利用高炉水淬渣制作多孔吸声材料的研究

为了促进高炉炼铁水淬渣的二次利用,研究了以高炉炼铁水淬渣为原料,以硅微粉或水泥为粘结剂,采用压制成型方法制作的多孔吸声材料的吸声性能及力学性能。结果表明:用颗粒状的高炉炼铁水淬渣制作的多孔吸声材料具有良好的吸声性能,其平均吸声系数可以达到0.70以上;材料的抗压强度可以达到3.0 MPa以上。     

炼油废水处理的现状、问题及对策

针对原油性质日趋恶劣、排放标准日益严格的形势,介绍了炼油废水的处理现状,分析了炼油废水在达标排放、处理回用、运行成本等方面面临的主要问题,提出了从源头挖掘节水减排潜力、实施装置排水分级控制与高浓度废水预处理、对废水处理场进行适度改造和补充完善、开发含盐废水处理技术等对策。     

Tracking nitrogen losses in a greenhouse crop rotation experiment in North China using the EU-Rotate_N simulation model

Vegetable production in China is associated with high inputs of nitrogen, posing a risk of losses to the environment. Organic matter mineralisation is a considerable source of nitrogen (N) which is hard to quantify. In a two-year greenhouse cucumber experiment with different N treatments in North China, non-observed pathways of the N cycle were estimated using the EU-Rotate_N simulation model. EU-Rotate_N was calibrated against crop dry matter and soil moisture data to predict crop N uptake, soil mineral N contents, N mineralisation and N loss. Crop N uptake (Modelling Efficiencies (ME) between 0.80 and 0.92) and soil mineral N contents in different soil layers (ME between 0.24 and 0.74) were satisfactorily simulated by the model for all N treatments except for the traditional N management. The model predicted high N mineralisation rates and N leaching losses, suggesting that previously published estimates of N leaching for these production systems strongly underestimated the mineralisation of N from organic matter.     

A competitive indirect enzyme-linked immunoassay for lead ion measurement using mAbs against the lead-DTPA complex

Immunoassays for quantitative measurement of environmental heavy metals offer several advantages over other traditional methods. To develop an immunoassay for lead, Balb/c mice were immunized with a lead-chelate-protein conjugate to allow maximum exposure of the metal to the immune system. Three stable hybridoma cell lines were obtained through spleen cells fusion with Sp2/0 cells. One cell line, 2A11D11, produced mAbs with preferential selectivity and sensitivity for Pb-DTPA than DTPA, exhibiting an affinity constant of 3.34 ± 0.24 × 10⁹ M⁻¹. Cross reactivity (CR) with other metals were below 1%, except for Fe(III) with a CR less than 5%. This quantitative indirect ELISA for the lead ion was used to detect environmental lead content in local water sources; importantly, the results from the immunoassay were in excellent agreement with those from ICP-MS. Development of immunoassays for metal ions may thus facilitate the detection and regulation of environmental pollution.     

植物配置对表层流湿地净化效果的影响研究

以郑州市贾鲁河河水为处理对象,研究了不同植物配置表层流湿地的水质净化效果及影响因素。研究表明,单纯挺水植物湿地对TN、TP、NH4+-N和COD的平均去除率分别为28%、58%、49%和26%;采用沉水植物+浮叶植物+挺水植物组合的湿地对TN、TP、NH4+-N和COD的平均去除率分别为37%、64%、63%和32%,在对NH4+-N和TN的处理效果上表现出明显的优势,DO含量变化是导致处理效果差异的主要原因。研究结果表明,在湿地植物配置上,可从氮循环的角度,通过合理搭配湿地植物,强化硝化反硝化作用,以提高对氮素的去除效果。     

山海关区农村生态环境状况及保护对策

从山海关区农村生态环境现状出发,客观分析了农村生态环境存在的水体污染、土壤污染、水土流失等问题,以及影响农村生态环境的主要因素,如污水和垃圾的无组织排放、化肥和农药的不合理使用、基础设施差、监管缺位等,提出应从环保体制、环保意识、基础设施建设、自然资源保护、污染防治、强化监管等方面采取切实可行的措施,保护农村生态环境。     

土壤重金属污染及其修复技术研究

土壤重金属污染物有汞、镉、铅、锌等,主要来源于交通运输、工业污染和农业污染。土壤重金属污染会导致农作物减产甚至死亡,对人体健康也会产生极大危害。目前土壤重金属污染修复的技术主要包括工程修复法、物理化学修复法、化学修复法和生物修复法。植物修复技术作为一种新兴的绿色、生态、高效的修复技术具有良好的发展前景。     

Ambient TSP concentration and dustfall in major cities of China: Spatial distribution and temporal variability

Based on environmental monitoring data in 93 major cities and meteorological records at 398 weather stations in China from 1981 to 2007, total suspended particle (TSP) concentration, the intensity of dustfall, and sand and dust storm frequency (F_d) were analysed. During the past 27 years, the annual average TSP concentration (C_TSP) in 93 cities was 402 μg m^?3. Annual average C_TSP decreased from the north to the south and from inland to the coast areas with a peak value of 628.8 μg m^?3 in Lanzhou. In the 1980s, 1990s and 2000s, annual average C_TSP was 628.7, 319.2, and 250.1 μg m^?3, respectively. Annual average intensity of dustfall (I_d) was 240.5 t km^?2 a^?1, decreased from northern to southern China and from inland to the coast areas with the maximum value of 717.2 t km^?2 a^?1 in Baotou. In the 1980s, 1990s and 2000s, annual average I_d was 334.8, 220.9, 146 t km^?2 a^?1 respectively. Annual average I_d in the Loess Plateau region was commonly higher than 200 t km^?2 a^?1. The annual average F_d decreased from arid regions in northwestern China to humid areas in southeastern China with two sand and sand storm centers existing in Xinjiang Taklamakan Desert and western Inner Mongolia. The annual average F_d in the 1980s, 1990s, 2000s was 16, 8, 6 days respectively, decreased steadily from 18 days in 1981–5 days in 2007. Annual average I_d had a positive linear relation to annual average C_TSP (R² = 0.96). Annual average F_d had a positive relation with annual average C_TSP (R² = 0.97) as well as annual average I_d (R² = 0.94). TSP was the chief pollutant influencing Air Pollution Index (API) in northern China in spring and winter seasons. Sand and dust storm might be a major factor affecting the temporal variability and spatial distribution of TSP and dustfall in China.     

Characterization of plutonium in deep-sea sediments of the Sulu and South China Seas

Anthropogenic Pu isotopes are important geochemical tracers for sediment studies. Their distributions and sources in the water columns as well as the sediments of the North Pacific have been intensively studied; however, information about Pu in the Southeast Asian seas is limited. To study the isotopic composition of Pu, and thus to identify its sources, we collected sediment core samples in the South China Sea and the Sulu Sea during the KH-96-5 Cruise of the R/V Hakuho Maru. We analysed the activities of ^239+240Pu and the atom ratios of ²⁴⁰Pu/²³⁹Pu using isotope dilution sector-field inductively coupled plasma mass spectrometry (SF-ICP-MS). The ²⁴⁰Pu/²³⁹Pu atom ratios in the sediments of both areas (inventory weighted mean: 0.251 for the South China Sea and 0.280 for the Sulu Sea) were higher than the global fallout value (0.178 ± 0.019), suggesting the existence of Pu from the Pacific Proving Grounds in the North Pacific. Low inventories of ^239+240Pu in sediments were observed in the South China Sea (3.75 Bq/m²) and the Sulu Sea (1.38 Bq/m²). Most of the Pu input is still present in the water column. Scavenging and benthic mixing processes were considered to be the main processes controlling the distribution of Pu in the deep-sea sediments of both study areas.     

Remediation of acid mine drainage (AMD)-contaminated soil by Phragmites australis and rhizosphere bacteria

Experiments were conducted to assess the impact of citric acid (CA) and rhizosphere bacteria on metal uptake in Phragmites australis cultured in a spiked acid mine drainage (AMD) soil. Rhizosphere iron-oxidizing bacteria (Fe(II)OB) enhanced the formation of Fe plaque on roots, which decreased the uptake of Fe and Mn. CA inhibited the growth of Fe(II)OB, decreased the formation of metal plaque, raised the metal mobility in soil, and increased the accumulation of metals in all tissues of the reeds. The higher the CA dosage, the more metals accumulated into reeds. The total amount of metals in reeds increased from 7.8?±?0.5?×?10^?6 mol plant^?1 (Mn), 1.4?±?0.1?×?10^?3 mol plant^?1 (Fe), and 1.0?±?0.1?×?10^?4 mol plant^?1 (Al) in spiked soil without CA to 22.2?±?0.5?×?10^?6 mol plant^?1 (Mn), 3.5?±?0.06?×?10^?3 mol plant^?1 (Fe), and 5.0?±?0.2?×?10^?4 mol plant^?1 (Al) in soil added with 33.616 g C₆H₈O₇·H₂O for per kilogram soil. CA could be effective at enhancing the phytoremediation of metals from AMD-contaminated soil.