全文获取类型
收费全文 | 1093篇 |
免费 | 23篇 |
国内免费 | 13篇 |
专业分类
安全科学 | 60篇 |
废物处理 | 67篇 |
环保管理 | 209篇 |
综合类 | 111篇 |
基础理论 | 246篇 |
污染及防治 | 293篇 |
评价与监测 | 97篇 |
社会与环境 | 37篇 |
灾害及防治 | 9篇 |
出版年
2023年 | 15篇 |
2022年 | 12篇 |
2021年 | 17篇 |
2020年 | 18篇 |
2019年 | 21篇 |
2018年 | 23篇 |
2017年 | 32篇 |
2016年 | 26篇 |
2015年 | 29篇 |
2014年 | 43篇 |
2013年 | 162篇 |
2012年 | 62篇 |
2011年 | 57篇 |
2010年 | 37篇 |
2009年 | 49篇 |
2008年 | 52篇 |
2007年 | 60篇 |
2006年 | 41篇 |
2005年 | 38篇 |
2004年 | 32篇 |
2003年 | 31篇 |
2002年 | 31篇 |
2001年 | 14篇 |
2000年 | 16篇 |
1999年 | 11篇 |
1998年 | 14篇 |
1997年 | 12篇 |
1996年 | 10篇 |
1995年 | 7篇 |
1994年 | 15篇 |
1993年 | 13篇 |
1992年 | 9篇 |
1991年 | 7篇 |
1990年 | 6篇 |
1989年 | 5篇 |
1987年 | 10篇 |
1986年 | 8篇 |
1985年 | 8篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 5篇 |
1976年 | 4篇 |
1958年 | 2篇 |
1957年 | 3篇 |
1956年 | 2篇 |
1955年 | 3篇 |
排序方式: 共有1129条查询结果,搜索用时 46 毫秒
911.
Joseph W. Dellapenna 《Journal of the American Water Resources Association》1999,35(6):1301-1326
ABSTRACT: Existing legal regimes for the management of water resources are already stressed by changing technologies and growing populations. There is little reason for doubt that today the planet is undergoing significant and even alarming climate change. In the past such global climatic changes had dramatic effects on water resource availability with disastrous consequences for many human communities. Today's climate changes can be managed without such disastrous consequences for present day communities only if there are major reforms to existing water law regimes at the local, national, and international levels. In particular, at the local and national levels, water resources must be treated as public property rather than as common or private property. At the international level, water must be managed at the drainage basin level rather than according to national boundaries that largely ignore rational water management criteria. At all levels, care must be given to decentralizing decision making and to use economic incentives insofar as possible, without, however, mistaking economic incentives for markets. The public nature of water resources precludes true markets as a significant management tool. 相似文献
912.
The United States Environmental Protection Agency is considering recommending longer‐term sampling to achieve more accurate time‐weighted‐average detections for indoor air monitoring of volatile organic chemicals. The purpose of the research presented herein was to compare longer sampling times using passive diffusion samplers to the results from shorter‐term testing periods using sorbent tubes and low‐flow pumps (US EPA Method TO‐17) at great frequency for trichloroethene (TCE) in indoor air. A controlled release of TCE in a large room allowed for over two‐orders‐of‐magnitude daily concentration variability over the course of the two‐week monitoring event. The daily concentration measurements by US EPA Method TO‐17 and the passive diffusion samplers were performed in triplicate and had excellent reproducibility. The results of daily tests were averaged and compared with four passive diffusion devices exposed to indoor air for three, seven, ten, and fourteen days in accordance with ASTM D6196‐02. A specific uptake rate for each of the passive devices at the four different time intervals and the statistical significance of the time‐varying uptake rates were evaluated. The performance of each passive diffusion device was determined using a statistical performance criterion. The average concentration for all of the exposure periods could be reliably predicted using the established uptake rates for two of the four passive devices. © 2009 Wiley Periodicals, Inc. 相似文献
913.
Gerosa G Finco A Mereu S Vitale M Manes F Denti AB 《Environmental pollution (Barking, Essex : 1987)》2009,157(5):1737-1744
Ozone and energy fluxes have been measured using the eddy covariance technique, from June to December 2004 in Castelporziano near Rome (Italy), and compared to similar measurements made in the previous year. The studied ecosystem consisted in a typical Mediterranean Holm oak forest. Stomatal fluxes have been calculated using the resistance analogy and by inverting the Penmann-Monteith equation. Results showed that the average stomatal contribution accounts for 42.6% of the total fluxes. Non-stomatal deposition proved to be enhanced by increasing leaf wetness and air humidity during the autumnal months. From a comparison of the two years, it can be inferred that water supply is the most important limiting factor for ozone uptake and that prolonged droughts alter significantly the stomatal conductance, even 2 months after the soil water content is replenished. Ozone exposure, expressed as AOT40, behaves similarly to the cumulated stomatal flux in dry conditions whereas a different behaviour for the two indices appears in wet autumnal conditions. A difference also occurs between the two years. 相似文献
914.
Plahuta JM Teel AL Ahmad M Beutel MW Rentz JA Watts RJ 《Water environment research》2011,83(9):826-833
Deicers currently used for aircraft deicing, including ethylene glycol and propylene glycol, pose significant threats to surface waters, as a result of high biochemical oxygen demand (BOD) and toxicity to aquatic organisms. Oxidized starch may provide a less toxic deicer with lower BOD. The freezing point depression of starch formulations oxidized using hydrogen peroxide and catalysts (i.e., catalyzed hydrogen peroxide [H2O2] propagations-CHP) was 28 degrees C, and viscosities similar to those of commercial deicers were achieved after post-treatment with granular activated carbon. The most effective oxidized starch formulation exerted a 5-day BOD up to 6 times lower than glycol deicers (103 versus 400 to 800 g O2/L). Toxicity to Ceriodaphnia dubia for this formulation (48-hour lethal concentration, 50% [LC50] of 2.73 g/L) was greater than pure propylene glycol (13.1 g/ L), but lower than propylene glycol deicer formulations (1.02 g/L). Organic acids were identified by gas chromatography/mass spectrometry as the primary constituents in the oxidized starch solution. The proposed deicing system would provide effective deicing while exerting minimal environmental effects (e.g., lower toxicity to aquatic organisms and lower BOD). Furthermore, these deicers could be made from waste starch, promoting sustainability. 相似文献
915.
Biomass burning as fuel in the traditional grass-roofed rural households of Western Province of Kenya in open fire places, in poorly ventilated conditions, lead to accumulation of soot under the roofs. This study characterized and quantified the polycyclic aromatic hydrocarbons (PAHs) in accumulated soot in these households and determined the variation in PAHs concentrations with fuel biomass type. Soot samples collected from the households were extracted, cleaned and analysed by gas chromatography. The PAHs were identified using retention times, verified by gas chromatographic mass spectral analysis and quantified from peak area responses using the internal standard method. The PAHs levels significantly varied (P ≤ 0.05) with biomass type in the order: dung ≥ indigenous trees ≥ exotic trees ≥ shrubs and crop residues. Use of dung and wood from indigenous trees as fuel should be discouraged since they are higher emitters (P ≤ 0.05) of carcinogenic PAHs. 相似文献
916.
Impact of different land uses on polycyclic aromatic hydrocarbon contamination in coastal stream sediments 总被引:2,自引:0,他引:2
PAHs are ubiquitous environmental pollutants that can cause adverse health and ecological effects. In the present study, we examined the impact of land use on the concentration and composition of PAHs in 28 coastal stream sediments on the Island of Oahu, Hawaii. In densely populated urban areas, the concentration range of total PAHs in the stream sediments affected by mixed residential and industrial activities (RI) are 0.40-9.05 ppm, which is significantly higher than the 0.36-4.21 ppm detected in the stream sediments affected predominantly by urban residential land uses (UR). The stream sediments affected by agricultural activities (AG) reported a concentration range of 0.09-2.14 ppm, which is lower than those of the RI and UR stream sediments. The molecular weight of PAH is a factor, as only high molecular weight (HMW) PAHs were significantly affected by land uses (ANOVA P = 0.009). Correlation analysis showed that only in the UR stream sediments were significant correlations observed between PAH concentration and two anthropogenic indicators: population density (r = 0.57, P = 0.027) and vehicle density (r = 0.55, P = 0.034). The fractional concentrations of PAHs were analyzed by using PCA analysis, which led to the separate clustering of the RI and AG stream sediments and suggest distinct PAH sources between the two land uses. Two PAH source indicators, including Ant/(Ant + Phe) and Fl/(Fl + Py), indicates that PAHs sources in the RI stream sediments are most likely of petroleum origin, while PAHs in the UR and AG stream sediments most likely came from combustion activities. In addition, the concentration and relative potency of carcinogenic PAHs in the coastal stream sediments exhibited similar patterns as the total PAH concentration with respect to land uses. 相似文献
917.
The main objective of this study, within development of engineering solutions for coastal areas depuration, was to establish the role of the benthic macro-organisms in the biodegradation of the detergents in marine environment and to estimate the toxicity of these substances for a particular marine species: the ascidian Styela plicata. The experimental studies undertaken in aquarium with seawater enriched in a pure lynear alkylbenzene sulfonate (LAS), the 1-(p-sulfophenyl)nonane (1C9-LAS), showed that the degradation was two times more fast in presence of the S. plicata, than of the only marine bacteria. The toxicity of this pollutant was also determined. This study demonstrates that the ascidia S. plicata can be a potential biomediator for the surfactant 1C9-LAS, and it can be used to design a pilot project, to bioremediate harbours and the coastal areas interested from the urban pollution. 相似文献
918.
Darbah JN Kubiske ME Nelson N Oksanen E Vapaavuori E Karnosky DF 《Environmental pollution (Barking, Essex : 1987)》2008,155(3):446-452
We studied the effects of long-term exposure (nine years) of birch (Betula papyrifera) trees to elevated CO(2) and/or O(3) on reproduction and seedling development at the Aspen FACE (Free-Air Carbon Dioxide Enrichment) site in Rhinelander, WI. We found that elevated CO(2) increased both the number of trees that flowered and the quantity of flowers (260% increase in male flower production), increased seed weight, germination rate, and seedling vigor. Elevated O(3) also increased flowering but decreased seed weight and germination rate. In the combination treatment (elevated CO(2)+O(3)) seed weight is decreased (20% reduction) while germination rate was unaffected. The evidence from this study indicates that elevated CO(2) may have a largely positive impact on forest tree reproduction and regeneration while elevated O(3) will likely have a negative impact. 相似文献
919.
Microcosm investigations of stormwater pond sediment toxicity to embryonic and larval amphibians: variation in sensitivity among species 总被引:2,自引:0,他引:2
Snodgrass JW Casey RE Joseph D Simon JA 《Environmental pollution (Barking, Essex : 1987)》2008,154(2):291-297
Stormwater ponds have become common features of modern development and often represent significant amounts of open space in urbanized areas. Although stormwater ponds may provide habitat for wildlife, factors responsible for producing variation in wildlife use of ponds have received limited attention. To investigate the role of variation in species tolerances of pollutants in structuring pond-breeding amphibian assemblages, we exposed species tolerant (Bufo americanus) and not tolerant (Rana sylvatica) of urbanization to pond sediments in laboratory microcosms. Pond microcosms had elevated sediment metal levels and chloride water concentrations. Among R. sylvatica embryos, exposure to pond sediments resulted in 100% mortality. In contrast, B. americanus embryos and larvae experienced only sublethal effects (i.e., reduced size at metamorphosis) due to pond sediment exposure. Our results suggest variation in pollutant tolerance among early developmental stages of amphibians may act in concert with terrestrial habitat availability to structure amphibian assemblages associated with stormwater ponds. 相似文献
920.
A series of experiments was performed to prepare acidic macroencapsulated buffers composed of 20% Ca(H2PO4)(2) and 80% Eudragit S 100 polymer and alkaline macrocapsules composed of 65% K2HPO4 and 35% Eudragit E PO polymer (the powdered form of Eudragit E 100). Eudragit S 100 was shown to be soluble at a pH greater than 7.0, while Eudragit E 100 was soluble at a pH less than 7.0. Both polymers did not impart significant biochemical oxygen demand. The Eudragit E PO polymer solution showed low toxicity (EC50=91%) based on the Microtox Acute Toxicity Test compared to the 0.1mM background phosphate buffer solution (EC50=100%) while the Eudragit S 100 polymer solution showed higher toxicity (EC50=53%). Batch tests showed that the acidic macrocapsules reduced the pH of a 0.1mM phosphate solution from 11 to neutral, while the alkaline macrocapsules increased the pH of a 0.1mM phosphate solution from 3 to neutral. The macrocapsules could potentially be used as an in situ proportional pH controller for groundwater remediation. 相似文献