Tracing lead pollution sources in abandoned mine areas using stable Pb isotope ratios

This study focused on Pb isotope ratios of sediments in areas around an abandoned mine to determine if the ratios can be used as a source tracer. For pretreatment, sediment samples were dissolved with mixed acids, and a multi-collector inductively coupled plasma mass spectrometer (MC-ICP-MS, Nu plasma II) was used to investigate the Pb isotopic composition of the samples. The measured isotope ratios were then corrected for instrumental mass fractionation by measuring the ²⁰³Tl/²⁰⁵Tl ratio. Repeated measurements with the NIST SRM 981 reference material showed that the precision of all ratios was below 104 ppm (±2σ) for 50 ng/g. The isotope ratios (²⁰⁷Pb/²⁰⁶Pb) found were 0.85073?±?0.0004~0.85373?±?0.0003 for the main stream, while they were 0.83736?±?0.0010 for the tributary and 0.84393?±?0.0002 for the confluence. A binary mixing equation for isotope ratios showed that the contributions of mine lead to neighboring areas were up to 60 %. Therefore, Pb isotope ratios can be a good source tracer for areas around abandoned mines.     

The estimation of N2O emissions from municipal solid waste incineration facilities: The Korea case

The greenhouse gases (GHGs) generated in municipal solid waste (MSW) incineration are carbon dioxide (CO₂), methane (CH₄), and nitrous oxide (N₂O). In South Korea case, the total of GHGs from the waste incineration facilities has been increasing at an annual rate 10%. In these view, waste incineration facilities should consider to reduce GHG emissions.This study is designed to estimate the N₂O emission factors from MSW incineration plants, and calculate the N₂O emissions based on these factors. The three MSW incinerators examined in this study were either stoker or both stoker and rotary kiln facilities. The N₂O concentrations from the MSW incinerators were measured using gas chromatography-electron capture detection (GC-ECD) equipment.The average of the N₂O emission factors for the M01 plant, M02 plant, and M03 plant are 71, 75, and 153 g-N₂O/ton-waste, respectively. These results showed a significant difference from the default values of the intergovernmental panel on climate change (IPCC), while approaching those values derived in Japan and Germany. Furthermore, comparing the results of this study to the Korea Energy Economics Institute (KEEI) (2007) data on waste incineration, N₂O emissions from MSW incineration comprised 19% of the total N₂O emissions.     

Case study in Korea of manufacturing SRF for polyurethanes recycling in e-wastes

Statistics showed that approximately 1,195,000 refrigerator units (116,094 metric tons) were recycled annually in Korea’s formal sector. Although the recycling level for these was satisfactory, collecting and processing polyurethane at recycling centers (RCs) posed several problems, including the risk of fire from the incinerator, the generation of fugitive dust, and the high cost of disposal. The objective of our study is to provide an overview of refrigerator recycling and to introduce polyurethane solid refuse fuel (SRF) manufacturing facilities. These facilities, installed at four regional RCs in Korea, have a capacity of 800 kg/h, a motor of 476 kWh, and cost $664,300 (USD) to construct (criteria two facilities). According to our examination of the physico-chemical properties of SRF product, all results in categories have been satisfied with the quality standards. In terms of finances, RCs can reduce the total disposal cost from $160–175 to $60 by installing facilities, which results in savings of (on average) $180,546 annually. The Metropolitan Electronics Recycling Center, for example, has reduced its costs by $180,880 each year. Their return on investment was calculated to be about 3 years and 8 months (assuming no operating expenses) or 7 years and 4 months (including operating expenses).     

Variability of nitrous oxide and carbon dioxide emissions continuously measured in solid waste incinerators

Nitrous oxide and carbon dioxide were continuously measured and variability of emission factors (EFs) was evaluated in five municipal waste incinerators (MWIs) and four industrial waste incinerators (IWIs) from 24 to 86 days between 2008 and 2011. N₂O EFs were calculated by Monte Carlo simulation and mean N₂O EFs were 7.1, 107, 127, 219 g N₂O/ton waste combusted in MWIs with selective catalytic reduction (SCR) for NOx control, MWIs with selective non-catalytic reduction (SNCR), IWIs with SNCR, and a MWI using fluidized bed with SNCR, respectively. Climate-relevant CO₂ EFs ranged from 0.45 to 0.72 ton CO₂/ton waste combusted in MWIs. Maximum values of upper limit for 95% confidence intervals (CIs) of N₂O EFs estimated in each MWIs with SCR, MWIs with SNCR, IWIs with SNCR were 185, 94, 101% of mean N₂O EFs, respectively. Meanwhile, maximum values of upper limit for 95% CIs of CO₂ EFs were much lower as between 18 and 36% in those facilities. 84% CIs of mean N₂O EFs in MWIs with SNCR and IWIs with SNCR were overlapped indicating those values are not significantly different.     

Establishing methodology for evaluating refrigerant recovery and recycling equipment: institutional responses to climate change in South Korea

Journal of Material Cycles and Waste Management - This paper aims to propose testing methods and standards for evaluating refrigerant recovery and recycling equipment so that the methodology can be...     

The ionic compositions of fine and coarse particle fractions in the two urban areas of Korea

The ionic composition of PM2.5 and PM10 was investigated using PM samples collected from Seoul and Busan during the winter of 2002. Based on the measurement data, we attempted to investigate the relative roles of different source processes in the composition of airborne particles at the two distinct urban areas. According to our measurements, the major components of both PM fractions were clearly distinguished from each other at the two different sites. It was found that the ionic concentrations in coarse fractions were generally compatible with each other at the two sites (NH(4)(+), NO(3)(-), NSSS, etc.). However, differences in their concentration levels were significant in the fine fractions and their mass concentration levels in Seoul exhibit threefold enhancement relative to Busan. The results further indicated that anthropogenic signatures were generally more evident in the fine rather than coarse fractions at both sites. However, a comparison of the coarse fraction data indicated the dominance of natural (oceanic) processes at the Busan site and conservative relationships among the different ionic components. The results of the back trajectory analysis confirmed that air mass movement patterns influence the ionic compositions of PM across different particle fractions and between different study sites.     

Prevention of progressive collapse for building structures to member disappearance by accidental actions

Recently some building structures have collapsed because of losses of vertical load carrying capacities resulting from accidental events. In this paper, limit analysis called Compact Procedure is applied to some cases of collapsed structures and the key-elements in the structures are identified using Sensitivity Analysis. Two collapse prevention methods are discussed. For truss structures, the collapse can be prevented by reinforcement of members having sensitivity greater than 0.3–0.4. For frame structures, the relations between the sensitivity and the progressive collapse are defined using a safety factor and the progressive collapse can be prevented by fixing X braces into each span of the top floor.     

TCDD alters PKC signaling pathways in developing neuronal cells in culture

2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is known to induce neurodevelopmental deficits such as poor cognitive development and motor dysfunction. However, the mechanism of TCDD-mediated neurotoxicity remains unclear. Since PKC signaling is one of the most pivotal events involved in neuronal function and development, we analyzed the effects of TCDD on the PKC signaling pathway in cerebellar granule cells derived from PND-7 rat brain. Immunoblot analysis revealed the presence of PKC-alpha, betaII, delta, epsilon, lambda and iota in both cytosol and membrane fractions of cerebellar granule cells, but PKC-gamma was below the detectable level. TCDD induced a significant translocation of PKC-alpha, -betaII and -epsilon from cytosol to membrane fraction (p<0.05) and a marginal translocation of PKC-delta at high dose only (p<0.1). It also increased RACK-1, an adaptor protein for PKC, in a dose-dependent manner. Exposure to TCDD induced a dose-dependent increase of both [3H] PDBu binding and the intracellular calcium level. The results suggest that the selective PKC isozymes and RACK-1 are involved in TCDD-mediated signaling pathway and these proteins may be possible molecular targets in neuronal cells for TCDD exposure. Our study provides basic data to understand mechanism of TCDD-induced neurotoxicity with respect to PKC signaling pathway and a scientific basis for improving the health risk assessment of neurotoxicants by identifying intracellular target molecules in neuronal cells.     

Atmospheric deposition of polybrominated diphenyl ethers (PBDEs) in coastal areas in Korea

Atmospheric bulk samples were collected monthly, for one year, from urban, suburban, and rural sites located in the coastal areas of Korea, for the assessment of depositional fluxes and seasonal variations in atmospheric concentrations of PBDEs. Twenty individual PBDE congeners were found in atmospheric samples, and their depositional fluxes varied from 10.1 to 89.0 microg/m2/year. The highest depositional fluxes were found in two urbanized areas, with a strong urban-rural gradient. The relationship between PBDE and particulate depositional fluxes showed significant correlation for all locations, which suggested the association of PBDEs to particulate phase. Deca-BDE (BDE 209) was the predominant congener (>93%) in all deposition samples, which is consistent with a high consumption of deca-BDE for the flame-retardant market in Korea. Seasonal variability was observed in PBDE concentrations for the two urban sites, whereas no seasonal trend was found for either the suburban or the rural location.