Changes in the phytoplankton community at Helgoland, North Sea: lessons from single spot time series analyses

In recent regime shift analyses, the phytoplankton compartment of the marine food web was essentially represented by phytoplankton color or chlorophyll concentration. A detection of changes directly at the species level is highly desirable. The Helgoland Roads data series, a collection of high frequency long-term time series comprising biological and physico-chemical components of the southern North Sea, allow such an investigation at the level of single species. Aiming at a detection and characterization of habitat and community changes in the observation period (1962 until the end of 2008), we selected six species as representatives of certain classes, for example, benthic or neritic species, and applied a combination of novel analysis methods—a fitness-based analysis of the realized niche, a bloom-triggered averaging and a Markovian analysis of co-occurrence and succession patterns—to related abundance time series and concurrent environmental parameter time series. We found a general trend toward enlargement of niche size and shifts of the niche position, interesting salinity patterns around bloom events of two species, and statistically highly significant changes of a phytoplankton community segment after 1965 and after 1998. Interpreting our observations in ecological terms leads to the formulation of testable hypotheses.     

云南省生态资产与生态系统生产总值核算体系研究

生态系统作为重要的生态资产,为人类提供生态产品和服务,是人类生存和社会经济可持续发展的基础;生态系统生产总值（GEP）是生态资产提供的生态产品与服务价值总和,是生态资产的重要组成部分,也是生态资产对人类福祉的主要贡献。论文以云南省为例,分析了生态资产和GEP的内涵、关联与核算体系,评价了云南省2010年生态资产状况及其为受益者提供生态产品和服务价值的总和。评价结果显示：云南省2010年生态资产状况总体良好,林地、灌丛和草地生态系统的质量水平属于良等级;农田生态系统的质量水平差;生物多样性质量水平优。云南省2010年GEP总量为29 869.51亿元,其中,直接产品价值为4 132.69亿元,间接服务价值为25 736.81亿元。2010年GEP是当年该省国内生产总值（GDP）的4.13倍。研究结果表明,生态资产与GEP的核算,可以定量反映生态系统状况及其对区域社会经济发展的支撑作用,并为评估区域生态系统保护成效及建立生态系统可持续管理与绩效考核机制提供科学依据。     

Modelling spatial patterns of correlations between concentrations of heavy metals in mosses and atmospheric deposition in 2010 across Europe

Background

This paper aims to investigate the correlations between the concentrations of nine heavy metals in moss and atmospheric deposition within ecological land classes covering Europe. Additionally, it is examined to what extent the statistical relations are affected by the land use around the moss sampling sites. Based on moss data collected in 2010/2011 throughout Europe and data on total atmospheric deposition modelled by two chemical transport models (EMEP MSC-E, LOTOS-EUROS), correlation coefficients between concentrations of heavy metals in moss and in modelled atmospheric deposition were specified for spatial subsamples defined by ecological land classes of Europe (ELCE) as a spatial reference system. Linear discriminant analysis (LDA) and logistic regression (LR) were then used to separate moss sampling sites regarding their contribution to the strength of correlation considering the areal percentage of urban, agricultural and forestry land use around the sampling location. After verification LDA models by LR, LDA models were used to transform spatial information on the land use to maps of potential correlation levels, applicable for future network planning in the European Moss Survey.

Results

Correlations between concentrations of heavy metals in moss and in modelled atmospheric deposition were found to be specific for elements and ELCE units. Land use around the sampling sites mainly influences the correlation level. Small radiuses around the sampling sites examined (5 km) are more relevant for Cd, Cu, Ni, and Zn, while the areal percentage of urban and agricultural land use within large radiuses (75–100 km) is more relevant for As, Cr, Hg, Pb, and V. Most valid LDA models pattern with error rates of <?40% were found for As, Cr, Cu, Hg, Pb, and V. Land use-dependent predictions of spatial patterns split up Europe into investigation areas revealing potentially high (=?above-average) or low (=?below-average) correlation coefficients.

Conclusions

LDA is an eligible method identifying and ranking boundary conditions of correlations between atmospheric deposition and respective concentrations of heavy metals in moss and related mapping considering the influence of the land use around moss sampling sites.

     

Synthesis of silica materials containing cyclodextrin and their applications in wastewater treatment

Environmental Chemistry Letters - Cyclodextrin-functionalized silica networks are advanced&nbsp;adsorbents for environmental applications. Silica-based adsorbents are low-cost and robust...     

A new flux-orientated concept to derive critical levels for ozone to protect vegetation

The current European critical levels for ozone (O3) to protect crops, natural and semi-natural vegetation and forest trees are based on a relative small number of open-top chamber experiments with a very limited number of plant species. Therefore, the working group "Effects of Ozone on Plants" of the Commission on Air Pollution Prevention of the Association of German Engineers and the German Institute of Standardization reanalysed the literature on O3 effects on European plant species published between 1989 and 1999. An exposure-response relationship for wild plant species and agricultural crops could be derived from 30 experiments with more than 30 species and 90 data points; the relationship for conifer and deciduous trees is based on 20 experiments with nine species and 50 data points. From these relationships maximum O3 concentrations for different risk stages are deduced, below which the vegetation type is protected on the basis of the respective criteria. Because it is assumed that the fumigation concentrations reflect the O3 concentrations at the top of the canopy, i.e. the upper surface boundary of the quasi-laminar layer if the micrometeorological big-leaf approach is applied, the application of these maximum O3 concentrations requires the transformation of O3 concentrations measured at a reference height above the canopy to the effective phytotoxic concentrations at the top of the canopy. Thus, the approach described in this paper is a synthesis of the classical concept of toxicology of air pollutants (critical concentrations) and the more toxicological relevant dose concept.     

Artificial recharge of humic ground water

The purpose of this study was to investigate the efficiency of soil in removing natural organic matter from humic ground waters using artificial recharge. The study site, in western Denmark, was a 10,000 ml football field of which 2,000 m2 served as an infiltration field. The impact of the artificial recharge was studied by monitoring the water level and the quality of the underlying shallow aquifer. The humic ground water contained mainly humic adds with an organic carbon (OC) concentration of 100 to 200 mg C L(-1). A total of 5,000 mS of humic ground water were sprinkled onto the infiltration field at an average rate of 4.25 mm h(-1). This resulted in a rise in the water table of the shallow aquifer. The organic matter concentration of the water in the shallow aquifer, however, remained below 2.7 mg C L(-1). The organic matter concentration of the pore water in the unsaturated zone was measured at the end of the experiment. The organic matter concentration of the pore water decreased from 105 mg C L(-1) at 0.5 m to 20 mg C L(-1) at 2.5 m under the infiltration field indicating that the soil removed the organic matter from the humic ground water. From these results we conclude that artificial recharge is a possible method for humic ground water treatment.     

Benchmark Criteria: A Tool for Selecting Appropriate Models in the Field of Water Management

A milestone in the field of European water protection policy is the European Union’s Water Framework Directive (WFD), which came into force in December 2000 and which integrates the management of European waters in many ways. In this study, we start by focusing on management issues connected to the implementation of the WFD and pose a question: “what type of models would be the most suitable for use in the context of the WFD?” With this question in mind, we aim to establish a set of operational and functional selection criteria for (computer) models whose application is intended to support decision-making related to a particular water management issue. These so-called “benchmark criteria” should help water managers and other model users in choosing appropriate models, e.g., for the WFD implementation purposes. We first describe models and their use in general and then propose an approach for setting the benchmark criteria for models, basing it on the concept of uncertainty management, while keeping firmly in mind the important role of citizens and citizen organizations in water management. The suggested benchmark criteria are in the form of 14 questions through which each model can be evaluated. Finally, the process for testing and refining the benchmark criteria is highlighted.