Effects of Cu（Ⅱ） and humic acid on atrazine photodegradation

This work was designed to explore the characteristics of photodegradation of herbicides in the copper-polluted water body. The results showed that Cu(II) alone could induce a photo Fenton-like reaction to enhance the degradation of atrazine, in which hydroxyl radical ( OH) was a main active species. Humic acids restrained atrazine degradation, nevertheless, when introducing Cu(II), the photodegradation was accelerated, in which singlet oxygen (1O2) replaced OH acting as the prevailing species. A feasible mechanism for the photochemical process was also proposed, which is helpful for better understanding the environmental photochemistry of atrazine in the copper-polluted water.     

Interspecific competition effects on phosphorus accumulation by Hydrilla verticillata and Vallisneria natans

The competition between submersed plants has been recognized as an important factor influencing the structure of plant communities in shallow lakes. The ability of different species to take up and store nutrients from the surrounding ambience varies, and hence plant community structure might be expected to affect the cycling of nutrients in lake ecosystems. In this study, the uptake of phosphorus by Hydrilla verticillata and Vallisneria natans was studied and compared in monoculture and competitive mixed-culture plantings. Results showed that for both studied species the phosphorus concentrations of different tissues and of whole plants was unaffected by competition. However, the quantity of phosphorus accumulated by whole plants of H. verticillata was significantly higher in mixture culture than in monoculture, while that of V. natans was lower in the mixed culture. The results indicated that H. verticillata has a competitive advantage over V. natans, when the two species are grown in competition, and is able to accumulate a greater quantity of phosphorus.     

Chemical cleaning of fouled PVC membrane during ultrafiltration of algal-rich water

Cleaning of hollow-fibre polyvinyl chloride (PVC) membrane with di erent chemical reagents after ultrafiltration of algal-rich water was investigated. Among the tested cleaning reagents (NaOH, HCl, EDTA, and NaClO), 100 mg/L NaClO exhibited the best performance (88.4% 1.1%) in removing the irreversible fouling resistance. This might be attributed to the fact that NaClO could eliminate almost all the major foulants such as carbohydrate-like and protein-like materials on the membrane surface, as confirmed by Fourier transform infrared spectroscopy analysis. However, negligible irreversible resistance (1.5% 1.0%) was obtained when the membrane was cleaning by 500 mg/L NaOH for 1.0 hr, although the NaOH solution could also desorb a portion of the major foulants from the fouled PVC membrane. Scanning electronic microscopy and atomic force microscopy analyses demonstrated that 500 mg/L NaOH could change the structure of the residual foulants on the membrane, making them more tightly attached to the membrane surface. This phenomenon might be responsible for the negligible membrane permeability restoration after NaOH cleaning. On the other hand, the microscopic analyses reflected that NaClO could e ectively remove the foulants accumulated on the membrane surface.     

Synthesis and scale inhibitor performance of polyaspartic acid

Polyaspartic acid (PASP) has been extensively studied in recent years as a green scale inhibitor. PASP was synthesized by thermal polycondensation of maleic anhydride and ammonium carbonate in this study. The optimal polycondensation reaction conditions were the raw material (maleic anhydride and ammonium carbonate) molar ratio of 1.0:1.2, the polymerization temperature of 180°C and reaction time of 2.0 hr. The results showed that PASP exhibits very good scale inhibiting performance. The inhibition rate was 95% for calcium carbonate and 90% for calcium sulfate by the application of 5 mg/L PASP.     

微波酸活化粉煤灰吸附酸性大红染料废水实验研究

以微波酸活化改性后的粉煤灰为吸附剂,对酸性大红染料废水进行吸附脱色处理,考察了吸附时间、pH值、吸附剂投加量等对吸附脱色效果的影响。在酸性大红染料溶液初始浓度为100 mg/L、pH=5、活化粉煤灰投加量为10 g/L吸附1 h时,活化粉煤灰对酸性大红的脱色效果较好,去除率可达96%。对实验数据进行相关数学模型拟合,结果表明微波酸活化改性后的粉煤灰吸附去除酸性大红的等温吸附平衡符合Langmuir吸附等温式,改性前后的吸附过程动力学符合准二级吸附动力学模型,线性相关系数良好。     

福州城市边缘区森林土壤重金属污染特征及评价

为掌握福州城市边缘区森林土壤重金属污染特征,选取10个典型区域作为研究对象,分析森林土壤中Zn、Mn、Cr、Pb、Cu 5种重金属的含量及分布特征,并采用单项污染指数和综合污染指数法对土壤进行质量评价,结果表明:Cr、Pb是该区土壤重金属污染最主要的元素;Zn、Cu、Pb、Cr含量随土层深度增加而减少,Mn则相反;Zn...     

膨胀石墨污水净化处理研究

利用膨胀石墨强大的吸附能力来处理城市生活污水,结果发现用膨胀石墨处理污水的前8h,COD的去除率达43％;处理第5～9d将出现第二个高峰,COD的去除率达48％,分析原因可能是存在物理吸附和微生物絮凝两方面的作用。最后经过20d的处理,膨胀石墨对生活污水的COD和BOD总去除率分别达到86％、78．9％,且除臭能力也很显著。     

进一步探讨内蒙古自治区环境突发性污染事件应急监测工作

随着内蒙古经济社会的快速发展,环境突发性事件应急监测存在一些新问题,根据内蒙古实际情况,探讨环境突发性污染事件应急监测工作思路,进一步保护环境和人类生命安全。     

进一步探讨内蒙古自治区环境突发性污染事件应急监测工作

随着内蒙古经济社会的快速发展,环境突发性事件应急监测存在一些新问题,根据内蒙古实际情况,探讨环境突发性污染事件应急监测工作思路,进一步保护环境和人类生命安全。     

谈建设项目竣工验收监测质量控制

质量控制是贯穿环境监测全过程的技术手段和管理程序,文章通过对建设项竣工验收监测质量控制进行阐述,其目的是为了提高我们的监测水平和能力,更好的保护好我们的生态环境。