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181.
Givelet N Le Roux G Cheburkin A Chen B Frank J Goodsite ME Kempter H Krachler M Noernberg T Rausch N Rheinberger S Roos-Barraclough F Sapkota A Scholz C Shotyk W 《Journal of environmental monitoring : JEM》2004,6(5):481-492
For detailed reconstructions of atmospheric metal deposition using peat cores from bogs, a comprehensive protocol for working with peat cores is proposed. The first step is to locate and determine suitable sampling sites in accordance with the principal goal of the study, the period of time of interest and the precision required. Using the state of the art procedures and field equipment, peat cores are collected in such a way as to provide high quality records for paleoenvironmental study. Pertinent field observations gathered during the fieldwork are recorded in a field report. Cores are kept frozen at -18 degree C until they can be prepared in the laboratory. Frozen peat cores are precisely cut into 1 cm slices using a stainless steel band saw with stainless steel blades. The outside edges of each slice are removed using a titanium knife to avoid any possible contamination which might have occurred during the sampling and handling stage. Each slice is split, with one-half kept frozen for future studies (archived), and the other half further subdivided for physical, chemical, and mineralogical analyses. Physical parameters such as ash and water contents, the bulk density and the degree of decomposition of the peat are determined using established methods. A subsample is dried overnight at 105 degree C in a drying oven and milled in a centrifugal mill with titanium sieve. Prior to any expensive and time consuming chemical procedures and analyses, the resulting powdered samples, after manual homogenisation, are measured for more than twenty-two major and trace elements using non-destructive X-Ray fluorescence (XRF) methods. This approach provides lots of valuable geochemical data which documents the natural geochemical processes which occur in the peat profiles and their possible effect on the trace metal profiles. The development, evaluation and use of peat cores from bogs as archives of high-resolution records of atmospheric deposition of mineral dust and trace elements have led to the development of many analytical procedures which now permit the measurement of a wide range of elements in peat samples such as lead and lead isotope ratios, mercury, arsenic, antimony, silver, molybdenum, thorium, uranium, rare earth elements. Radiometric methods (the carbon bomb pulse of (14)C, (210)Pb and conventional (14)C dating) are combined to allow reliable age-depth models to be reconstructed for each peat profile. 相似文献
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185.
Degradation of Pesticides on Plant Surfaces and its Prediction - A Case Study on Tea Plant 总被引:4,自引:0,他引:4
The degradative kinetics of pesticides on plant surface are characterized by an initial rapid degradation which follows a first-order kinetics, then transferred to a more slower degradative rate. The degradative process mainly consists of photodegradation, evaporation, rainfall elution and growth dilution. The influencing parameters of these processes were investigated by using the tea plant as a case study. The predictive model of the initial concentration, photodegradation rate constant, evaporation rate constant, rainfall elution rate, growth dilution rate and the total degradation rate was discussed and verified in four locations situated in the range of 25°-30°N latitude, and acceptable results were obtained. 相似文献
186.
通过实验与实际工程相结合,定量描述了大气采样系统中金属氧化物的存在对SO2测定值的影响,并阐述了其反应机理,提出了相应措施。 相似文献
187.
Thin-film technique is becoming an industry standard for the preparation of TiO2-based photocatalyst for organic destruction. The catalyst provides several advantages over the conventional powder TiO2 in the treatment of wastewater and groundwater. In this study, a continuous stir flow reactor model is developed capable of describing the photocatalytic process. The model incorporates the following fundamental mechanisms: adsorption, diffusion, liquid-film transfer, UV attenuation, and photocatalytic reaction. All of the simulation results indicate that there exists a highly nonlinear relation between each of these parameters and the destruction rate. Various incident light intensities also are incorporated to simulate the energy efficiency. The simulations illustrate that the photocatalytic model can be used to elucidate the effect of process variables. It is also possible to “custom-design” a catalyst for the treatment of a particular waste stream. 相似文献
188.
Methane emissions from natural wetlands 总被引:3,自引:0,他引:3
Zhengping Wang Dong Zeng William H. Patrick Jr. 《Environmental monitoring and assessment》1996,42(1-2):143-161
Methane is considered one of the most important greenhouse gases in the atmosphere. Because of the strict anaerobic conditions required by CH4-generating microorganisms, natural wetland ecosystems are one of the main sources of biogenic CH4. The total natural wetland area is estimated to be 5.3 to 5.7 × 1012 m2, making up less than 5% of the Earth's land surface. However, natural wetland plays a disproportionately large role in CH4 emissions. Wetlands are likely the largest natural sources of CH4 to the atmosphere, accounting for about 20% of the current global annual emission. Out of the total amount of CH4 emitted, northern wetlands contribute 34%, temperate wetlands 5%, and tropical systems about 60%.Because of the unique characteristics and high productivity, wetland ecosystems are important in the global carbon cycle. Natural wetlands are permanently or temporarily saturated. Strict anaerobic conditions consequently develop, which allows methanogenesis to occur. But the thin oxic layer and the oxic plant rhizophere promote activity of CH4-oxidizing bacteria or methanotrophs. Thus, both CH4 formation and consumption in wetland systems are microbiological processes and are controlled by many factors. Eight of the controlling factors, including carbon supply, soil oxidation-reduction status, pH, temperature, vegetation, salinity and sulfate content, soil hydrological conditions and CH4 oxidation are discussed in this paper. 相似文献
189.
用密切值法评价沙湾荒漠区生态环境质量 总被引:3,自引:0,他引:3
利用多目标决策中的密切值法进行沙湾荒漠区生态环境综合评价。该方法简便、适用、且分辨率较高,对各监测点群的定量描述符合实际状况。 相似文献
190.
根据塔里木油田1993-1996年环境空气监测数据,对其环境空气质量状况进行了分析和评价。 相似文献