长江口海域悬浮颗粒物中钴、镍、铁、锰的化学形态及分布特征研究

研究了重金属Co、Ni、Fe、Mn在长江口及邻近海域悬浮颗粒中的含量、存在形态以及它们在河水与海水混合过程中迁移转化特征,其变化动态特征表明,Co、Ni、Fe以残渣态为主要存在形式;由于Fe-Mn氧化物的形成和吸附作用,使上述金属从水体经过悬浮颗粒转到沉积物中;以Fe-Mn氧化物和碳酸盐形态存在的重金属含量受水体环境的pH和盐度制约。用多元回归分析求得不同形态重金属含量与盐度、pH值和悬浮物含量的变化方程,以及与环境要素间的相互关系。     

城市垃圾与排水污泥混合堆肥配比的研究

配比是城市垃圾与排水系统污泥（污水厂污泥和管道污泥）混合堆肥工艺的关键参数。研究以理论和实验分析的方法，确定了合理的实验方法，即以堆反原料参数空隙率与堆肥过程评价参数（稳定周期或过程平均耗氧速率）的实验数据相关分析来确定适宜配比值域。城市垃圾与污水厂污泥适宜配比，城市垃圾与污水厂污泥、管道污泥适宜配比，分别为０．２６～０．３８、０．３～０．４（总污泥重量分率）。     

基于生态足迹理论的辽宁省可持续发展动态分析

运用生态足迹方法对辽宁省2000年-2009年生态足迹和生态承载力进行了计算,并对辽宁省可持续发展程度进行了分析和预测。结果表明2000年-2009年期间辽宁省人均生态足迹快速增长,增幅达58.5%;而人均生态承载力基本不变,造成其生态赤字不断加大,涨幅达73.7%,生态系统处于一种不可持续发展状态。在此基础上利用非线性回归预测模型,对辽宁省未来十年的生态赤字进行了预测。并根据辽宁省近年来可持续发展与经济发展状况,提出遏制生态环境恶化、促进区域可持续发展的一些建议。     

新农药环境化学行为研究(Ⅶ)除草剂哌草丹(Dimepiperate)在土壤、水环境中的滞留、转化

研究了除草剂哌草丹在土壤、水环境中的吸附、脱附、水解及光解过程.结果指出:哌草丹在土壤上的吸附主要受土壤有机质的影响,粘土矿也有一定作用.吸附和脱附均可用Freundlich方程描述;根据降解产物推测了哌草丹的水解和光降解的机理,哌草丹的水解产物为2-苯基丙烯和六氢吡啶等,六氢吡啶可与土壤粘土矿(蒙脱石)作用,并与蒙脱石层间阳离子形成配合物;哌草丹光降解的产物为六氢吡啶、苯乙酮和甲醛.     

Experimental study on the feasibility of explosion suppression by vacuum chambers

In view of the invalidity of suppression and isolation apparatus for gas explosion, a closed vacuum chamber structure for explosion suppression with a fragile plane was designed on the base of the suction of vacuum. Using methane as combustible gas, a series of experiments on gas explosion were carried out to check the feasibility of the vacuum chamber suppressing explosion by changing methane concentration and geometric structure of the vacuum chamber. When the vacuum chamber was not connected to the tunnel, detonation would happen in the tunnel at methane volume fraction from 9.3% to 11.5%, with flame propagation velocity exceeding 2000 m/s, maximum peak value overpressure reaching 0.7 MPa, and specific impulse of shock wave running up to 20 kPa s. When the vacuum chamber with 5/34 of the tunnel volume was connected to the flank of the tunnel, gas explosion of the same concentration would greatly weaken with flame propagation velocity declining to about 200 m/s, the quenching distance decreasing to 3/4 of the tunnel length, maximum peak value overpressure running down to 0.1-0.15 MPa and specific impulse of shock wave below 0.9 kPa s. The closer the position accessed to the ignition end, the greater explosion intensity weakened. There was no significant difference between larger section and smaller vacuum chambers in degree of maximum peak value overpressure and specific impulse declining, except that quenching fire effect of the former was superior to the latter. The distance of fire quenching could be improved by increasing the number of the vacuum chambers.     

Study on machinability of a stellite alloy with uncoated and coated carbide tools in turning

Stellite alloys, which have been widely used in the aerospace, automotive and chemical industries, are hard-to-cut cobalt-based materials. This study investigates the machinability of stellite 12 alloys with uncoated carbide cutting tool grades YG610 (K01-K10) and YT726 (K05-K10/M20) and SANDVIK coated carbide tool SNMG150612-SM1105 under dry cutting conditions. Both wear mechanisms and failure modes of the uncoated and coated tools were investigated with turning experiments. The results show that the coated tool SM1105 remarkably outperforms the uncoated tools; and the cutting tool YG610 generally outperforms YT726 under all cutting conditions. Built-up edge was found with YG610 in some cutting conditions and with SM1105 at cutting speed of 16 m/min. Tool surface burning marks were observed on YT726 at relatively higher cutting speeds. Wear develops slowly with coated tools SM1105 until VB reaches 0.2 mm at most conditions (except at v = 43 m/min, f = 0.25 mm/r). Excessive tool flank typically resulted in tool breakage at the cutting edge for uncoated tools. Abrasive and adhesive wear of cutting tools were observed at low cutting speeds while diffusion and chemical wear occurred at higher cutting speeds.     

Two selenium tolerant Lysinibacillus sp. strains are capable of reducing selenite to elemental Se efficiently under aerobic conditions

Microbes play important roles in the transport and transformation of selenium (Se) in the environment, thereby influencing plant resistance to Se and Se accumulation in plant. The objectives are to characterize the bacteria with high Se tolerance and reduction capacity and explore the significance of microbial origins on their Se tolerance, reduction rate and efficiency. Two bacterial strains were isolated from a naturally occurred Se-rich soil at tea orchard in southern Anhui Province, China. The reduction kinetics of selenite was investigated and the reducing product was characterized using scanning electron microscopy and transmission electron microscopy-energy dispersive spectroscopy. The bacteria were identified as Lysinibacillus xylanilyticus and Lysinibacillus macrolides, respectively, using morphological, physiological and molecular methods. The results showed that the minimal inhibitory concentrations (MICs) of selenite for L. xylanilyticus and L. macrolides were 120 and 220 mmol/L, respectively, while MICs of selenate for L. xylanilyticus and L. macrolides were 800 and 700 mmol/L, respectively. Both strains aerobically reduced selenite with an initial concentration of 1.0 mmol/L to elemental Se nanoparticles (SeNPs) completely within 36 hr. Biogenic SeNPs were observed both inside and outside the cells suggesting either an intra- or extracellular reduction process. Our study implied that the microbes from Se-rich environments were more tolerant to Se and generally quicker and more efficient than those from Se-free habitats in the reduction of Se oxyanions. The bacterial strains with high Se reduction capacity and the biological synthesized SeNPs would have potential applications in agriculture, food, environment and medicine.     

中国南海渔业环境资源的保护研究

南海渔业资源具有"公共池塘资源"的基本属性是导致其面临地缘政治紧张局势的内生困境,为此有必要从南海渔业在低敏度领域的现实表征为立足点,与南海领土主权与海域划界争端等高敏度领域相互结合的角度考察与评判南海渔业资源环境保护的主权变动动向:应该注重传统捕鱼权在南海周边国家的海洋管辖权边界的应用.以东南亚渔业管理组织和新建立南海渔业管理组织联合协同组织新的东南亚渔业管理组织必定有助于南海渔业资源纠纷的解决.     

基于循环经济理念发展再生资源产业

探讨了循环经济理念下的资源观和资源循环规律，论述了循环经济赋予再生资源新的内涵、新的产业地位，分析了我国再生资源产业现状、面临的形势和存在的问题。最后从立法、政策、回收体系建设等方面给出产业发展建议。     

组合式油烟洗涤净化装置运行条件优化

通过设计二级组合式油烟洗涤装置,以清水为介质,进行动态模拟油烟气洗涤净化实验,研究最佳运行操作条件.实验结果表明:烟气流率、入口浓度和液相油烟浓度积累是影响二级组合式油烟洗涤装置总效率的重要因素,曝气深度对洗涤槽的洗涤效率有重要影响,而喷淋量则对填料洗涤塔的洗涤效果有重要影响;在烟气流率为2.8m3/h,入口浓度为3mg/m3,曝气深度为4.5～6.0cm(对应水深约为14.0cm),喷淋量为0.9L/min, 液相浓度＜12mg/L·CCL4的运行条件下,该净化装置对油烟废气的最大总净化效率可达80%.