are readily available. However, TPx DT has increased peroxidase activity, catalytic efficiency, and higher removal efficiency than TPx WT, probably due to the expression of TPX1 and TPX2 isoenzymes. 相似文献
243.
Carolina Fernández-Ramos Oscar Ballesteros Alberto Zafra-Gómez Francisco Javier Camino-Sánchez Rosario Blanc Alberto Navalón José Luís Vílchez 《Environmental science and pollution research international》2014,21(6):4286-4296
The study describes the environmental monitoring of anionic surfactants―alcohol sulfates (AS) and alcohol ethoxysulfates (AES)—in marine sediments. Concentration values were obtained after pressurised liquid extraction (PLE) and liquid chromatography–tandem mass spectrometry analysis (LC–MS/MS). Samples were collected from a range of wastewater discharge points along the coast of the provinces of Huelva, Málaga, Granada and Almería. Urban, agricultural and industrial wastewaters are discharged at the selected 38 sampling sites. Principal component analysis was carried out in order to evaluate the distribution and behaviour of these compounds in these coastal environments. Evaluation of the data revealed that the behaviour and sources of AS and AES in marine sediments are different, and that the distribution of AES depends on the length of the alkyl chain, while the number of ethoxylated units is not relevant. Additionally, the 38 sampling sites can be grouped into only two types of outfalls according to their AS distribution. The concentration of compounds in sediment samples ranged from 7.52 to 13.50 mg kg?1 for AS, from 3.04 to 10.68 mg kg?1 for AES–C12Ex and from 3.83 to 11.56 mg kg?1 for AES–C14Ex. 相似文献
244.
Hariz Islas-Flores Leobardo Manuel Gómez-Oliván Marcela Galar-Martínez Sandra García-Medina Nadia Neri-Cruz Octavio Dublán-García 《Environmental science and pollution research international》2014,21(7):5157-5166
Although trace concentrations of ibuprofen (IBP) have been detected in diverse water bodies, there is currently insufficient information on the potentially deleterious effects of this xenobiotic. The present study aimed to determine whether IBP induces oxidative stress in brain, liver, gill, and blood of the common carp Cyprinus carpio. To this end, the median lethal concentration at 96 h (96-h LC50) was determined and the lowest observed adverse effect level was established. Carp were exposed to the latter concentration (17.6 mg L?1) for 12, 24, 48, 72, and 96 h, and the following biomarkers were evaluated: lipid peroxidation (LPX) and activity of the antioxidant enzymes superoxide dismutase, catalase, and glutathione peroxidase. Results indicated that LPX and antioxidant enzymes’ activity increased significantly (p?<?0.05) with respect to the control group in liver, gill, and blood, while no significant differences occurred in brain. In conclusion, IBP induced oxidative stress on C. carpio, the liver being the organ most affected by this damage. 相似文献
245.
Tatiana Simonetto Colla Robson Andreazza Francielle Bücker Marcela Moreira de Souza Letícia Tramontini Gerônimo Rodrigues Prado Ana Paula Guedes Frazzon Flávio Anastácio de Oliveira Camargo Fátima Menezes Bento 《Environmental science and pollution research international》2014,21(4):2592-2602
This study investigated the effectiveness of successive bioaugmentation, conventional bioaugmentation, and biostimulation of biodegradation of B10 in soil. In addition, the structure of the soil microbial community was assessed by polymerase chain reaction-denaturing gradient gel electrophoresis. The consortium was inoculated on the initial and the 11th day of incubation for successive bioaugmentation and only on the initial day for bioaugmentation and conventional bioaugmentation. The experiment was conducted for 32 days. The microbial consortium was identified based on sequencing of 16S rRNA gene and consisted as Pseudomonas aeruginosa, Achromobacter xylosoxidans, and Ochrobactrum intermedium. Nutrient introduction (biostimulation) promoted a positive effect on microbial populations. The results indicate that the edaphic community structure and dynamics were different according to the treatments employed. CO2 evolution demonstrated no significant difference in soil microbial activity between biostimulation and bioaugmentation treatments. The total petroleum hydrocarbon (TPH) analysis indicated a biodegradation level of 35.7 and 32.2 % for the biostimulation and successive bioaugmentation treatments, respectively. Successive bioaugmentation displayed positive effects on biodegradation, with a substantial reduction in TPH levels. 相似文献
246.
Cristina Barazzetti Barbieri Jorge Eduardo Souza Sarkis Luiz Antonio Martinelli Isabella C. A. C. Bordon Horst Mitteregger Jr. Marcos Antônio Hortellani 《Environmental Forensics》2014,15(2):134-146
A forensic approach was used to evaluate sediments from Portão Stream, including analysis of metals, carbon (C) and nitrogen (N) stable isotopes, and C:N ratios. Samples collected at various points located along the stream were tested in order to investigate a possible illegal leachate input. The studied stream is heavily impacted by sewage and industrial discharges from two cities along its course. Among the metals analyzed, chromium (Cr) was noticeably the main pollutant, showing the highest levels, above regulatory limits, downstream from some potential sources of effluents enriched with this metal. Isotope analyses revealed a general trend of depletion in the heavier isotope along the stream for C and N. The exception was one point near a hazardous waste landfill, where relatively more enriched δ13C and δ15N values were found. The isotope and metal analysis results indicated that this site was affected by a particular source, demonstrating the combination of these parameters could be used for the discrimination of sources in a heavily polluted stream. Nevertheless, further investigations are necessary to provide a comprehensive evaluation of the biogeochemical processes involved in the incorporation of leachate in sediments to use this analysis as evidence for the illegal leachate discharge. 相似文献
247.
Behaviour of different lichen species as biomonitors of air pollution by PAHs in natural ecosystems 总被引:2,自引:0,他引:2
Six different species of lichens (Parmelia sulcata Tayl., Evernia prunastri (L.) Ach., Ramalina farinacea, Pseudevernia furfuracea (L.) Zopf., Usnea sp. and Lobaria pulmonaria (Schreb.) Hoffm.) were collected in two mountain valleys in Central Pyrenees: the Aspe and Aragon valleys. Two multivariate techniques have been applied with different purposes, ANOVA and Discriminant Analysis (DA), to evaluate the data. The PAHs spatial distribution was studied in the three more abundant and widespread species in the area: P. sulcata, E. prunastri (L.) Ach. and R. farinacea in terms of total PAHs, PAHs related to the combustion processes and toxicity. Different behaviour of each lichen species to trap PAHs was found, being P. sulcata the best one to monitor the most persistent PAHs of pyrogenic origin and E. prunastri the most appropriate to provide information about pyrogenic and petrogenic PAHs. Traffic was the most relevant influence in PAHs bioaccumulation in lichen species. 相似文献
248.
Santos MJ Sousa JP Tiago I Veríssimo A Lemos MF 《Journal of environmental monitoring : JEM》2011,13(8):2102-2104
Changes in saprophytic organism's gut microbial communities may present a threat to organic matter breakdown which can ultimately lead to soil function impairment. In this study, Amplified Ribosomal DNA Restriction Analysis (ARDRA) was evaluated as a potential simple molecular tool to assess shifts in bacterial community structure in hindgut populations of Porcellio dilatatus exposed to contaminated food. This prospective tool can also be used for a variety of purposes and samples prior to the use of more specific and sophisticated methods. 相似文献
249.
In recent years, several monitoring programs have been established as a consequence of EU Directives which include requirements for monitoring the quality of water resources (drinking water, groundwater and surface water). Plant protection products (PPPs) are an obvious target for monitoring activities, since they are directly released into the environment. In Italy, the National Environmental Protection Agency (ISPRA ex APAT) has recently published two reports containing the results of the National Plans for Control of Environmental Effects of PPP. These documents contain the collection of monitoring data related to the presence of PPP residues in surface water and groundwater. The first objective of this work was to critically analyze the results of monitoring campaigns on pesticide residues in surface waters in Italy. In particular, the paper focuses on whether and how the Italian approach satisfies the requirements of the Water Framework Directive, whether they are representative of the whole national territory, and how the utilized approach is appropriate for the characterization of risk to surface water. Starting from this analysis, some considerations about the limits of environmental monitoring as a tool for managing risk were highlighted. 相似文献
250.
Martín J Camacho-Muñoz D Santos JL Aparicio I Alonso E 《Journal of environmental monitoring : JEM》2011,13(7):2042-2049
Guadalquivir River (South of Spain) is among the major freshwater sources of the European Atlantic basin. Until now scientific efforts have been focused on contamination by heavy metals and some priority pollutants in Guadalquivir River. However, the presence of "emerging contaminants", such as pharmaceutically active compounds, has not yet been studied. In this work the occurrence and risk assessment of sixteen pharmaceutically active compounds, belonging to different therapeutic groups, in Guadalquivir River during its course through Seville city are reported. Wastewater effluents from four wastewater treatment plants discharging into Guadalquivir River and river water samples were analyzed. All studied pharmaceutically active compounds, except sulfamethoxazole, trimethoprim, estrone and clofibric acid, were detected in effluent wastewaters at concentration levels up to 28.9 μg L(-1). Among the pharmaceutically active compounds found in effluent wastewater, seven were present in Guadalquivir River samples at concentration levels up to 0.75 μg L(-1), which indicated an important dilution from effluent discharge. Environmental risk assessment reveals that potential ecotoxicological risk cannot be expected on Guadalquivir River at measured concentration levels. Only, the lipid regulator gemfibrozil showed a medium risk for the environment. The risk for acute toxic effects in the environment with the current use of active pharmaceutical ingredients is unlikely. However, the results do not rule out the potential for chronic environmental effects. 相似文献