基于24Model的矿工怠工行为 管理模式架构及策略研究

为减少矿工怠工行为,基于24Model研究矿工怠工行为的管理模式架构及策略。首先,基于冰山模型理论分析矿工怠工行为的影响因素;其次,基于24Model和行为修正理论提出集怠工行为识别、行为原因分析、行为管理策略选择和行为修正评估于一体的矿工怠工行为管理模式架构;最后,提出了针对性的管理策略。对于提高煤矿企业矿工的工作绩效具有重要的理论意义和实践价值。     

一种导电混凝土的制备及其电阻率测量

本文综述了导电混凝土的发展以及应用情况，提出了用导电混凝土作为接地材料的设想，并选择氧化铁粉作为骨料，添加适量碳粉配制了一种导电混凝土来验证。通过改变不同的配比制作导电混凝土模型，用四电极法测量其电阻率，得出碳粉比例对其电阻率的影响。     

“十三五”期间中国生态环境质量变化特征

以国家生态环境监测网监测结果为基础,总结归纳了"十三五"时期中国生态环境质量变化特征和主要环境问题。结果表明:"十三五"期间,全国生态环境质量全面好转,2020年环境空气优良天数比例比"十二五"末期上升5.8个百分点;地表水总体水质由轻度污染转为良好,Ⅰ～Ⅲ类水质断面比例上升17.4个百分点,劣V类断面比例下降9.0个百分点;酸雨污染程度减轻,海洋等环境要素质量稳中向好。但与此同时,后续改善难度加大,全国仍有40%地级及以上城市空气质量超标,4.8%的国土面积发生酸雨,辽河和海河流域仍是轻度污染,部分河流污染较重,地下水以IV类水质为主,农村饮用水源地和地表水水质均受到不同程度污染,近三分之一国土面积县域生态质量为较差和差。总体来看,当前生态环境质量与人民对美好生态环境的需求和美丽中国目标的实现还有较大差距。逐年上升的能源消费总量和不断增长的汽车保有量,增加了生态环境质量继续改善的压力。     

Volcano-related materials in concretes: a comprehensive review

Massive volcano-related materials (VRMs) erupted from volcanoes bring the impacts to natural environment and humanity health worldwide, which include generally volcanic ash (VA), volcanic pumice (VP), volcanic tuff (VT), etc. Considering the pozzolanic activities and mechanical characters of these materials, civil engineers propose to use them in low carbon/cement and environment-friendly concrete industries as supplementary cementitious materials (SCMs) or artificial/natural aggregates. The utilization of VRMs in concretes has attracted increasing and pressing attentions from research community. Through a literature review, this paper presents comprehensively the properties of VRMs and VRM concretes (VRMCs), including the physical and chemical properties of raw VRMs and VRMCs, and the fresh, microstructural and mechanical properties of VRMCs. Besides, considering environmental impacts and the development of long-term properties, the durability and stability properties of VRMCs also are summarized in this paper. The former focuses on the resistance properties of VRMCs when subjected to aggressive environmental impacts such as chloride, sulfate, seawater, and freezing–thawing. The latter mainly includes the fatigue, creep, heat-insulating, and expansion properties of VRMCs. This study will be helpful to promote the sustainability in concrete industries, protect natural environment, and reduce the impacts of volcano disaster. Based on this review, some main conclusions are discussed and important recommendations regarding future research on the application of VRMs in concrete industries are provided.     

Selenium status of children in Kashin–Beck disease endemic areas in Shaanxi,China: assessment with mercury

Environmental Geochemistry and Health - The causes of Kashin–Beck disease (KBD) in children are multifactorial, and particular consideration has been given to childhood selenium (Se)...     

河南省在用柴油车加载减速烟度排放限值研究

随着车辆技术进步和燃油品质提升,河南省在用柴油车加载减速污染物现行排放限值已不能对高排放车辆进行有效监控。依据《确定压燃式发动机在用汽车加载减速法排气烟度排放限值的原则和方法》(HJ/T 241—2005),采用相对光吸收系数与累积频率法,对9 458份在用柴油车检测数据进行统计分析,提出符合河南省的在用柴油车排放限值。建议河南省在用国三、国四、国五轻型柴油车尾气光吸收系数限值分别为0.98、0.89、0.76m~(-1),而相应重型柴油车尾气光吸收系数限值分别为0.66、0.62、0.48m~(-1);依据该限值,河南省在用柴油车的年检合格率控制在82.6%,高排放柴油车比例为17.4%,符合HJ/T 241—2005的要求。     

雷管壳体安全检测过程的模拟与检测时间的确定

采用数值模拟与现场试验相结合的方法,分析了带缺陷雷管在气压检测过程中气体的泄漏过程,确定了最佳的检测时间。采用Fluent建立了缺陷雷管正气压检测模型,分析了缺陷在不同位置处的气体泄漏过程,研究了气体泄漏过程中,雷管内部气压的分布及其随时间变化过程,结果表明:距雷管顶端的缺陷因尺寸较大,所以该泄漏点的压强要大于侧壁处,而气体泄漏流速小于侧壁处,综合分析缺陷处和雷管内部的气体压降过程及试验,可确定4s为最佳的充气时间,5s作为最佳的雷管质量诊断时间。     

Determination of 27 pharmaceuticals and personal care products (PPCPs) in water: The benefit of isotope dilution

• Isotope dilution method was developed for the determination of 27 PPCPs in water. • The established method was successfully applied to different types of water samples. • The correction effect of corresponding 27 ILSs over 70 d was investigated. • Benefit of isotopic dilution method was illustrated for three examples. Pharmaceuticals and personal care products (PPCPs) are a unique group of emerging and non-persistent contaminants. In this study, 27 PPCPs in various water samples were extracted by solid phase extraction (SPE), and determined by isotope dilution method using liquid chromatography coupled to tandem triple quadruple mass spectrometer (LC-MS/MS). A total of 27 isotopically labeled standards (ILSs) were applied to correct the concentration of PPCPs in spiked ultrapure water, drinking water, river, effluent and influent sewage. The corrected recoveries were 73%–122% with the relative standard deviation (RSD)<16%, except for acetaminophen. The matrix effect for all kinds of water samples was<22% and the method quantitation limits (MQLs) were 0.45–8.6 ng/L. The developed method was successfully applied on environmental water samples. The SPE extracts of spiked ultrapure water, drinking water, river and wastewater effluent were stored for 70 days, and the ILSs-corrected recoveries of 27 PPCPs were obtained to evaluate the correction ability of ILSs in the presence of variety interferences. The recoveries of 27 PPCPs over 70 days were within the scope of 72%–140% with the recovery variation<37% in all cases. The isotope dilution method seems to be of benefit when the extract has to be stored for long time before the instrument analysis.     

机械活化煤气化细渣资源化利用及残碳燃烧反应动力学探究

随着我国煤气化技术的快速发展，气化渣的产生和排放量逐年增加.煤气化细渣的大量堆存，给当地的环境保护造成了巨大的压力，已经成为限制煤化工产业基地可持续发展急需解决的重大问题.本文针对气化细渣中残碳反应活性低和转化难度大的问题，研究了机械活化法对气化渣残碳反应动力学的影响.采用Coats-Redfern法分析了机械活化对残碳反应活化能的作用规律.结果表明，机械活化8 h，残碳燃烧反应活性显著提高，650℃下的活化能由63.2 k J·mol^-1降到28.4 k J·mol^-1.不添加其他化学试剂，1000℃烧制高强度轻质陶粒，其堆积密度为0.867 g·cm^-3，筒压强度为7.67 MPa.相关研究可以为我国气化细渣的资源化利用提供一定的数据和技术基础.