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351.
Although microbial transformations via cometabolism have been widely observed, the few available kinetic models of cometabolism have not adequately addressed the case of inhibition from both the growth and nongrowth substrates. The present study investigated the degradation kinetics of self-inhibitory growth (phenol) and nongrowth (4-chlorophenol, 4-CP) substrates, present individually and in combination. Specifically, batch experiments were performed using an Acinetobacter isolate growing on phenol alone and with 4-CP present. In addition, batch experiments were also performed to evaluate the transformation of 4-CP by resting, phenol-induced Acinetobacter cultures. The Haldane kinetic model adequately predicted the biodegradation of phenol alone, although a slight discrepancy was noted in cases of higher initial phenol concentrations. Similarly, a Haldane model for substrate utilization was also able to describe the trends in 4-CP transformation by the resting cell cultures. The 4-CP transformation by the Acinetobacter species growing on phenol was modeled using a competitive kinetic model of cometabolism, which included growth and nongrowth substrate inhibition and cross-inhibition terms. Excellent agreement was obtained between the model predictions using experimentally estimated parameter values and the experimental data for the synchronous disappearance of phenol and 4-CP. 相似文献
352.
Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (DL-PCBs) were measured in ambient air samples collected from different parts of South Korea in 2008, and the measured levels were used for assessing the spatial and temporal distribution of atmospheric PCDDFs and DL-PCBs in South Korea. The average concentrations of atmospheric PCDD/Fs and DL-PCBs among the 37 sites were 28 fg I-TEQ m−3 (ND ∼ 617) and 1 fg WHO-TEQ m−3 (ND ∼ 0.016). Elevated atmospheric levels of PCDD/Fs and DL-PCBs observed at residential/industrial sites and in the north-west of Korea, indicated a potential contribution and impacts of anthropogenic sources of PCDD/Fs and DL-PCBs. These levels were similar or lower than those previously reported in other ambient air surveys. Average concentrations of PCDD/Fs showed small seasonal variations (ANOVA analysis, p = 0.144). The highest concentrations of PCDD/Fs were observed during winter, followed by spring, autumn and summer. Atmospheric PCDD/Fs and DL-PCBs in South Korea rapidly decreased during the last 10 years (1998-2008), demonstrating the efficiency of stricter regulations and the application of best available technologies/best environmental practices at emission sources. Comparison of the congener profiles and principal component analysis showed that current atmospheric PCDD/Fs are mostly influenced by industrial sources and PCBs from old commercial PCB uses. Nationwide POPs monitoring will continue and allows an effective evaluation of the implementation of the Stockholm Convention on POPs. 相似文献
353.
Reductive dechlorination and biodegradation of 2,4,6-trichlorophenol using sequential permeable reactive barriers: laboratory studies 总被引:3,自引:0,他引:3
The reductive dechlorination and biodegradation of 2,4,6-trichlorophenol (2,4,6-TCP) was investigated in a laboratory-scale sequential barrier system consisting of a chemical and biological reactive barrier. Palladium coated iron (Pd/Fe) was used as a reactive barrier medium for the chemical degradation of 2,4,6-TCP, and a sand column seeded with anaerobic microbes was used as a biobarrier following the chemical reactive barrier in this study. Only phenol was detected in the effluent from the Pd/Fe column reactor, indicating that the complete dechlorination of 2,4,6-TCP was achieved. The residence time of 30.2-21.2h was required for the complete dechlorination of 2,4,6-TCP of 100 mg l(-1) in the column reactor. The surface area-normalized rate constant (k(SA)) is 3.84 (+/-0.48)x10(-5)lm(-2)h(-1). The reaction rate in the column tests was one order of magnitude slower than that in the batch test. In the operation of the biobarrier, about 100 microM of phenol was completely removed with a residence time of 7-8d. Consequently, the dechlorination prior to biodegradation turns out to increase the overall treatability. Moreover, the sequential permeable reactive barriers, consisting of iron barrier and biobarrier, could be recommended for groundwater contaminated with toxic organic compounds such as chlorophenols. 相似文献
354.
The adsorption characteristics of heavy metals by various particle sizes of MSWI bottom ash 总被引:8,自引:0,他引:8
The incineration rate of municipal solid waste (MSW) has been increased because of difficulty in securing a proper disposal site for MSW in Korea. The advantage of incineration is reduction of the volume of waste; however, significant amounts of bottom ash and fly ash were generated in the incineration process. Their treatment has attracted growing interest because of the potential toxicity of hazardous heavy metals. Generally, heavy metals are less released from bottom ash than from fly ash. In this study the adsorption characteristics of heavy metals were investigated using various particle sizes of MSWI bottom ash. Since bottom ash has a broad particle size distribution, it was sieved to size classes of +20, -20, -48, -80, -100 mesh. Cation exchange capacity (CEC) was analyzed by the ammonium acetate method to evaluate the potential as an adsorbent. The CEC values and surface areas increase as the range of particle size becomes finer. The adsorption experiment was conducted using synthetic (Cu and Ni) and plating rinse water as a function of reaction time (10-180 min), liquid/solid ratio (2-100) and particle size (+20 to -100 mesh), respectively. The adsorption rate increased with decreasing particle size and with increasing liquid/solid ratio; however, the removal efficiency of Cu was higher than that of Ni. In the case of plating rinse water, the adsorption rate decreased sharply at high liquid/solid ratio, and it showed over 80% of adsorption rates for Cu and Ni at an initial pH of 3. 相似文献
355.
Life cycle assessment of selective non-catalytic reduction (SNCR) of nitrous oxides in a full-scale municipal solid waste incinerator 总被引:1,自引:0,他引:1
Selective non-catalytic reduction (SNCR) of nitrous oxides in a full-scale municipal solid waste incinerator was investigated using LCA. The relationship between NOx-cleaning and ammonia dosage was measured at the plant. Un-reacted ammonia - the ammonia slip - leaving the flue-gas cleaning system adsorbed to fly-ash or in the effluent of the acidic scrubber was quantified from the stoichiometric reaction of NOx and ammonia assuming no other reaction products was formed. Of the ammonia slip, 37% was associated with the fly-ash and 63% was in the effluent of the acidic scrubber. Based on NOx-cleaning efficiency, the fate of the ammonia slip as well as the environmental impact from ammonia production, the potential acidification and nutrient enrichment from NOx-cleaning was calculated as a function of ammonia dosage. Since the exact fate of the ammonia slip could not be measured directly, a number of scenarios were set up ranging from “best case” with no ammonia from the slip ending up in the environment to “worst case” where all the ammonia slip eventually ended up in the environment and contributed to environmental pollution. In the “best case” scenario the highest ammonia dosage was most beneficial demonstrating that the environmental load associated with ammonia production is of minor importance. In contrast, in a “worst case” scenario” NOx-cleaning using SNCR is not recommendable at all, since the impacts from the ammonia slip exceed the saved impacts from the NOx removal. Increased dosage of ammonia for removal of NOx is recommendable as long as less than 10-20% of the ammonia slip to the effluent of the acidic scrubber ends up in the environment and less than 40% of the slip to the fly-ash ends up in the environment. The study suggests that the actual fate of the ammonia slip is crucial, but since the release of the ammonia may take place during transport and at the facilities that treat the wastewater and treat the fly-ash this factor depends strongly on local conditions and may be hard to determine. Thus, LCA-modeling proved useful in assessing the balance between ammonia dosage and NOx-removal in flue-gas cleaning from waste incineration. 相似文献
356.
Influence of calcium chloride on the thermal behavior of heavy and alkali metals in sewage sludge incineration 总被引:2,自引:0,他引:2
In order to separate and reuse heavy and alkali metals from flue gas during sewage sludge incineration, experiments were carried out in a pilot incinerator. The experimental results show that most of the heavy and alkali metals form condensed phase at temperature above 600 degrees C. With the addition of 5% calcium chloride into sewage sludge, the gas/solid transformation temperature of part of the metals (As, Cu, Mg and Na) is evidently decreased due to the formation of chloride, while calcium chloride seems to have no significant influence on Zn and P. Moreover, the mass fractions of some heavy and alkali metals in the collected fly ash are relatively high. For example, the mass fractions for Pb and Cu in the fly ash collected by the filter are 1.19% and 19.7%, respectively, which are well above those in lead and copper ores. In the case of adding 5% calcium chloride, the heavy and alkali metals can be divided into three groups based on their conversion temperature: Group A that includes Na, Zn, K, Mg and P, which are converted into condensed phase above 600 degrees C; Group B that includes Pb and Cu which solidify when the temperature is above 400 degrees C; and Group C that includes As, whose condensation temperature is as low as 300 degrees C. 相似文献
357.
Nutrient-impregnated charcoal: an environmentally friendly
slow-release fertilizer 总被引:20,自引:0,他引:20
Modabber Ahmed Khan Ki-Wook Kim Wang Mingzhi Bu-Kug Lim Weon-Hee Lee Jong-Yoon Lee 《The Environmentalist》2008,28(3):231-235
The widespread contamination of surface and ground water quality from the heavy use of fertilizer in modern agriculture is
the current concern. Therefore, this study was carried out to develop a slow-release fertilizer using charcoal. The morphology
of the charcoal impregnated fertilizer was investigated by scanning electron microscopy (SEM). This study also evaluated the
release patterns of N, P, and K from impregnated charcoal using a simulated soil solution and distilled water as leaching
solutions. The patterns of N, P, and K releases were examined in both static and continuous-flow conditions for 360 h. Releases
of N, P, and K from impregnated charcoal were found to be slow and steady. However, the release trends of N, P, and K were
higher in soil solution than distilled water under both the above conditions. Dissolution occurred when N, P, and K were released
in the above leached solutions. As a result, the fertilizer impregnated charcoal could be developed as slow-release type fertilizer
to minimize the contamination. 相似文献
358.
This article describes the integrated modeling approach for planning the size and the operation of constructed wetlands for
maximizing retention of nonpoint source pollutant loads and reservoir water-quality improvement at a catchment scale. The
experimental field-scale wetland systems (four sets, 0.88 ha each) have been in operation since 2002, where water depth was maintained
at 30–50 cm and hydraulic loading rate was at 6.3–18.8 cm/day. The wetland system was found to be adequate for treating polluted
stream water with stable removal e ciency even during the winter. The integrated modeling system (modified-BASINS) was applied to
the Seokmoon estuarine reservoir watershed and calibrated with monitoring data from constructed wetland, stream, and reservoir. The
calibrated integrated modeling system estimated that constructing wetlands on 0.5% (about 114 ha) of the watershed area at the mouth
of reservoir could reduce 11.61% and 13.49% of total external nitrogen and phosphorus loads, respectively. It also might improve the
nitrogen and phosphorus concentration of the reservoir by 9.69% and 16.48%, respectively. The study suggested that about 0.1%–1.0%
of the watershed area should be allocated for constructed wetland to meet specified water-quality standards for the estuarine reservoir
at the polder area where land use planning is relatively less complicated. 相似文献
359.
Geumhee Yun Hansaem Lee Yongsuk Hong Sungpyo Kim Glen T. Daigger Zuwhan Yun 《环境科学学报(英文版)》2019,31(2):388-402
We examined how long-term operation of anaerobic–oxic and anaerobic–anoxic sequencing batch reactors(SBRs) affects the enhanced biological phosphorus removal(EBPR)performance and sludge characteristics. The microbial characteristics of phosphorus accumulating organism(PAO) and denitrifying PAO(DPAO) sludge were also analyzed through a quantitative analysis of microbial community structure. Compared with the initial stage of operation characterized by unstable EBPR, both PAO and DPAO SBR produced a stable EBPR performance after about 100-day operation. From day 200 days(DPAO SBR)and 250 days(PAO SBR) onward, sludge granulation was observed, and the average granule size of DPAO SBR was approximately 5 times larger than that of PAO SBR. The DPAO granular sludge contained mainly rod-type microbes, whereas the PAO granular sludge contained coccus-type microbes. Fluorescence in situ hybridization analysis revealed that a high ratio of Accumulibacter clade I was found only in DPAO SBR, revealing the important role of this organism in the denitrifying EBPR system. A pyrosequencing analysis showed that Accumulibacter phosphatis was present in PAO sludge at a high proportion of 6%,whereas it rarely observed in DPAO sludge. Dechloromonas was observed in both PAO sludge(3.3%) and DPAO sludge(3.2%), confirming that this organism can use both O_2 and NO_3~- as electron acceptors. Further, Thauera spp. was identified to have a new possibility as denitrifier capable of phosphorous uptake under anoxic condition. 相似文献
360.
Characteristics of contaminants in water and sediment of a constructed wetland treating piggery wastewater effluent 总被引:2,自引:0,他引:2
Constructed wetland (CW) is the preferred means of controlling water quality because of its natural treatment mechanisms and function as a secondary or tertiary treatment unit. CW is increasingly applied in Korea for secondary effluent of livestock wastewater treatment. This study was conducted to recognize the characteristics of contaminants in the accumulated sediment at the bottom soil layer and to reduce the phosphorus release from sediments of the free water surface CW for the treatment of secondary piggery wastewater effluent from a livestock wastewater treatment facility. The results revealed that the dominant phosphorus existence types at near the inlet of the CW were non-apatite phosphorus (59%) and residual phosphorus (32%) suggesting that most of the particles of the influent are made up of inorganic materials and dead cells. Sediment accumulation is important when determining the long-term maintenance requirements over the lifetime of CW. Continuous monitoring will be performed for a further assessment of the CW system and design. 相似文献