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排序方式: 共有3671条查询结果,搜索用时 31 毫秒
921.
Jiao He Guoli Zi Zhiying Yan Yongli Li Jiao Xie Deliang Duan Yongjuan Chen Jiaqiang Wang 《环境科学学报(英文版)》2014,26(5):1195-1202
Cyanobacteria, which occurred in eutrophic water harvest solar light to carry out photosynthesis with high efficiency. In this work, cyanobacteria (Microcystis sp.) were used as biotemplate to synthesize titania structure. The synthesized titania sample had similar morphology to that of the original template in spite of the fragile unicellular structures and extremely high water content of cyanobacterial cells. Incorporation of biogenic C, as well as the morphology inherited from biotemplate improved visible- light absorbance of the titania structure. The sample exhibited higher visible-light photocatalytic activity than commercial titania photocatalyst Degussa P25 for Rhodamine B (RhB) degradation. Compared with those C-doped titania photocatalysts prepared by other methods, cyanobacteria templated titania photocatalyst offer some potential for competitive advantages. The reported strategy opened up a new use for the cyanobacteria. It could also be used for titania in applications such as treatment of polluted water, dye-sensitized solar cells, or other regions. 相似文献
922.
Quantification of viable bacteria in wastewater treatment plants by using propidium monoazide combined with quantitative PCR (PMA-qPCR) 总被引:1,自引:0,他引:1
The detection of viable bacteria in wastewater treatment plants(WWTPs) is very important for public health, as WWTPs are a medium with a high potential for waterborne disease transmission. The aim of this study was to use propidium monoazide(PMA) combined with the quantitative polymerase chain reaction(PMA-qPCR) to selectively detect and quantify viable bacteria cells in full-scale WWTPs in China. PMA was added to the concentrated WWTP samples at a final concentration of 100 μmol/L and the samples were incubated in the dark for 5 min, and then lighted for 4 min prior to DNA extraction and qPCR with specific primers for Escherichia coli and Enterococci, respectively. The results showed that PMA treatment removed more than 99% of DNA from non-viable cells in all the WWTP samples, while matrices in sludge samples markedly reduced the effectiveness of PMA treatment. Compared to qPCR, PMA-qPCR results were similar and highly linearly correlated to those obtained by culture assay, indicating that DNA from non-viable cells present in WWTP samples can be eliminated by PMA treatment, and that PMA-qPCR is a reliable method for detection of viable bacteria in environmental samples. This study demonstrated that PMA-qPCR is a rapid and selective detection method for viable bacteria in WWTP samples, and that WWTPs have an obvious function in removing both viable and non-viable bacteria. The results proved that PMA-qPCR is a promising detection method that has a high potential for application as a complementary method to the standard culture-based method in the future. 相似文献
923.
924.
通过对当前应急救援队伍的装备配置和维护保养情况进行调查,结合基层队伍的专项训练情况,分析现阶段应急救援队伍应急保障中存在的薄弱点,就如何提高应急救援队伍的救援能力提出建议。 相似文献
925.
pH值对易腐有机垃圾厌氧发酵产物分布的影响 总被引:23,自引:4,他引:19
易腐有机垃圾的厌氧发酵(水解和酸化)程度和发酵类型受pH值的影响.批式实验结果表明:发酵液pH=7时有利于微生物的生长繁殖,从而促进碳水化合物的水解和酸化过程,还能促进可溶性蛋白的酸化过程.在不同pH值条件下,易腐有机垃圾的基本发酵类型为:pH=7时主要进行丁酸发酵;pH=8时丁酸发酵类型逐渐占优势;而pH=5时丙酸发酵类型逐渐占优势.乳酸是酸化初期的主要产物,但在发酵液的pH=5和pH=7条件下,乳酸可被微生物进一步代谢,而pH=8时乳酸却未能被代谢.在酸化初期醇的产生量大于挥发性脂肪酸,酸化后期pH=5和pH=7时挥发性脂肪酸与醇产生量比值为1.2~1.5∶1,而pH=8时两者比值为1.6~2.5∶1.pH为5、7和8三者的水解速率常数kh分别为0.000 8 h-1、0.000 9 h-1和0.000 2h-1.pH=7在反应时间t>100 h以后,发酵液中可溶态总有机碳全部由酸化产物组成,酸化完全;而pH=5和pH=8达到酸化完全的反应时间分别为t>300 h和t>600 h. 相似文献
926.
Comparison of catalytic activity of two platinised TiO2 films towards the oxidation of organic pollutants 总被引:2,自引:0,他引:2
Two types of platinised TiO2 films, i.e., Pt-TiO2/ITO and Pt(TiO2)/ITO, were prepared by a procedure of dip-coating and subsequent photo-deposition, and photo-deposition and subsequent dip-coating, respectively. They were well characterized by DRS, XRD spectra, SEM microscopy and photoelectrochemical measurement. Their photocatalytic, dark catalytic and photoelectrocatalytic activities were investigated using formic acid as a model organic pollutants. Compared with pure TiO2/ITO film, the photocatalytic activity of the platinised TiO2 films were apparently improved. However, the improvement was considerably dependent on the preparation method of these films. Pt-TiO2/ITO not only possessed higher photocatalytic activity but also showed a dark catalytic activity towards HCOOH degradation. As a sequence, it was first emphasized that the dark catalytic effect of Pt-TiO2/ITO was partly responsible for degradation of formic acid in the photocatalytic oxidation process. Although the Pt(TiO2)/ITO film does not exhibit the dark catalytic activity, its photocatalytic degradation efficiencies towards HCOOH are higher than that of Pt-TiO2/ITO film. Therefore, in view of enhanced photocatalytic activity, the Pt(TiO2)/ITO was more favored than Pt-TiO2/ITO film. 相似文献
927.
Trace level perchlorate analysis in water initiated a new development in the Ion Chromatography (IC) technology. Maintenance of a low detection limit may be highly affected by the operating conditions of the IC system. In this paper the homoscedasticity of the IC system within the calibration concentration range, the effect of the system drift on the calibration curve and the effect of the self regeneration suppressor (SRS) current on the detection limit were investigated. The experimental results were evaluated by statistical methods such as the Cochran test and the lack of fit test. The detection limits were obtained by two ways. One through method detection limit (MDL) and the other through detection limit from the calibration curve (DTC). The Cochran test results revealed the homoscedasticity of the IC system. The effect of system drift on the calibration curve was noticed by the lack of fit test. MDL yielded a lower but less reliable detection limit than DTC. An acceptable detection limit can be achieved under the lower SRS current (100 mA). 相似文献
928.
Accumulation of copper in brown rice and effect of copper on rice growth and grain yield in different rice cultivars 总被引:2,自引:0,他引:2
A pot experiment with 38 commonly cultured rice cultivars showed that the effect of Cu (100 mg kg(-1)) on rice growth, grain yield and accumulation of Cu in brown rice varied greatly with different cultivars. Although the average Cu concentration in brown rice of the 38 cultivars was significantly increased (P<0.01) compared with the control, in none of the cultivars did Cu concentration in brown rice exceed the maximum permissible limit of 10 mg Cu kg(-1). This suggests that rice grown in Cu-contaminated paddy soil (100 mg Cu kg(-1)) will not adversely affect human health through the food chain. Because of the significant negative correlation between grain weight and Cu concentration in brown rice with the soil Cu treatment, screening for cultivars with low Cu accumulation in brown rice and high grain yield for Cu-contaminated areas is feasible. The present research led to the recommendation of three such cultivars: Jiahua, Zhenxian 866, Zhe 733. The average grain yield under Cu treatment (100 mg Cu kg(-1) soil) was significantly (P<0.01) reduced compared with the control. The decreases or increases of grain yields mainly resulted from the combined effects of the panicles per pot, spikelets per panicle and filled spikelets per panicle under the soil Cu treatment. Furthermore, there were significant (r=0.869, P<0.01) positive correlations between the RC (relative changes) of spikelets per panicle and filled spikelets per panicle under the soil Cu treatment. 相似文献
929.
Effects of metsulfuron-methyl on the microbial population and enzyme activities in wheat rhizosphere soil 总被引:1,自引:0,他引:1
He YH Shen DS Fang CR He R Zhu YM 《Journal of environmental science and health. Part. B》2006,41(3):269-284
The effects of metsulfuron-methyl, a sulfonylurea herbicide, on the wheat soil microorganisms were evaluated by the methods of microbial inoculation culture, and the activities of three enzymes were measured using the colorimetric method. The tolerant microorganisms that can resist 500 microg x g(-1) metsulfuron-methyl in the counting culture medium were studied specially. Metsulfuron-methyl distinctly inhibited the common aerobic heterotriphic bacteria, but the effects on common fungi and common actinomycete were not evident. In the meantime, the number of tolerant fungi increased greatly in the rhizosphere after the application of metsulfuron-methyl in contrast to the significant decrease of the amount of tolerant actinomycete. It indicates that fungi might turn into the dominant microbial type and actinomycete is the sensitive factor in the soil polluted by sulfonylurea residues. The population of aromatic compounds-decomposing bacteria, aerobic azotobacter, and nitrite bacteria all increased in the earlier period, but the aerobic azotobacter decreased rapidly in number 30 days later, and the amount of nitrite bacteria also showed a temporary decrease with time 15 days later. However, the denitrifying bacteria just began to increase significantly after the crops had grown for 50 days. The amount of sulfur-oxidizing bacteria gradually decreased with the growth of crops, and so were the sulfate-reducing bacteria after metsulfuron-methyl application. To all types of microorganisms, there were more microbes in rhizosphere samples than those in nonrhizosphere except aerobic azotobacter. It means the growth of wheat root system can stimulate the growth of most microorganisms. The activities of hydrogen peroxidase and polyphenol oxidase in soil samples after metsulfuron-methyl application were notably lower than those in the control, and the difference of the activities between the samples of rhizosphere and nonrhizosphere was evident. On the contrary, the activity of dehydrogenase was not inhibited by the application of metsulfuron-methyl, and the rhizosphere effect was not obvious either. 相似文献
930.
Liu Z He Y Li F Liu Y 《Environmental science and pollution research international》2006,13(5):328-332
Background, Aim and Scope
The polynitramines, hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX),
are important military explosives and regulated toxic hazardous compounds. Production, testing and use of the compounds has
resulted in numerous acres of contaminated soils and groundwater near many munitions facilities. Economical and efficient
methods for treatment of wastewater and cleanup of soils or groundwater containing RDX and HMX are needed. This study focuses
on the photocatalytic treatment of RDX wastewater with nano-sized titanium dioxide (nano-TiO2) under simulated sunlight, whose
intensity and wavelength are similar to that of the real sunlight in Xi'an at noon. The objective is to determine the potential
for RDX destruction with nano-TiO2 in aqueous solution.
Materials and Methods:
An activated carbon fiber (ACF) cloth-loaded with nano-TiO2 was put into the RDX containing solution, and the concentration
of RDX was measured (by HPLC–UV) at regular time intervals under simulated sunlight.
Results:
The RDX degradation percentage of the photocatalytic process is higher than that of Fenton oxidation before 80 min, equivalent
after 80 min, and it reaches 95% or above after 120 min. The nano-TiO2 catalyst can be used repeatedly.
Discussion:
The photocatalytic degradation kinetics of RDX under simulated sunlight can be described by a first-order reaction kinetics
equation. The possible degradation mechanism of RDX was presented and the degradation performance was compared with that of
biological method.
Conclusions:
It was demonstrated that the degradation of RDX wastewater is very effective with nano-TiO2 as the photocatalytic catalyst
under simulated sunlight. The efficiency of the nano-TiO2 catalyst for RDX degradation under simulated sunlight is nearly
identical to that of Fenton oxidation.
Recommendations and Perspectives:
To date, a number of catalysts show poor absorption and utilization of sunlight, and still need ultraviolet light irradiation
during wastewater degradation. The nano-TiO2 used in the described experiments features very good degradation of RDX under
simulated sunlight, and the manufacturing costs are rather low (around 10 Euro/m2). Moreover, the degradation efficiency is
higher compared to that of the biological method.
This method exhibits great potential for practical applications owing to its easiness and low cost. If it can be applied extensively,
the efficiency of wastewater treatment will be enhanced greatly. 相似文献