秦皇岛市地质灾害风险区划的思考与探索

秦皇岛市已发现崩塌、泥石流、滑坡、采空塌陷等各类地质灾害点204处,已发生地质灾害111处,占54%。其中,人类工程经济活动与地质灾害形成发展关系密切。保护地质环境与生态环境,可采取加强地灾防治宣传,制止无序群采,禁止山区放牧,科学合理开采地下水,防止海水入侵,在群测群防的基础上,采取必要的工程治理措施。     

Latitudinal pattern in species diversity and its response to global warming in permafrost wetlands in the Great Hing’an Mountains, China

Permafrost wetlands are one of the most sensitive plant communities in response to global warming. Global warming could induce natural plant communities to shift into cooler climate zones, or extirpate. To understand how plant communities in permafrost wetlands are affected by global warming, we examined the patterns of plant species diversity in the 24 permafrost wetlands in the Great Hing’an Mountains along a latitudinal gradient. This gradient was characterized by a northward decline in mean annual temperature (Δ = 3.5°C) and mean annual precipitation (Δ = 38.7 mm). Our results indicated that latitudinal patterns in species diversity existed in the permafrost wetlands. The numbers of family, genus and species, the Gleason index and Shannon-Wiener index for shrubs decreased linearly with decreasing latitude, but increased for herbaceous plants. The latitudinal patterns in species diversity had influenced strongly by temperature. Simple linear regression yielded about 2 decreases in shrub number and 9 increases in herbaceous species number with an increase of mean annual temperature by 1°C, with 0.33 decreases in shrub diversity and 0.29 increases in herbaceous species diversity. If temperature warms 3.7°C by 2100, herbaceous plants might increase in the permafrost wetlands, with species number increasing 48% or 6 times and species diversity increasing 40% or 2 times; and some shrub species might decrease and even disappear in part of the areas with lower latitude, with species number decreasing 50–100% and species diversity decreasing 69–100%. The permafrost wetlands in the Great Hing’an Mountains might continue degenerating and shift northward with global warming over the next century.     

升金湖自然湿地越冬鹤类生境适宜性变化研究

升金湖湿地位于安徽省长江中下游区域,是鹤类重要的越冬地之一,湿地景观的变化影响越冬鹤类的生境质量。研究湿地内越冬鹤类生境变化地对湿地生态恢复有着重要的研究意义。以升金湖国家级自然保护区为研究对象,利用ERDAS软件将1986年到2015年间8个年份冬季的TM影像数据将景观类型分为8种类型,用FRAGSTATS软件计算出各个年份的景观指标。选取干扰程度、食物丰富度、植被覆盖和水文条件4种因子作为影响越冬鹤类生境的主要因子。建立越冬鹤类生境适宜性评价模型,用ArcGIS生成鹤类生境适宜性评价图。用皮尔逊相关分析研究鹤类数量与生境适宜性的相关性。结果表明：升金湖保护区的景观格局变化明显,湿地斑块数量增加,景观的破碎度程度增加,景观斑块差异在逐渐变小,多样性指数和均匀度指数逐渐变大。越冬鹤类生境适宜性综合指数从0.845下降到0.465,总体的生境明显恶化。越冬鹤类的生境适宜性面积从1986年的 13 577.11 hm2 下降到2015年的 7 424.42 hm2,进而导致越冬鹤类数量在1986年到2015年总体呈下降趋势。鹤类数量与生境适宜性呈正相关。 关键词： 生境影响因子;生境适宜性评价模;越冬鹤类;景观格局     

甲基异噻唑啉酮对斑马鱼胚胎的急性毒性和机制研究

甲基异噻唑啉酮(methylisothiazolinone,MIT)作为防腐剂,广泛用于个人护理品、日用品和涂料中。MIT随着污水进入地表水循环,普遍存在于水体中,但目前关于MIT对水生生物毒性的研究还比较少。本文以模式生物斑马鱼的胚胎作为受试对象,评价MIT对斑马鱼胚胎的毒性。将受精后3 h的健康斑马鱼胚胎暴露于梯度浓度的MIT下,观察其对胚胎生长发育的影响,用吖啶橙(AO)染色检测细胞凋亡情况。结果发现,48 h暴露浓度大于1.0 mg·L-1的胚胎孵化被显著抑制,72 h浓度大于1.52 mg·L-1的幼鱼心率显著降低,统计96 h幼鱼死亡和畸形数,并重复验证和计算得到96 h半致死浓度(96 h 50%lethal concentration,96 h-LC50)为6.15 mg·L-1,96 h半致畸浓度(96 h 50%teratogenesis concentration,96 h-TC50)为3.89 mg·L-1,测量96 h胚胎体长,分析最小生长抑制浓度(minimum concentration to inhibit growth,MCIG)为2.31 mg·L-1,AO染色显示72 h胚胎的凋亡细胞主要集中在脑部和尾部。不同时期下镜检观察到,胚胎出现的畸形主要包括尾部发育不良,脊柱弯曲,卵黄囊水肿和心包水肿。此外,高浓度处理组24 h胚胎自主抽动次数增加,72 h和96 h活动能力减弱,触碰反应迟钝。因此,推断MIT对斑马鱼胚胎的发育有较大影响,同时有一定的神经毒性。根据《危险化学品鱼类急性毒性分级试验方法》,判定MIT对斑马鱼胚胎为高毒,该毒性实验结果可为MIT在工业生产和环境中的风险管理提供依据。     

Promotional effect of transition metal doping on the properties of KF/CaO catalyst for biodiesel synthesis

A series of heterogeneous KF/CaO catalysts modified with transition metals (lanthanum, cerium, and zirconium) were prepared via wet impregnation method and applied to the trsansesterification process of waste cooking oil (WCO) as feedstock with methanol to biodiesel production. The structure, performance of the solid catalysts was characterized by X-ray diffraction (XRD), temperature programmed desorption of CO₂ (CO₂-TPD), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS). The effect of methanol/oil molar ratio, ¹reaction time, reaction temperature, catalyst amount, and stability was investigated. The results showed that 10 wt% of lanthanum, cerium, and zirconium improved the catalytic activity of KF/CaO catalyst. The maximum catalytic activity using the lanthanum doping of 10wt% on KF/CaO catalyst was reached 98.7% under the optimal reaction condition of methanol/oil molar ratio of 12:1, reaction for 1 h at reaction temperature of 65°C, and 4% (wt/wt oil) catalyst amount. In addition, the FAME yield of KF/CaO/La catalyst remained higher than 95% after 10 cycles. The promotional effect of lanthanum doping could be attributed to the enhancement of the basicity strength of KF/CaO catalyst and block the leach of Ca²⁺ in the transesterification reaction.     

用微电极测定曝气量对SBR系统中硝化作用的影响

为了研究曝气量对硝化作用的影响,实验采用3个相同的SBR装置,分别在曝气量为4、10和16 L/h的条件下处理人工污水,并采用自制的溶解氧、NO3-、NH4+和pH微电极测定了活性污泥絮体内部微元环境中相应基质的浓度。结果表明,曝气量为4 L/h时,活性污泥絮体内存在厌氧微区,NO3--N浓度减小了,发生了反硝化作用;而曝气量为10 L/h和16 L/h时,活性污泥絮体内发生的都是硝化反应,且NH4+-N浓度的减小量、NO3--N浓度的增大量都随着曝气量的增大而增大,pH随着曝气量的增大而减小。     

腐蚀性工业废气治理技术的研发及应用

这些年工业快速发展带动了我国经济快速发展,但是在工业生产过程中产生了大量的废气废液,有效处理这些工业有毒物质是工业发展需要面临的重要问题。本文在此基础上就腐蚀性工业废气治理技术的相关问题作了一定研究,以更好地促进我国经济的协调发展。     

臭氧氧化预处理难降解农药废水的研究

采用臭氧氧化技术预处理脲类农药生产废水,调节废水pH至弱碱,在此基础上考察废水臭氧氧化预处理的影响因素,得出最佳预处理条件：COD为200 mg/L,初始pH为11.3,臭氧投加量为14.2 mg/L。连续预处理180 min后,可生化性从0.12提高到0.58,说明该项技术可大大提高脲类农药废水的可生化性。     

上泉拱坝稳定分析及加固设计

上泉水库坝体为浆砌石连拱坝,现被定为病险水库,通过对拱坝结构强度、支墩抗滑稳定的计算分析,采用右坝肩基础、支墩防渗处理、坝体加固处理等措施进行除险加固,并对大坝稳定进行了验算。     

表面处理对芳纶无纬布防弹性能的影响

本文对芳纶无纬布的表面处理进行了研究,对比了处理前后的面密度、表面光滑柔软性能、厚度、防水性能以及防弹性能。通过比较可知,经过表面处理后,芳纶无纬布不仅实现了防水功能,且其防弹性能没有下降。这说明,此处理方法可行,适合推广。