Occurrence and distribution of organochlorine pesticides - lindane, p,p'-DDT, and heptachlor epoxide - in surface water of China

Persistent organochlorine pesticides pollutants (OCPs) have been reported to occur at relatively high concentrations in some Chinese waters. In order to map the distribution of organochlorine pesticides in the surface water throughout China, samples were collected from over 600 sites in seven major river basins and three main internal rivers drainage areas during 2003 and 2004. The surface water samples were analyzed for the representative organochlorine pesticides contaminants including lindane (gamma-HCH), p,p'-DDT and heptachlor epoxide. In general, the most frequently detected compound was lindane, being detected in 83.9% of samples (mean=31.3 ng/l; range <0.17-860 ng/l), and the highest concentration was present in the Yellow River basin. p,p'-DDT was detected in 63.1% of the samples collected (mean=14.6 ng/l; range <0.14-368 ng/l) with the highest concentration present in the Huaihe River basin. Heptachlor epoxide was detected in only 9.3% of water samples (range <0.11-10 ng/l). Measured concentrations for the three compounds were low and rarely exceed the environment quality standard for surface water of China. Lindane was more frequently detected at much higher concentrations in the rivers of northern China compared with those of southern China. The sites with higher concentration of lindane and p,p'-DDT mainly occurred in the Yellow River and Huaihe River basins, so the results of this investigation indicate that the organochlorine pesticide contamination of Yellow River and Huaihe River basins should be of particular concern relative to the other basins. When compared with other regions of the world, it appears that the Chinese surface water is moderately polluted by lindane and p,p'-DDT.     

基于河流健康的辽河干流生态调度分期研究

河流健康受水文条件、人类活动干扰等因素影响存在季节性特点。作为以维护河流健康为目标的生态调度,在四季变化明显的北方地区也应具有分时期的特性。以辽河干流为研究区域,以月为单位对其河流健康进行评价,探讨河流健康的年内变化规律。研究表明辽河干流河流健康状况存在明显的分期特性,不同时期健康状况差异较大。基于上述特点,提出以分期生态调度的方式来改善河流健康,并划分出封冻期、汛前枯水期、汛期、汛后枯水期4个时期。同时确定出封冻期的最小生态需水、枯水期的河流自净需水、汛期的输沙需水的需水要求。最后耦合出辽河干流生态流量过程并与Tennant法比较,表明该流量过程符合天然的径流节律,能更好地维护河流健康     

长江宜宾江段渔业资源现状调查

于2011年5～7月和10月在长江干流宜宾江段进行了鱼类资源调查。共采集到鱼类62种（亚种）,隶属于4目10科40属,其中19种为长江上游特有鱼类。圆口铜鱼（Coreius guichenoti）、瓦氏黄颡鱼（Pelteobagrus vachelli）、鲫（Carassius auratus）、长薄鳅（Leptobotia elongate）、中华沙鳅（Botia superciliaris）、南方鲇（Silurus meridionalis）、铜鱼（Coreius heterodon）、鲢（Hypophthalmichthys molitrix）、鲇（Silurus asotus）等为宜宾江段优势种。对主要经济种的体长体重数据进行了分析,结果表明渔获规格较历史数据下降明显,单船日捕捞量亦有减少,长江宜宾段的渔业资源呈现衰退的趋势。作为向家坝蓄水前最后一次对宜宾江段的鱼类群落结构进行分析,研究结果可以为分析向家坝水库蓄水对长江上游鱼类的影响提供数据参考     

Scientific Basis and Technological Path of Regional Strategic Environmental Assessment

Abstract

The study tries to set up a system to extract strategic environmental assessment (SEA) in exploitation of regional development based on the present situation of environmental assessment in China. First, the article summarizes the emphasis and deficiency of international academic community’s SEA research in the past 10 years. Based on this, the article puts forward the concept and evaluation principles of regional strategic environmental assessment (RSEA). Then the article expounds the necessity of carrying out RSEA. After that, the article discusses in detail the process of RSEA, which includes defining evaluation scope, describing regional background, combing strategic behavior, designing development scenarios, predicting the pressure on environment, assessing environmental impact, screening alternatives and proposing regulation and control schemes.     

农村黑臭水体沉积物细菌群落结构特征

沉积物微生物是农村黑臭水体物质循环和有机物降解等过程的主要驱动者,其群落结构组成常因外界环境的微小变化而变化.以菏泽市东明县29个农村黑臭水体为研究对象,测定农村黑臭水体上覆水和沉积物氮、磷及重金属等污染物指标,结合Illumina测序结果,分析农村黑臭水体沉积物细菌群落组成和多样性特征及其与环境因子的相关性.结果表明,该区域农村黑臭水体上覆水和沉积物中污染物分布范围均较广.与农业面源相比,以农村生活污水为主要污染来源的农村黑臭水体上覆水中氮、磷污染物浓度更高,分别是农业面源的3.1倍和1.5倍.此外,该区域农村黑臭水体沉积物中重金属含量处于较低水平,普遍低于菏泽市土壤元素背景值.该区域农村黑臭水体沉积物细菌群落的优势菌门为变形菌门、放线菌门、绿弯菌门、厚壁菌门和酸杆菌门,这5种优势菌门的序列总和占全部序列的70.3%～83.6%.γ-变形菌纲、α-变形菌纲、厌氧绳菌纲和放线菌纲是沉积物细菌群落的优势菌纲;硫杆菌属和假节杆菌属是其优势菌属.Spearman相关性分析结果表明,环境因子中DO、 COD、 TN、 TP和有机质对农村黑臭水体沉积物细菌菌属有显著影响(P<0.05),沉...     

硅肥等量施用对土壤镉生物有效性和水稻吸收镉的影响

为研究硅（Si）肥等量施用对水稻不同生育期吸收镉（Cd）和土壤Cd生物有效性的影响,采用5种不同种类的Si肥（SiO₂用量为225 kg ·hm^-2）开展田间小区试验.结果表明,随着水稻生育期的延长,水稻根系和茎叶的Cd含量增加;施用Si肥,不同生育期水稻根系、茎叶和籽粒Cd含量平均分别降低14.9%、28.2%和12.2%;硅钙镁铁肥（SiCaMgFe）和水溶Si肥（SiW）处理,籽粒Cd含量分别比对照处理降低21.1%（P<0.05）和21.2%（P<0.05）;水稻根表铁膜中Cd含量（DCB-Cd）随着水稻生育期延长而增加,施用Si肥,水稻不同生育期DCB-Cd含量有高有低,DCB-Cd是根系Cd含量的15.8%~42.8%;与对照相比,施用Si肥水稻成熟期土壤可交换态Cd （Exc-Cd）含量平均降低36.4%,其它形态的含量平均增加12.5%~48.2%.水稻全生育期根系Cd与Si呈极显著负相关,与DCB-Cd呈极显著正相关,DCB-Cd与土壤有效态Cd和有效态Si呈极显著负相关,土壤Exc-Cd与Carb-Cd呈极显著负相关,土壤有效态Cd与pH值呈显著负相关.施用相同Si肥用量,SiCaMgFe和SiW处理降低水稻Cd含量的效果好;施用Si肥通过提高土壤pH值和土壤有效Si含量、降低土壤有效态Cd和Exc-Cd含量,促进Exc-Cd向Carb-Cd转移,减少根表铁膜对Cd的吸附,从而减少水稻对土壤Cd的吸收.     

Removal of polycyclic aromatic hydrocarbons from aqueous solution on soybean stalk-based carbon

Soybean [ (L.) Merr.] stalk-based carbons were prepared by phosphoric acid activation at different carbonization temperatures. Characteristics of the prepared carbon, including specific surface area, iodine number, and amount of methylene blue sorption, were determined. Experiments on phenanthrene, naphthalene, and acenaphthene, as representatives of polycyclic aromatic hydrocarbons (PAHs), removal from aqueous solution by the prepared carbon were conducted at different levels of carbon addition. The results indicated that the specific surface area, iodine number, and amount of methylene blue sorption increased with an increase of carbonization temperature. The maximum values were observed at 700°C and were 287.63 m g, 508.99 mg g, and 90.14 mg g, respectively. The removal efficiencies of phenanthrene, naphthalene, and acenaphthene tended to increase with increasing carbon amounts and carbonization temperature. The optimal removal performance was obtained under the experimental conditions of carbon concentrations of 0.04 g 32 mL and carbonization temperature of 700°C, and the removal efficiencies of phenanthrene, naphthalene, and acenaphthene were 99.89, 100, and 95.64%, respectively. The performance of the prepared carbon was superior to that of commercial activated carbon. Additionally, for the same carbon concentrations, the removal efficiency of PAHs on prepared carbons followed the order: phenanthrene > naphthalene > acenaphthene. Results obtained from this work provide some insight into the reuse of an agricultural residue, and also provide a new application for the treatment of PAHs in contaminated water utilizing activated carbon prepared from agricultural residues.     

异烟酸-吡唑啉酮光度法测定地表水中氰化物的质量控制指标研究

通过对大量监测数据进行统计分析,获得异烟酸-吡唑啉酮光度法（HJ484—2009）测定水中氰化物质量控制评定指标。研究表明：样品浓度在0．05～0．3mg／L范围内时,建议控制室内相对标准偏差≤3％,室间相对标准偏差≤10％;样品浓度小于等于0．05mg／L时,建议控制相对偏差≤10％;样品浓度大于0．05mg／L时,...     

可靠性增长摸底试验方法研究分析

介绍了可靠性增长摸底试验方法的适用范围,对其试验对象进行了探讨,并对如何确定最佳试验时间的两种方法进行了研究.分析指出试验应力的选取也是影响可靠性增长摸底试验效果的关键因素,并用具体试验方案举例说明其有效性,证明了开展可靠性增长摸底试验这项工作可达到快速有效、节约经费的作用.     

煤工尘肺患者生存质量与家庭功能和社会支持的关系研究

为了解煤工尘肺患者的生存质量的现状及其与家庭功能和社会支持之间的关系,采用SF-36量表、家庭功能评定量表和社会支持评定量表对212名煤工尘肺患者进行问卷调查。单因素分析显示,煤工尘肺患者在SF-36量表的躯体疼痛、总体健康、活力、情感职能、精神健康5个维度的得分与对照组的差异有统计学意义（p〈0.05）。生存质量得分与家庭功能得分呈负相关,生存质量得分与社会支持得分呈正相关。以生存质量得分为因变量,以家庭功能和社会支持的分量表得分为自变量进行多元逐步回归分析显示,生存质量的影响因素为社会支持利用度、家庭功能的总的功能、情感介入、社会支持的客观支持和问题解决。研究结果表明,煤工尘肺患者生存质量较低,与其家庭功能和社会支持有密切关系,需要从家庭功能和社会支持采取综合措施,提高煤工尘肺患者的生存质量。