Soil contamination in Colombian playgrounds: effects of vehicles,construction, and traffic

The presence of potentially hazardous elements (PHEs) in playground soils is generally associated with anthropogenic sources such as vehicle traffic, industries, construction sites, and biomass burning. Studies indicate that PHEs are harmful to human health and may even be carcinogenic. Therefore, the aim of this study was to evaluate the physicochemical, morphological, and mineralogical properties of soil samples from three public playgrounds located in the cities of Bogota, Medellin, and Barranquilla. Besides, the possible impacts caused by the aerodynamics of particles in Colombian cities were verified. The morphology, composition, and structure of the nanoparticles (NPs) (< 100 nm) present in these soils were evaluated by field emission scanning electron microscopy (FE-SEM) equipped with high-precision field emission (FE) and high-resolution transmission electron microscopy (HR-TEM). Soil samples were predominantly feldspar, quartz, and, to a lesser extent, clay minerals, carbonates, and hematites. The average content of PHEs was anthropogenically enriched in relation to the upper continental crust. As and Sn showed a large spatial variation, indicating the influence of local sources, such as vehicle traffic and industries. There is an inverse relationship between the total concentrations of some elements and their leachable fractions. The accumulation of traffic-derived PHEs has a negative impact on human health and the environment, which is alarming, especially for elements such as Pb, Sb, or As. Therefore, the presence of PHEs should receive greater attention from public health professionals, and limits should be set and exposures controlled. This study includes the construction of a baseline that provides basic information on pollution, its sources, and exposure routes for humans in the vicinity of Colombia’s major cities, characterized by their increasing urbanization and industrialization.

     

Volcanic mercury in Pinus canariensis

Mercury (Hg) is a toxic element that is emitted to the atmosphere by both human activities and natural processes. Volcanic emissions are considered a natural source of mercury in the environment. In some cases, tree ring records taken close to volcanoes and their relation to volcanic activity over time are contradictory. In 1949, the Hoyo Negro volcano (La Palma-Canary Islands) produced significant pyroclastic flows that damaged the nearby stand of Pinus canariensis. Recently, 60 years after the eruption, we assessed mercury concentrations in the stem of a pine which survived volcano formation, located at a distance of 50 m from the crater. We show that Hg content in a wound caused by pyroclastic impacts (22.3 μg kg^?1) is an order of magnitude higher than the Hg concentrations measured in the xylem before and after the eruption (2.3 μg kg^?1). Thus, mercury emissions originating from the eruption remained only as a mark—in pyroclastic wounds—and can be considered a sporadic and very high mercury input that did not affect the overall Hg input in the xylem. In addition, mercury contents recorded in the phloem (9.5 μg kg^?1) and bark (6.0 μg kg^?1) suggest that mercury shifts towards non-living tissues of the pine, an aspect that can be related to detoxification in volcanism-adapted species.     

The recycling cycle of materials as a design project tool

Currently, a large number of companies consider recycling of materials as an opportunity to maximize profits and to reduce the environmental impact generated by these materials after they are disposed. However, there is also a strong constraint on the use of recycled materials mainly due to the lack of technical/scientific information, which would relate their physical properties to their recycling cycle. This information should be used in the initial phase of the product design to serve as reference for the simulation of a project to point out the physical properties obtained from recycling the Projected material (Pm). Thus, it would be possible to foresee some recycling strategy to keep the good characteristics of recycled materials by encouraging their use, regardless of the product to be designed.Therefore, the Recycling Cycle of Materials (RCM) is a tool that provides scientific/technical support in the selection of materials. It uses the information related to the physical properties of the Pm as a parameter for product design after five recycling cycles. For the case study, this tool has been applied to obtain the basic material of ABS/PC blend. Subsequently, this blend was evaluated using DSC, FTIR, traction and impact methods to obtain delimiting data for the definition of the mechanical properties resulting from the application of RCM.     

Mapping the Spatial Variability of Plant Diversity in a Tropical Forest: Comparison of Spatial Interpolation Methods

Knowledge of the spatial distribution of plant species is essential to conservation and forest managers in order to identify high priority areas such as vulnerable species and habitats, and designate areas for reserves, refuges and other protected areas. A reliable map of the diversity of plant species over the landscape is an invaluable tool for such purposes. In this study, the number of species, the exponent Shannon and the reciprocal Simpson indices, calculated from 141 quadrat sites sampled in a tropical forest were used to compare the performance of several spatial interpolation techniques used to prepare a map of plant diversity, starting from sample (point) data over the landscape. Means of mapped classes, inverse distance functions, kriging and co-kriging, both, applied over the entire studied landscape and also applied within vegetation classes, were the procedures compared. Significant differences in plant diversity indices between classes demonstrated the usefulness of boundaries between vegetation types, mapped through satellite image classification, in stratifying the variability of plant diversity over the landscape. These mapped classes, improved the accuracy of the interpolation methods when they were used as prior information for stratification of the area. Spatial interpolation by co-kriging performed among the poorest interpolators due to the poor correlation between the plant diversity variables and vegetation indices computed by remote sensing and used as covariables. This indicated that the latter are not suitable covariates of plant diversity indices. Finally, a within-class kriging interpolator yielded the most accurate estimates of plant diversity values. This interpolator not only provided the most accurate estimates by accounting for the indices' intra-class variability, but also provided additional useful interpretations of the structure of spatial variability of diversity values through the interpretation of their semi-variograms. This additional role was found very useful in aiding decisions in conservation planning.     

Health and environmental assessment of mercury exposure in a gold mining community in Western Mindanao, Philippines

The small-scale gold mining activities using mercury began in the late 1980s in Sibutad, Western Mindanao. It is located very near the Murcielagos Bay with tailing ponds directly discharging into bodies of water. This cross-sectional study aimed to determine the health and environmental effects of gold mining activities on the community. Residents were randomly selected and classified into two groups, namely, the directly exposed and indirectly exposed populations using a set inclusion criteria. Complete medical and laboratory examinations were performed. Environmental and biologic samples were collected for total mercury and methylmercury determinations. The results showed that the directly exposed group had significantly higher mean blood total mercury and methylmercury levels in comparison with the indirectly exposed population. Although there were no significant differences between hair total mercury and methylmercury levels, there was a trend for higher levels of these biomarkers among the directly exposed residents as compared with the unexposed group. The absence of statistically significant differences may be attributable to the small sample size. Ambient air quality monitoring for mercury exceeded the allowable levels. However, levels of mercury in drinking water and sediments were within allowable limits. Frequency of gastrointestinal complaints was significantly associated with elevated hair methylmercury levels (p=0.02). Also, there appears to be a trend towards higher blood total mercury levels and frequency of gastrointestinal complaints (p=0.09). An interesting finding in this study was the increasing incidence of elevated diastolic blood pressure with elevated hair total mercury levels (p=0.07). Mercury storage at home is a risk factor.