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11.
Tanning processes performed in drums consume large amounts of water and chemicals, most of which end up in the wastewater. This study explores an alternative approach at an industrial scale to the traditional pickle-chrome tanning method. The new method replaces formic and sulphuric acids with sulphonic aromatic acid. Because it is done without float, there is a sizeable reduction in the amount of added salt and chrome salt as well as an increase in temperatures at the end of the tanning process. From an environmental perspective, the new method offers important advantages. For instance, there is no float addition in the tannage. Also, there are reductions of 94% and 99%, respectively, in the discharge of chlorides and chrome, as well as a 75% reduction in the residual float. Our financial assessment demonstrated that the new method is 42% cheaper than a traditional approach. 相似文献
12.
This study tests an alternative method to the traditional unhairing method used during the process of tanning the hides. The new method is based on the substitution of sodium sulfide by hydrogen peroxide as an unhairing agent in both hair recovery and recirculation of the floats employed in the process. The properties of the hides obtained using the two methods have been compared and the results indicate that those hides have similar physical, chemical, and organoleptic properties. However, the differences existing from an environmental point of view are significant. These include reductions of water consumption (approx 70%), chemical oxygen demand (approx 35%), toxicity (98%) and total kjendhal nitrogen (50%). Also, the risk associated with the production of hydrogen sulfide is eliminated, which implies a great improvement in terms of safety for the workers. Given the large amounts of water and chemical pollution discharged in the process, the reductions in absolute values represent a significant improvement. A financial assessment was carried out to demonstrate that the proposed new system is 16% more economic than the traditional one. 相似文献
13.
Colmenero Sujo L Montero Cabrera ME Villalba L Rentería Villalobos M Torres Moye E García León M García-Tenorio R Mireles García F Herrera Peraza EF Sánchez Aroche D 《Journal of environmental radioactivity》2004,77(2):205-219
High-resolution gamma spectrometry was used to determine the concentration of 40K, 238U and 232Th series in soil samples taken from areas surrounding the city of Aldama, in Chihuahua. Results of indoor air short-time sampling, with diffusion barrier charcoal detectors, revealed relatively high indoor radon levels, ranging from 29 to 422 Bq/m3; the radon concentrations detected exceeded 148 Bq/m3 in 76% of the homes tested. Additionally, liquid scintillation counting showed concentrations of radon in drinking water ranging from 4.3 to 42 kBq/m3. The high activity of 238U in soil found in some places may be a result of the uranium milling process performed 20 years ago in the area. High radon concentrations indoor and in water may be explained by assuming the presence of uranium-bearing rocks underneath of the city, similar to a felsic dike located near Aldama. The estimated annual effective dose of gamma radiation from the soil and radon inhalation was 3.83 mSv. 相似文献
14.
Trace element speciation in poultry litter 总被引:8,自引:0,他引:8
Jackson BP Bertsch PM Cabrera ML Camberato JJ Seaman JC Wood CW 《Journal of environmental quality》2003,32(2):535-540
Trace elements are added to poultry feed for disease prevention and enhanced feed efficiency. High concentrations are found in poultry litter (PL), which raises concerns regarding trace element loading of soils. Trace metal cation solubility from PL may be enhanced by complexation with dissolved organic carbon (DOC). Mineralization of organo-As compounds may result in more toxic species such as As(III) and As(V). Speciation of these elements in PL leachates should assist in predicting their fate in soil. Elemental concentrations of 40 PL samples from the southeastern USA were determined. Water-soluble extractions (WSE) were fractionated into hydrophobic, anionic, and cationic species with solid-phase extraction columns. Arsenic speciation of seven As species, including the main As poultry feed additives, roxarsone (ROX; 3-nitro-4-hydroxyphenylarsonic acid) and p-arsanilic acid (p-ASA; 4-aminophenylarsonic acid), was performed by ion chromatography-inductively coupled plasma-mass spectrometry (IC-ICP-MS). Total As concentrations in the litter varied from 1 to 39 mg kg(-1), averaging 16 mg kg(-1). Mean total Cu, Ni, and Zn concentrations were 479, 11, and 373 mg kg(-1), respectively. Copper and Ni were relatively soluble (49 and 41% respectively) while only 6% of Zn was soluble. Arsenic was highly soluble with an average of 71% WSE. Roxarsone was the major As species in 50% of PL samples. However, the presence of As(V) as the major species in 50% of the PL samples indicates that mineralization of ROX had occurred. The high solubility of As from litter and its apparent ready mineralization to inorganic forms coupled with the large quantity of litter that is annually land-applied in the USA suggests a potential detrimental effect on soil and water quality in the long term. 相似文献
15.
Guillermo Cabrera Miguel A. Marino 《Journal of the American Water Resources Association》1976,12(2):317-335
ABSTRACT. Transient, two-dimensional solutions are developed which describe the movement and distribution of a conservative substance in a stream-aquifer system. The solutions are obtained by solving sequentially the groundwater flow and mass transport equations. A variational approach in conjunction with the finite element method is used to solve the groundwater flow equation. Galerkin's approach coupled with the finite element method is used to solve the mass transport equation. Linear approximated triangular elements and a centered scheme of numerical integration are employed to calculate the hydraulic head distribution and the concentration of solute in the flow region. The linear approximation used to define the concentration function within each element is not appropriate for cases involving steep concentration gradients. For such cases, higher order approximations are necessary to assure the continuity of gradients across interelemental boundaries. Numerical examples that illustrate the applicability of the model are presented. 相似文献
16.
Esther del Val Juan Carlos Senar Juan Garrido-Fernández Manuel Jarén Antoni Borràs Josep Cabrera Juan José Negro 《Die Naturwissenschaften》2009,96(7):797-801
Carotenoids may provide numerous health benefits and are also responsible for the integumentary coloration of many bird species.
Despite their importance, many aspects of their metabolism are still poorly known, and even basic issues such as the anatomical
sites of conversion remain controversial. Recent studies suggest that the transformation of carotenoid pigments takes place
directly in the follicles during feather growth, even though the liver has been previously recognised as a storing organ for
these pigments with a certain potential for conversion. In this context, we analysed the carotenoid profile of plasma, liver,
skin and feathers of male Common Crossbills (Loxia curvirostra). Interestingly, the derivative feather pigment 3-hydroxy-echinenone was detected in the liver and in the bloodstream (i.e.
the necessary vehicle to transport metabolites to colourful peripheral tissues). Our results demonstrate for the first time
with empirical data that the liver may act as the main site for the synthesis of integumentary carotenoids. This finding contradicts
previous assumptions and raises the question of possible inter-specific differences in the site of carotenoid conversion in
birds. 相似文献
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