This study aimed at finding effective strategies for high-performance removal of reactive blue 19 (RB19) dye from aqueous solution. Chitosan (CS) films had been prepared by using solvent casting with mild drying for this purpose. The CS films were characterized by X-ray diffraction, field-emission scanning electron microscopy, and Fourier transform infrared (FTIR) spectroscopy. The performance of RB19 removal using CS were evaluated by varying contact time, solution pH, initial dye concentration, and adsorbent dosage. Adsorption isotherms, kinetics, and desorption were investigated by batch experiments. Results showed that CS films exhibited the optimal adsorption performance for RB19 removal and high maximum adsorption capacities of RB19, which were 799 and 822.4 mg g?1 at 20 and 40 °C, respectively. Adsorption kinetic data were well described by the pseudo-second-order kinetic model. FTIR analyses further indicated that interactions between RB19 and the CS film occurred during adsorption. The CS films also exhibited satisfactory desorption of RB19 at about 80 % after 30 min of desorption at pH 11. Our study demonstrated that the CS films can be easily prepared and applied for effective removal of RB19 in treatment of wastewater. 相似文献
The use of recurrence plots have been extensively used in various fields. In this work, recurrence plots investigate the changes in the non-linear behaviour of urban air pollution using large datasets of raw data (hourly). This analysis has not been used before to extract information from large datasets for this type of non-linear problem. Two different approaches have been used to tackle this problem. The first approach is to show results according to monitoring network. The second approach is to show the results by particle type. This analysis shows the feasibility of using recurrence analysis for pollution monitoring and control. 相似文献
A considerable number of bird species carry feathers to their nests. Feathers’ presence in the nests has traditionally been
explained by their insulating properties. Recently, however, it has been suggested that feathers carried to the nests by females
of the spotted starling (Sturnus unicolor L.) could have an ornamental function based on their ultraviolet (300–400 nm) and human-visible longer wavelength (400–700 nm)
coloration. In our population, 95.7% of feathers found inside next-boxes occupied by nesting starlings were rock dove fly
feathers. Of these feathers, 82.7% were naturally positioned with their reverse side oriented toward the entrance hole and
42.4% of all found feathers were situated within the nest-cup. Here we experimentally assess the signaling function of ultraviolet
coloration of feathers in nests of spotless starlings by providing nests with a number of pigeon flight feathers that were
respectively treated on their obverse, reverse, both, or neither side with a UV blocker. Starlings placed 42.5% of the experimental
feathers in the nest-cup irrespective of the UV block treatment. Orientation of feathers toward the entrance hole was not
related with their ultraviolet radiation. However, feathers placed within the nest-cup were more likely found with their reverse
side oriented toward the entrance hole confirming our correlative findings. These results suggest a minor role of ultraviolet
coloration on feather location by spotless starlings. 相似文献
In this study, different pretreatment strategies of sugarcane bagasse prior to citric acid modification were investigated in terms of Pb2+ adsorption capacity. Pretreatment strategies included the use of NaOH, HCl, and C2H5OH in various concentrations. In order to fundamentally understand how these pretreatment methods affect the modification of sugarcane bagasse by citric acid as well as the Pb2+ adsorption capacity of sugarcane bagasse, three main components of sugarcane bagasse namely cellulose, hemicellulose, and lignin were isolated and esterified by citric acid under the same conditions. ATR-FTIR, XPS, SEM, and an analysis of the number of carboxylic acid groups were used to investigate the physicochemical and chemical properties of the materials. These three components were proved to participate in adsorption and induce the esterification with citric acid. Hence, pretreatment with ethanol and 0.01 M NaOH which could retain cellulose, hemicellulose, and lignin in sugarcane bagasse achieved a high Pb2+ adsorption capacity, i.e., 122.4 and 97 mg/g after the esterification with citric acid. In contrast, pretreatment with 0.5 M NaOH and 0.1 M HCl removed lignin and hemicellulose, leading to the lowest value of approximately 45 mg/g for citric acid esterified-pretreated sugarcane bagasse. XPS analysis and number of carboxylic group measurement confirmed the esterification between bagasse and citric acid. To understand the adsorption mechanism of adsorbent, two kinetic models including pseudo-first-order model and pseudo-second-order model were applied. The experimental data were well described by the pseudo-second-order model. The adsorption isotherm data were fitted Langmuir and Freundlich.
Environmental Science and Pollution Research - The aim of this study was to analyze dispersion behavior characteristics and pollution hazard risk after a release of liquid chlorine. A full-scale... 相似文献